• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3233-3237
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• 2010

A $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ cathode was modified by coating with Li-La-Ti-O, and the effect of the coating thickness on their electrochemical properties was studied. The thickness of the coating on the surface of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ was increased by increasing the wt % of the coating material. The rate capability of the Li-La-Ti-O-coated electrode was superior to that of the pristine sample. 1- and 2-wt %-coated samples showed considerable improvement in capacity retention at high C rates. However, the rate capability of a 5-wt %-coated sample decreased. All the coated samples showed a high discharge capacity and slightly improved cyclic performance under a high cut-off voltage (4.8 V) condition. Results of a storage test confirmed that the Li-La-Ti-O coating layer was effective in suppressing the dissolution of the transition metals as it offered protection from the attack of the acidic electrolyte. In particular, the 2- and 5-wt %-coated samples showed a better protection effect than the 1-wt %-coated sample.

• Journal of Advanced Marine Engineering and Technology
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• 제33권6호
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• pp.860-866
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• 2009

It is very important to choose optimal material having good corrosion resistance and capabilities for the part materials such as the automotive exhaust system under a hot salt corrosion atmosphere. Generally, two types of corrosion come into the automotive exhaust system. One is 'Condensate Corrosion', which is occurred by exhaust gas condensate formed at the inner surface of exhaust system heated up during driving, which results in the acid condensate pitting. The other is 'High Temperature Salt Corrosion' occurring from the interaction between the chloride ion coming from salt at the seaside district or snow salt and the outer surface of exhaust system. By the corrosion attack, the main muffler is firstly damaged and the life cycle of an automobile is significantly decreased. It has been investigated that the hot salt corrosion properties of a STS 409L and 436L ferritic stainless steels which are well-known for the materials of the automotive exhaust system. In addition, the corrosion properties of hot dip aluminum coated STS 409L have been compared with uncoated steels. Aluminum coated STS 409L showed a superior corrosion resistance than uncoated STS 409L, and futhermore showed a better corrosion resistance than a STS 436L, which is an expensive ferritic stainless steel having a excellent corrosion resistance caused from more chromium content of an alloying element.

• 자원환경지질
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• 제27권6호
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• pp.507-521
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• 1994

Bentonite occurs in the Janggi Conglomerate of Tertiary age and consists mainly of montmorillonite with Mg as predominant interlayer cations. The bentonite was reacted with various concentrations of sulfuric acid (0.8~1.5M) for various reaction time (1-10h) at $103^{\circ}C$. Cation exchange capacity, exchangeable cations, surface area and solid acidity of the original bulk and acid activated bentonites were measured. Chemical analysis, X-ray diffraction, differential thermal analysis and infrared spectroscopy were used to characterize the changes in structure and properties of the acid activated bentonite. The dissolution of octahedral cations occurs not only from the edge of the clay platelets but also throughout the whole clay structure creating vacant octahedral sites. These lattice defects are created by $H^+$ diffused into the smectite layers. The cations leached possibly from the octahedral sheets are adsorbed on the interlayer exchange sites. They are exchanged with hydronium ions again by stronger acid attack. These reactions create wedge-shaped pores resulting in the increase of the surface area and the changes the morphology in the lattice structure.

• Wind and Structures
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• 제32권3호
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• pp.205-217
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• 2021

Cold regions with high air density and wind speed attract wind energy producers across the globe exhibiting its potential for wind exploitation. However, exposure of wind turbine blades to such cold conditions bring about devastating impacts like aerodynamic degradation, production loss and blade failures etc. A series of wind tunnel tests were performed to investigate the effect of icing on the aerodynamic properties of wind turbine blades. A baseline clean wing configuration along with four different ice accretion geometries were considered in this study. Aerodynamic force coefficients were obtained from the surface pressure measurements made over the test model using MPS4264 Simultaneous pressure scanner. 3D printed Ice templates featuring different ice geometries based on Icing Research Tunnel data is utilized. Aerodynamic characteristics of both the clean wing configuration and Ice accreted geometries were analysed over a wide range of angles of attack (α) ranging from 0° to 24° with an increment of 3° for three different Reynolds number in the order of 105. Results show a decrease in aerodynamic characteristics of the iced aerofoil when compared against the baseline clean wing configuration. The key flow field features such as point of separation, reattachment and formation of Laminar Separation Bubble (LSB) for different icing geometries and its influence on the aerodynamic characteristics are addressed. Additionally, attempts were made to understand the influence of Reynolds number on the iced-aerofoil aerodynamics.

• 한국항공우주학회지
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• 제34권12호
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• pp.9-17
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• 2006

진동하는 에어포일에서 비정상 경계층의 거동을 조사하기 위하여 실험적 연구가 수행되었다. 가로세로비가 2.7인 NACA 0012 에어포일은 시험부에 수직으로 설치되었고, 1/4 시위에서 조화 피칭운동을 한다. 에어포일의 진동 진폭은 -6$^{\circ}$에서 +6$^{\circ}$까지 변화하며 평균 받음각은 0$^{\circ}$ 이다. 표면에 부착되는 프로브(글루온 프로브)가 경계층 표면 유동를 측정하기 위하여 이용되었다. 측정은 자유흐름속도는 1.98, 2.83, 4.03m/s에서 수행되었고, 시위길이를 근거로 한 레이놀즈수는 각각 2.3$\times$104, 3.3$\times$104, 4.8$\times$104이다. 에어포일의 무차원 진동수를 모든 경우에서 0.1로 고정하였다. 비정상 경계층에서 최소 전단력의 위치와 경계층 붕괴의 위치는 레이놀즈수 2.3$\times$104와 3.3$\times$104 사이에서 크게 다르게 나타난다.

• 콘크리트학회논문집
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• 제15권6호
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• pp.794-801
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• 2003

건축물의 요구성능에 대한 관심이 점차 높아짐에 따라 건축물의 성능평가를 통하여 사용연한을 예측하고 건축물의 수명을 연장시키거나, 새롭게 재구성하려는 노력이 계속되고 있다. 그러나 아직 염화물에 의한 성능저하 평가에 있어 그 비용의 문제와 평가과정의 전문성 등의 많은 난점을 가지고 있다. 본 연구는 콘크리트 내부의 염화물침투 깊이를 측정하는 간이적 방법인 비색판별법을 이용하여 염화물에 의한 성능저하평가를 하고자 비색판별법의 적용가능성을 검토 후 변색위치의 침투염화물량을 정량분석하였다. 또한, 이를 이용하여 콘크리트 표면염화물량을 산정하고 철근위치 염화물량의 예측 및 한계염화물량에 도달시간 예측의 실용적 평가수단을 제시하였다. 염화물에 의한 철근콘크리트 구조물의 성능평가에 있어 간이평가 수단인 비색판별법의 활용에 따라 샘플수의 다량확보를 통한 신뢰수준의 향상을 이룰 수 있을 것으로 사료된다.

• 대한기계학회논문집B
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• 제29권8호
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• pp.911-920
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• 2005

The present study investigates heat/mass transfer and flow characteristics in a ribbed rotating passage with turning region. The duct has an aspect ratio (W/H) of 0.5 and a hydraulic diameter ($D_h$) of 26.67 mm. Rib turbulators are attached in the parallel arrangement on the leading and trailing surfaces of the passage. The ribs have a rectangular cross section of 2 m (e) $\times$ 3 m (w) and an attack angle of $70^{\circ}$. The pitch-to-rib height ratio (p/e) is 7.5, and the rib height-to-hydraulic diameter ratio (e/$D_h$) is 0.075. The rotation number ranges from 0.0 to 0.20 while the Reynolds number is constant at 10,000. To verify the heat/mass transfer augmentation, internal flow structures are calculated for the same conditions using a commercial code FLUENT 6.1. The results show that a pair of vortex cells are generated due to the symmetric geometry of the rib arrangement, and heat/mass transfer is augmented up to $Sh/Sh_0=2.9$ averagely, which is higher than that of the cross-ribbed case presented in the previous study for the stationary case. With the passage rotation, the main flow in the first-pass deflects toward the trailing surface and the heat transfer is enhanced on the trailing surface. In the second-pass, the flow enlarges the vortex cell close to the leading surface, and the small vortex cell on the trailing surface side contracts to disappear as the passage rotates faster. At the highest rotation number ($R_O=0.20$), the turn-induced single vortex cell becomes identical regardless of the rib configuration so that similar local heat/mass transfer distributions are observed in the fuming region for the cross- and parallel-ribbed case.

• Advances in materials Research
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• 제9권3호
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• pp.233-250
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• 2020

In this study, a chitosan based coating method was developed and applied on the shoe lining leather surface for evaluating its inhibition to bacterial and fungal attacks. At first, chitosan was prepared from raw prawn shells and then the prepared chitosan solution was applied onto the leather surface. Secondly, the characterization of the prepared chitosan and chitosan treated leather was performed by solubility test, ATR-FTIR, XRD pattern, SEM and TGA. Evaluation of antimicrobial efficacy of chitosan was assessed against two gram positive, two gram negative bacteria and a reputed fungi by agar diffusion test. The results of this study demonstrated that chitosan took place in both the surface of collagen fibres and inside the collagen matrix of crust leather. The chitosan showed strong antimicrobial activities against all the tested microorganisms and the inhibition increased with increasing percentage of chitosan. Therefore, the prepared chitosan in this study can be an environment friendly biocide, which functions simultaneously against different spoilage bacteria and fungi on the finished leather surface. Thus by using the prepared chitosan in shoe lining leather, the possibility of microbial attack during shoe wearing can be minimized which is one of the important hygienic requirements of footwear.

• Wind and Structures
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• 제37권4호
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• pp.315-329
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• 2023

We investigated the wind characteristics in the near-surface layer during the landfall of Typhoon Mujigae (2015) based on observations from wind towers in the coastal areas of Guandong province. Typhoon Mujigae made landfall in this region from 01:00 UTC to 10:00 UTC on October 4, 2015. In the region influenced by the eyewall of the tropical cyclone, the horizontal wind speed was characterized by a double peak, the wind direction changed by >180°, the vertical wind speed increased by three to four times, and the angle of attack increased significantly to a maximum of 7°, exceeding the recommended values in current design criteria. The vertical wind profile may not conform to a power law distribution in the near-surface layer in the region impacted by the eyewall and spiral rainband. The gust factors were relatively dispersed when the horizontal wind speed was small and tended to a smaller value and became more stable with an increase in the horizontal wind speed. The variation in the gust factors was the combined result of the height, wind direction, and circulation systems of the tropical cyclone. The turbulence intensity and the downwind turbulence energy spectrum both increased notably in the eyewall and spiral rainband and no longer satisfied the assumption of isotropy in the inertial subrange and the -5/3 law. This result was more significant in the eyewall area than in the spiral rainband. These results provide a reference for forecasting tropical cyclones, wind-resistant design, and hazard prevention in coastal areas of China to reduce the damage caused by high winds induced by tropical cyclones.

• 한국추진공학회지
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• 제13권3호
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• pp.41-49
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• 2009

본 논문은 공기흡입식 추진기관의 고체 로켓 부스터 분리에 관한 수학적 모델링과 시뮬레이션 기법을 기술하였다. 비행체 및 부스터는 하나의 다물체(multi-body)로 고려하였고 부스터는 단지 비행체의 축 방향으로 움직이는 것으로 가정하였다. 비행체 및 부스터의 동적 운동은 Kane 방법에 의해 모델링 되었다. 다양한 부스터 위치에 따라 전체 시스템에 작용하는 공력은 DATCOM 소프트웨어를 사용하여 산출되었으며 부스터 분리 유효 작용면에 작용하는 내부 분리 압력은 일반적인 기체역학 및 Taylor-MacColl 관계식에 의해 산출되었다. 수치적 해석은 Mathworks사의 Matlab이 사용되었다. 해석 결과에 의하면 부스터 분리 동안 마하수 및 받음각 변화 등은 크지 않는 것으로 나타났으며, 실제 시험 장치를 이용한 부스터 분리 시험이 진행될 경우 자세 각 변화, 흡입 유동 특성 등은 무시할 만한 수치임을 확인할 수 있었다.