• 제목/요약/키워드: atomic block

검색결과 115건 처리시간 0.028초

방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구 (Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation)

  • 이선영;송주명;손준용;신준화
    • 방사선산업학회지
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    • 제6권2호
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    • pp.171-176
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    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

Control of Block Copolymer Microdomain: In-Situ and Real-Time SANS Studies of Polymerization-Induced Self-assembly of Block Copolymer Microdomain Structure

  • Koizumi, Satoshi;Yamauchi, Kazuhiro;Hasegawa, Hirokazu;Tanaka, Hirokazu;Motokawa, Ryuhei;Hashimoto, Takeji
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.71-72
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    • 2006
  • We investigated a simultaneous living anionic polymerization process of isoprene (I) and 4styrene-d_8$ (S) in $benzene-d_6$ as a solvent with sec-buthyllithium as an initiator into polyisoprene(PI)-block-poly($styrene-d_8$)(PS) and the polymerization-induced molecular self-assembling process. This process was observed in-situ by time-resolved small-angle neutron scattering (SANS) experiment. The SANS profiles measured exhibited three time regions, where (i) the selective growth of PI chains occurs; (ii) the living chain ends switch from isoprenyllithium to styryllithium, and (iii) the SANS exhibited the polymerization induced disorder-to-order transition and order-to-order transition.

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Structural integrity assessment procedure of PCSG unit block using homogenization method

  • Gyogeun Youn;Wanjae Jang;Youngjae Jeon;Kang-Heon Lee;Gyu Mahn Lee;Jae-Seon Lee;Seongmin Chang
    • Nuclear Engineering and Technology
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    • 제55권4호
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    • pp.1365-1381
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    • 2023
  • In this paper, a procedure for evaluating the structural integrity of the PCSG (Printed Circuit Steam Generator) unit block is presented with a simplified FE (finite element) analysis technique by applying the homogenization method. The homogenization method converts an inhomogeneous elastic body into a homogeneous elastic body with same mechanical behaviour. This method is effective when the inhomogeneous elastic body has repetitive microstructures, and thus the method was applied to the sheet assembly among the PCSG unit block components. From the method, the homogenized equivalent elastic constants of the sheet assembly were derived. The validity of the determined material properties was verified by comparing the mechanical behaviour with the reference model. Thermo-mechanical analysis was then performed to evaluate the structural integrity of the PCSG unit block, and it was found that the contact region between the steam header and the sheet assembly is a critical point where large bending stress occurs due to the temperature difference.

공간예측에 의한 고속 2${\times}$2 프랙탈 영상압축 (A Very Fast 2${\times}$2 Fractal Coding By Spatial Prediction)

  • 위영철
    • 한국정보과학회논문지:시스템및이론
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    • 제31권11호
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    • pp.611-616
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    • 2004
  • 본 논문은 극소 원자블록(ultra small atomic block)에 공간예측(spatial prediction)을 적용하여 프랙탈(fractal) 영상압축의 압축시간을 획기적으로 향상시키고 화질/압축률을 향상시키는 방법을 제안한다. 본 방법은 치역(range block)의 크기가 아주 작으면 아주 적은 탐색범위 내에서 변환계수(transformation parameter)들의 값을 극히 제한하더라도 유사한 정의역(domain block)을 쉽게 찾을 수 있고 변환계수들이 좋은 상호관계를 유지함을 이용하여 변환계수 예측으로 화질/압축률을 향상시킨다. 특히, 본 방법은 탐색범위를 극히 제한하기 때문에 기존의 프랙탈 압축방법들 보다 압축시간을 획기적으로 향상시킨다.

Lifetime Evaluation of Digital Engineered Safety Features Actuation System Using Reliability Block Diagram

  • Park, Joo-Hyun;Lee, Dong-Young;Park, Jong-Gyun;Han, Jae-Bok;Jun Lyou
    • 한국신뢰성학회:학술대회논문집
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    • 한국신뢰성학회 2002년도 정기학술대회
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    • pp.387-401
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    • 2002
  • The Digital Engineered Safety Feature Actuation System (DESFAS) of nuclear power plants actuates safety systems to mitigate severe accidents occurred in nuclear power plants. The reliability of the system should be evaluated in order to meet the reliability criteria of nuclear power plants. In this work, we have calculated and evaluated the lifetime of DESFAS by using Reliability Block Diagram (RBD) and failure rates of digital control components. Surveillance test is assumed in the evaluation. The result shows that the digital control component can be used in DESFAS system.

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