• Title/Summary/Keyword: asymmetric step

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Synthesis of Pyrimidine Nucleosides as a Potential Asymmetric Catalysts (핵산유도체의 비대칭촉매 가능성연구)

  • Youn, In-Kwon;Beak, Gi-Hueon
    • The Journal of Natural Sciences
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    • v.9 no.1
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    • pp.95-104
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    • 1997
  • We synthesized the following series of 3', 5'hydroxy modified thymidine analogs to check the potential asymmetric catalytic effects. 3'-monomethylammino and dimethylaminothymidine was synthesized from thymidine via 8 step and 7 step in 38%, 20% overall yields respectively. 5'Acetyl-3'-dimethylamino thymidine was prepared from thymidine via 8 step in 40% overall yield. 5‘-TBS-3'-up-t BOC methylamino thymidine was prepared from thymidine via 6 step in 30% overall yield. 3'-acetyl-5'-t BOC amino thymidine was prepared from thymidine via 7 step in 31% overall yield.

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Texture and Plastic Strain Ratio Changes during a 2 Step Asymmetric Rolling and Annealing of AA5083 Al Alloy Sheet (2단계 비대칭 압연과 열처리한 AA5083 Al 합금판재의 집합조직과 소성변형비 변화)

  • Jeong, H.B.;Lee, J.H.;Kim, G.H.;Nam, S.K.;Kim, I.
    • Transactions of Materials Processing
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    • v.23 no.2
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    • pp.82-87
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    • 2014
  • The plastic strain ratio is one of the factors that affect the deep drawability of Al alloy sheet. The deep drawability of Al alloy sheet is limited because of its low plastic strain ratio. Therefore an increase in the plastic strain ratio to improve the deep drawability of Al alloy sheet is needed. The current study investigated the increase of the plastic strain ratio and the change in texture of AA5083 Al alloy sheet after a 2 step asymmetric rolling with heat treatments. The average plastic strain ratio of initial AA5083 Al alloy sheets was 0.83. After the first asymmetric rolling step of 88% deformation and subsequent heat treatment at $320^{\circ}C$ for 10 minutes the value was still 0.83. After the second asymmetric rolling of 14% reduction and subsequent heat treatment at $330^{\circ}C$ for 10 minutes the plastic strain ratio rose to 1.01. The average plastic strain ratio after the 2 step asymmetric rolling and heat treatment is 1.2 times higher than that of initial AA5083 Al alloy sheet. This result is related to the development of ND/<111> texture component after the second asymmetric rolling and heat treatment.

A Wide Voltage-Gain Range Asymmetric H-Bridge Bidirectional DC-DC Converter with a Common Ground for Energy Storage Systems

  • Zhang, Yun;Gao, Yongping;Li, Jing;Sumner, Mark
    • Journal of Power Electronics
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    • v.18 no.2
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    • pp.343-355
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    • 2018
  • A wide-voltage-conversion range bidirectional DC-DC converter is proposed in this paper. The topology is comprised of one typical LC energy storage component and a special common grounded asymmetric H-bridge with four active power switches/anti-parallel diodes. The narrow output PWM voltage is generated from the voltage difference between two normal (wider) output PWM voltages from the asymmetric H-bridge with duty cycles close to 0.5. The equivalent switching frequency of the output PWM voltage is double the actual switching frequency, and a wide step-down/step-up ratio range is achieved. A 300W prototype has been constructed to validate the feasibility and effectiveness of the proposed bidirectional converter between the variable low voltage side (24V~48V) and the constant high voltage side (200V). The slave active power switches allow ZVS turn-on and turn-off without requiring any extra hardware. The maximum conversion efficiency is 94.7% in the step-down mode and 93.5% in the step-up mode. Therefore, the proposed bidirectional topology with a common ground is suitable for energy storage systems such as renewable power generation systems and electric vehicles with a hybrid energy source.

Process Design for Hot Forging of Asymmetric to Symmetric Rail Steel (비대칭 레일강으로부터 대칭 레일강으로의 열간단조 공정설계)

  • 조해용;이기정;오병기;이학규
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.666-669
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    • 2002
  • Process design of hot forging, asymmetric to symmetric rail, which is used for the turnout of railway express has been investigated. Owing to the big difference in shape between the initial billet and the final forged product, it is impossible to hot forge the rail in a single step. Therefore, multi step forging as well as die design for each step are necessary for the production. The deformation behavior during hot forging has been analyzed by the numerical simulation through commercial FEA software, DEFORM$^{TM}$-2D. Modification of the design and repeated simulation have been carried out on the basis of the simulation result. For comparison with the simulation results, flow analysis experiment using plasticize has been also carried out. The results of the flow analysis experiment showed good agreement with those of the simulation. Therefore, the developed process design could be applied to the actual production.

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Optical Asymmetric Cryptography Modifying the RSA Public-key Protocol

  • Jeon, Seok Hee;Gil, Sang Keun
    • Current Optics and Photonics
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    • v.4 no.2
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    • pp.103-114
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    • 2020
  • A new optical asymmetric cryptosystem is proposed by modifying the asymmetric RSA public-key protocol required in a cryptosystem. The proposed asymmetric public-key algorithm can be optically implemented by combining a two-step quadrature phase-shifting digital holographic encryption method with the modified RSA public-key algorithm; then two pairs of public-private keys are used to encrypt and decrypt the plaintext. Public keys and ciphertexts are digital holograms that are Fourier-transform holograms, and are recorded on CCDs with 256-gray-level quantized intensities in the optical architecture. The plaintext can only be decrypted by the private keys, which are acquired by the corresponding asymmetric public-key-generation algorithm. Schematically, the proposed optical architecture has the advantage of producing a complicated, asymmetric public-key cryptosystem that can enhance security strength compared to the conventional electronic RSA public-key cryptosystem. Numerical simulations are carried out to demonstrate the validity and effectiveness of the proposed method, by evaluating decryption performance and analysis. The proposed method shows feasibility for application to an asymmetric public-key cryptosystem.

Process Design for Hot Forging of Asymmetric to Symmetric Rib-Well Shape Steel (비대칭 리브-웨브형강으로부터 대칭 리브-웨브형강으로의 열간단조 공정설계)

  • Cho, Hae-Yong;Lee, Ki-Joung;Choi, Jong-Ung;Jo, Chang-Yong;Lee, Hak-Kyu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.1
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    • pp.152-157
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    • 2003
  • Process design of hot forging, asymmetric to symmetric rib-web shape steel, which is used for the turnout of railway express has been investigated. Owing to the big difference in shape between the initial billet and the final forged product, it is impossible to hot forge the rail in a single step. Therefore, multi step forging as well as die design for each step are necessary for the production. The deformation behavior during hot forging has been analyzed by the numerical simulation through commercial FEA software, $DEFORM^{TM}$-2D. Modification of the design and repeated simulation have been carried out on the basis of the simulation result. For comparison with the simulation results. flow analysis experiment using plasticine has been also carried out. The results of the flow analysis experiment showed good agreement with those of the simulation. Therefore, the developed process design could be applied to the actual production.

Characteristics of Bifurcation Phenomena of Symmetric Flow Pattern in a Plane Sudden-Expansion Flow (평면급확장유동내 대칭유동분기현상의 특성에 관한 연구)

  • Cho, Jin-Ho;Lee, Moon-J.;Kim, Ki-Tae
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.33-38
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    • 2001
  • Bifurcation of unstable symmetric flow patterns to stable asymmetric ones in laminar sudden-expansion flow has been numerically investigated. Computations were carried out for an expansion ratio of 3 and over a range of the flow Reynolds numbers by using numerical methods of second-order time accuracy and a fractional-step method that guarantees divergence-free flowfields at all times. The critical Reynolds number above which bifurcation of pitchfork type to asymmetric flow pattern takes place is lower in a flow with a higher expansion ratio, in agreement with the previously reported results. The bifurcation diagrams show that the bifurcation takes place at a Reynolds number, $Re_c = 86.3$, higher than the value that has been reported. The lower critical Reynolds number may be due to deficiencies in their computations which employed SIMPLE-type relaxation methods rather than the initial-value approach of the present study. Characteristics of the flow development during the transition to asymmetric stable flow have been investigated by using spectral analysis of the velocity signals obtained by the simulations.

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Mass Transfer Modelling of Asymmetric Membrane Formation by Phase Inversion

  • 김제영;이환광;백기전;김성철
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.81-82
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    • 1997
  • 1. Introduction : The growth of membrane science was initiated by the invention of asymmetric membrane which can be formed by the technique known as phase inversion. The basic procedure of phase inversion involves casting a thin film of polymer solution onto a suitable substrate followed by immersion in a coagulation bath (quench step). Therefore, events occurring during the quench period, at which time solvent-nonsolvent exchange and eventual polymer precipitation take place, can play a controlling role in the determination of ultimate membrane structure.

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Operational Properties of Ridge Waveguide Lasers with Laterally Tapered Waveguides for Monolithic Integration

  • Kwon, Oh-Kee;Kim, Ki-Soo;Sim, Jae-Sik;Baek, Yong-Soon
    • ETRI Journal
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    • v.29 no.6
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    • pp.811-813
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    • 2007
  • We report on a ridge waveguide laser diode with laterally tapered waveguides fabricated in a single growing step using a double patterning method. In this structure, nearly constant output power is obtained with the change of the lower tapered waveguide width, and the facet power ratio of 1.4 to 1.5 is observed over the current range. The asymmetric facet power property is also investigated.

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Development of the Growth and Wavelength Control Technique of In As Quantum Dots for 1.3 μm Optical Communication Devices (1.3 μm 광통신용 소자를 위한 InAs 양자점 성장 및 파장조절기술 개발)

  • Park, Ho-Jin;Kim, Do-Yeob;Kim, Goon-Sik;Kim, Jong-Ho;Ryu, H.H.;Jeon, Min-Hyon;Leem, Jae-Young
    • Korean Journal of Materials Research
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    • v.17 no.7
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    • pp.390-395
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    • 2007
  • We systematically investigated the effects of InAs coverage variation, two-step annealing and an asymmetric InGaAs quantum well (QW) on the structural and optical characteristics of InAs quantum dots (QDs) by using atomic force microscopy (AFM), transmission electron microscopy (TEM) and photoluminescence (PL) measurement. The transition of size distribution of InAs QDs from bimodal to multi-modal was noticeably observed with increasing InAs coverage. By means of two-step annealing, it is found that significant narrowing of the luminescence linewidth (from 132 to 31 meV) from the InAs QDs occurs together with about 150 meV blueshift, compared to as-grown InAs QDs. Finally, the InAs QDs emitting at longer wavelength of $1.3\;{\mu}m$ with narrow linewidth were grown by an asymmetric InGaAs QW. The excited-state transition for the InAs QDs with an asymmetric InGaAs QW was not noticeably observed due to the large energy-level spacing between the ground states and the first excited states. The InAs QDs with an asymmetric InGaAs QW will be promising for the device applications such as $1.3\;{\mu}m$ optical-fiber communication.