• Title/Summary/Keyword: aromatic

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Inclusion Selectivity of the Cyanocadmate Host Complex with Piperazine Ligand for Aromatic Guest Molecules; Benzene, Toluene, Ethylbenzene and Xylene Isomers (Piperazine 리간드를 가진 시아노카드뮴 호스트 착물의 방향족 게스트 분자에 대한 포접선택성)

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.333-338
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    • 2003
  • Inclusion selectivity of a three-dimensional piperazine-ligated cyanocadmate host complex, $[Cd_x(CN)_{2x}\{HN(CH_2CH_2)_2NH\}_y]{\cdot}zG$, has been investigated for benzene (B), toluene (T), ethylbenzene (E), o- (O), m- (M), and p-xylene (P) isomers as the aromatic guest molecules. From the binary, ternary and quarternary guest mixtures of E and xylene isomer (X), the order of inclusion selectivity in the host complex is O>E>P>M. From the binary to quinary BTX mixtures, the order of preference in the complex is seen to be B>T>O${\gg}$P>M.

Dietary Intake and Venous Blood Concentration of Polycyclic Aromatic Hydrocarbons in Low-level Exposure (다환방향족탄화수소류의 음식물을 통한 섭취량과 혈중농도)

  • Moon, Chan-Seok
    • Journal of Environmental Health Sciences
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    • v.38 no.5
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    • pp.386-392
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    • 2012
  • Objectives: This study aims to evaluate the blood concentrations and dietary intake for 24-hour food duplicate of low level polycyclic aromatic hydrocarbons (PAHs). Design: The geometric means of the blood concentrations and dietary intake of 16 PAHs in college student candidates were simply compared with instrumental detection. Methods: The concentrations of 16 PAHs in venous blood and 24-hour food duplicates were analyzed with head-space solid phase microextraction (HS-SPME) of gas chromatography-mass spectrometry. Results: Naphthalene, acenaphthylene, pyrene, benz(a)anthracene, chrysene, and acenaphthene among the 16 analyzed PAHs were simultaneously detected both in venous blood and 24-hour food duplicate samples. Conclusion: The main exposure source of the six PAHs is thought to be oral intake from food through low level non-occupational exposure.

Biodegradation of Polycyclic Aromatic Hydrocarbons by White Rot Fungi (백색부후균을 이용한 다환방향족 탄화수소(PAHs) 의 분해)

  • 류원률;서윤수;장용근;조무환
    • KSBB Journal
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    • v.15 no.3
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    • pp.262-267
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    • 2000
  • The white rot fungi Phanerochaete chrysosporium(IFO 31249) Trametes sp and Pleurotus sp. were studied for their ability to degrade Polycyclic Aromatic Hydrocarbons(PAHs) using anthracene and pyrene as model compounds. The disapperarance anthracene and pyrene of from cultures of wild type strains. P chrysosporium Trametes sp. and Pleurotus sp was observed However the activities of ligninolytic enzymes were not detected in P chrysosporium cultures during degradation while ligninolytic enzymes were detected in both culture of Trametes sp. and Pleurotus sp. Therefore our results showed that PAHs was degraded under ligninolytic as well as nonligninolytic conditions. The results also indicate that lignin peroxidase(LiP) mananese peroxidase(MnP) and laccase are not essential for the biodegradation of PAHs by white rot fungi.

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Analysis of VolatHe Flavour Components in Aromatic Rices using Electronic Nose System (전자코 시스템에 의한 향미의 방향미 성분 분석)

  • 문형인;이재학;이동진
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.6
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    • pp.672-677
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    • 1996
  • Volatile flavour components rates from aromatic rices were analyzed by Electronic nose systems. In functional group, polar compounds and aldehyde compounds showed much of volatile flavour components than apolar compounds, sulphur compounds and aminated compounds. The profiles of volatile flavour components rates were markedly differents of sen-sing times, amylose content.

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디젤 오염토양에서 화학적 산화에 의한 PAH 분해특성 및 PAH 분해미생물의 거동

  • 정해룡;안영희;김인수;최희철
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.22-25
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    • 2002
  • The effect of in-situ chemical oxidation on the indigenous soil microorganisms (total microbes and PAH-degrading microbes) and contaminant removal were investigated. Field soil contaminated with diesel in gas station was collected and the soil was treated from 0 to 900 minutes by in-situ ozonation as chemical remediation. The treated soil samples were incubated with supplying oxygen during the 9 weeks to understand the characteristics of microbes regrowth, damaged by ozone. The sharp decrease of aromatic fraction and TPH was observed within 60 minutes of ozone application and aromatic fraction and TPH then slowly decreased. The phenanthren-degrading bacteria were the most sensitive to ozonation, because 1 hour of ozonation reduced the microbes from 10$^{6}$ CFU/g-soil to below detection limits.

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Cellular Responses of Pseundomonas sp. KKI to Two-Ring Polycyclic Aromatic Hydrocarbon, Naphthalene

  • Kahng, Hyung-Yeel
    • Journal of Microbiology
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    • v.40 no.1
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    • pp.38-42
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    • 2002
  • The strain KKI isolated from soil contaminated with polycyclic aromatic hydrocarbons was identified as Pseundomonas sp. based on analyses by MIDI and Biolog Identification System. Cellular and physiological responses of strain KKI to two-ring polycyclic aromatic hydrocarbon, naphthalene were evaluated using radiorespirometry, PLFAs and sequence analysis of Rieske-type iron sulfur center of dioxygenase. KKI was found to be able to rapidly mineralize naphthalene. Notably, KKI cells pregrown on phenanthrene were able to mineralize naphthalene much more rapidly than naphthalenepregrown cells. The total cellular fatty acids of KKI were comprised of eleven C-even and two C-odd fatty acids (fatty acids < 0.2% in abundance were not considered in this calculation). Lipids 12:0 2OH, 12:03 OH, 16:0, 18:1 6c, 18:0 increased for naphthalene-exposed cells, while lipids 18:1 7c1/15:0 ism 2OH, 17:0 cyclo, 18:1 7c, 19:0 cyclo decreased. Data from Northern hybridization using a naphthalene dixoygenase gene fragment cloned out from KKI as a probe provided the information that naphthalene dioxygenase gene was more highly expressed in cells grown on phenanthrene than naphthalene.

Antimicrobial Activities of Volatile Essential Oils from Korean Aromatic Plants

  • Shin, Kuk-Hyun;Chi, Hyung-Joon;Lim, Soon-Sung;Cho, Seon-Haeng;Moon, Hyung-In;Yu, Jae-Hyeun
    • Natural Product Sciences
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    • v.3 no.2
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    • pp.141-147
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    • 1997
  • Volatile essential oils obtained by steam distillation from 55 plant parts of 42 species of representative aromatic plants newly collected in Korean peninsula have been evaluated for antimicrobial activity against 5 microorganisms. The essential oils derived from 15 plant parts and 9 plant parts were found to exhibit very strong antimicrobial activities by more than 95% inhibition at 100 ${\mu}g/ml$ against Staphylococcus aureus and Pseudomonas aeruginosa, respectively. Essential oil components such as l-limonene, ${\beta}-myrcene$, linalool, ${\gamma}-terpinene$, ${\alpha},{\beta}-phellandrene$, 1,8-cineole, l-borneol and bornylacetate, as a whole, have primarily contributed to the manifestation of the antimicrobial activity.

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A Study on the Smoldering Zone Spread of the Heaped Saw-Dust (퇴적 목분의 훈소층 전파에 관한 연구)

  • 정국삼;강민호
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.90-96
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    • 1997
  • This paper was concerned with temperature aspect in the smoldering time of the accumulated each saw-dust sample of larch, oregon, aromatic trees which was formed with heaped cone-shape. The smoldering time and temperature of each sample was measured under the wind velocity of 0.10~0.15 m/s and circumstance relative humidity of 60%. As a result, the very lowest heat beginning temperature was detected in aromatic. The effective smoldering phenomena in the sample were detected when the larch saw-dust of [-20+40mesh] and the aromatic saw-dust of [-40+50mesh, -50+60mesh]. Finally the larger a particle size of saw-dust was the better a smoldering time was short. Also, it showed more increasing temperature above $70^{\circ}C$in the smoldering reaction.

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Biodegradation of Aromatic Compounds from Soil by Drum Bioreactor System

  • Woo, Seung-Han;Park, Jong-Moon
    • Journal of Microbiology and Biotechnology
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    • v.14 no.3
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    • pp.435-441
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    • 2004
  • A drum bioreactor was used for the treatment of sandy soil contaminated with three kinds of aromatic compounds (phenol, naphthalene, and phenanthrene), and its performance was evaluated in two different operation modes; intermittent and continuous rotation of drum. When the drum bioreactor was operated with one rotation per day, the microbial growth was relatively low, and most of the compounds remaining in soil, except naphthalene of 90 mg/kg dry soil, disappeared mainly due to volatilization. In contrast, when the drum was continuously rotated at 9 rpm (rotation/min), the number of microorganisms was drastically increased and nitrate was consumed for growth as a nitrogen source. Phenol and phenanthrene were removed at rates of 56.7 mg/kg dry soil/day and 3.2 mg/kg dry soil/day, respectively.