• Title/Summary/Keyword: anodic polarization behavior

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Anodic Polarization Properties of Ti-Zr-Pd Based Alloys for Biomedical Applications (생체용 Ti-Zr-Pd계 합금의 양극분극특성)

  • Jung, Jong-Hyun
    • Journal of Technologic Dentistry
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    • v.23 no.1
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    • pp.21-30
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    • 2001
  • For biomedical applications. Ti-X%Zr-Y%Pd(X: $10{\sim}20$, Y:0.2 or 0.4) based alloys not containing harmful Al and V were newly designed, and polarization curves for their alloys were measured at $37^{\circ}C$ in 5% HCl solution in order to understand effects of Zr on the corrosion. From the results of anodic polarization behavior, it was found that the corrosion resistance increased with increasing Zr content. The results show their potential to develope Ti-based alloys for biomedical materials. The Ti-20%Zr-0.2%Pd alloy shows excellent corrosion resistance and was superior to those of the Ti. Ti-6%Al-4%V ELI alloy, Co-30%Cr-6%Mo alloy and STS 316L stainless steel.

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Anodic Polarization Characteristics in Ti-20%Zr(-5%Cr) Alloys for Dental Castings (치과주조용 Ti-20%Zr(-5%Cr)합금의 양극분극특성)

  • Jung, Jong-Hyun;Han, Sok-Yoon
    • Journal of Technologic Dentistry
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    • v.26 no.1
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    • pp.41-48
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    • 2004
  • Ti-20%Zr(-5%Cr) alloys not containing harmful Al and V were newly designed in order to reveal their possibility for dental casting and melted in an arc melting and casting furnace under Ar atmosphere. The corrosion resistance was studied by anodic polarization test. From the observation of anodic polarization behavior, it was found that the corrosion resistance was markedly increased by the addition of Cr. The corrosion resistance of Ti-20%Zr-5%Cr alloy was superior to that in Ti-6%Al-4%V alloy but almost similar to that in CP Ti using in market place today.

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The Study on the Behavior of Polarization curve of Reinforcement with Oxidation Layer (산화피막이 있는 철근의 분극곡선의 거동에 대한 연구)

  • 한정섭
    • Journal of Ocean Engineering and Technology
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    • v.14 no.1
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    • pp.60-66
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    • 2000
  • In order to study for corrosion behavior of reinforcing steel with oxidation layer. Experiments were done with various NaCl concentrations and with immersion time in simulated concrete pore solution(SPS) the characteristics of corrosion behavior were measured by polarization resistance method and cyclic potentiodynamic method. reinforcements were coated by epoxy except corrosion without oxidation layer and it also showed two anodic-nose. by the result of potention dynamic test the potential curve shift to low with time and anodic-nose was appeared with 3% NaCl solution after 15 days. By result of cyclic Potentiodynamic test the type of corrosion was different accoding to concentration.

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Electrochemical Properties of Austenitic Stainless Steel with Initial Delay Time and Surface Roughness in Electropolishing Solution (전해연마 용액에서 안정화 시간과 표면 거칠기에 따른 오스테나이트 스테인리스강의 전기화학적 특성)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.158-169
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    • 2022
  • The objective of this study was to investigate the electrochemical behavior and damage degree of metal surface under different conditions by performing a potentiodynamic polarization experiment using an electropolishing solution for UNS S31603 based on initial delay time and surface roughness (parameters). A second anodic peak occurred at initial delay time of 0s and 100s. However, it was not discovered at 1000s and 3600s. This research referred to an increase in current density due to hydrogen oxidation reaction among various hypotheses for the second anodic peak. After the experiment, both critical current density and corrosion current density decreased when the initial delay time (immersion time) was longer. As a result of surface analysis, characteristics of the potentiodynamic polarization behavior were similar with roughness, although the degree of damage was clearly different. With an increase in surface roughness value, the degree of surface damage was precisely observed. As such, electrochemical properties were different according to the immersion time in the electropolishing solution. To select electropolishing conditions such as applied current density, voltage, and immersion time, 1000s for initial delay time on the potentiodynamic polarization behavior was the most appropriate in this experiment.

Characteristics on Corrosion Resistance of Medium High Carbon Low Alloy Steels using Plasma Nitriding Process (플라즈마 질화처리한 중, 고탄소저합금강의 내식성에 관한 연구)

  • 이병찬
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.5
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    • pp.702-711
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    • 1998
  • The characteristics of corrosion resistance for the surface of medium high carbon steels and low alloy steels utilizing as manufacturing the machinery structures and machining tools and treating by plasma/ion nitriding process have been studied in terms of electrochemical polarization behav-iors including corrosion potential(Ecorr) anodic polarization trends and polarization resistance(Rp) The seven base materials showed a clear passivation behavior for the polarization tests in the ASTM standard solution 1N ${H_2){SO_4}$ Although the treated surface by plasma nitriding for the seven test materials showed a significant increase in hardness the treatment gave a detri-mental effect in corrosion resistance. The various characteristics including corrosion potential polarization curves microstructures corrosion current polarization resistance among non-treat-ed nitriding and/or soft-nitriding treated specimens have been investigated and some of the mechanisms discussed.

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Corrosion Tests for High Chromium Cast Iron Using Galvanostatic Polarization Technique in a Simulating Slurry Solution (모사 슬러리 용액에서 정전류 분극을 활용한 고크롬 주철 부식 시험)

  • Ochgerel Baasanjav;Jun-Seob Lee;Ye-Jin Lee;Jun-Seok Oh;Je-hyun Lee
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.252-256
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    • 2023
  • The galvanostatic polarization technique was used to accelerate corrosion in high chromium cast iron (HCCI) immersed in a simulated slurry solution of 0.1 mol dm-3 H2SO4, 0.05 mol dm-3 HCl, and 10 wt% SiC. The HCCI contained 27 wt% of Cr and 2.8 wt% of C, and its microstructure mainly comprised austenitic and carbide phases. A two-electrode system using a dense carbon rod and the HCCI sample was employed for the galvanostatic polarization by applying an anodic current for 24 hours. The corrosion rate increased upon applying the anodic current, but the increase was not significant, particularly for current densities higher than 10 µA cm-2. Following polarization, the corrosion morphology revealed that the anodic current accelerated surface corrosion in the HCCI; however while the depth of the corroded area increased, the increase was not substantial. The propagation behavior of the anodic current and its impact on corrosion were further discussed.

The Study on the Corrosion Characteristics of Al-Alloy Shell for Cooler (알루미늄합금 원통냉각기의 부식 특성에 관한 연구)

  • 임우조;김성진;윤병두
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.39 no.2
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    • pp.152-157
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    • 2003
  • Most Recently, with rapid development in marine industries such as marine structures and ship, there occurs much interest in the study of corrosion characteristics which play an important role in design of cooling water system like heat-exchanger. Especially, as operating environment of fresh cooling water system in vessels is acidified, this system is seriously corroded. In this study, to study on the corrosion characteristics of Al-alloy shell for cooler, the electrochemical polarization test of materials for the marine fresh water cooler such as Al-alloy, Cu and naval brass was carried out in fresh water. And thus the polarization resistance and anodic polarization behavior of Al-alloy, Cu and naval brass are investigated. Also, galvanic corrosion characteristics of Al-alloy coupled with Cu and naval brass is considered. The main results obtained are as follows ; (1) The current density of corrosion is high in order of Al-alloy > naval brass > Cu (2) As anodic potential increases, the corrosion resistance of naval brass is better than that of Cu. (3) The galvanic corrosion of Al-alloy coupled with Cu and naval brass is activated than corrosion of Al-alloy.

The Effect on the Wear-Corrosion Behavior of Ductile Cast Iron in the Various pH Environments (구상흑연주철재의 마멸-부식특성에 미치는 pH의 영향)

  • 임우조;박동기
    • Tribology and Lubricants
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    • v.19 no.1
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    • pp.31-35
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    • 2003
  • This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the various pH environments. In the variety of pH solutions, corrosion and wear-corrosion loss of GCD 600 were investigated. Also, the anodic polarization test of GCD 600 using potentiostat/galvanostat was carried out. And rubbed surface of GCD 60 using scanning electron micrographs after immersion and wear-corrosion test was examined in the environment of various pH values. The main results are as following In alkali zone, the wear-corrosion loss of GCD 600 increases, but corrosion loss decreases. The unevenness and crack of wear-corrosion surface in neutral zone becomes duller than that in alkali zone. As the corrosive environment is acidified, wear-corrosion behavior of GCD 600 with passing immersion time becomes sensitive.

Study on the Damage Behavior of 304 Stainless Steel for Gas Boiler with Specific Resistance (비저항에 따른 가스보일러용 304스테인리스강재의 손상거동에 관한 연구)

  • Yun, Byoung-Du;Lim, Uh-Joh;Jeong, Ki-Cheol
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.6-10
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    • 2005
  • This paper was studied on the damage behavior of stainless steel (STS 304) for gas boiler with specific resistance. The electrochemical polarization test of STS304 for gas boiler was carried out. And the anodic polarization and damage aspect, such as pitting corrosion, was considered. With being low specific resistance, the passive current density of STS 304 increases, passive region and pitting potential is low. Also, the patting aspect of STS304 In specific resistance $74{\Omega}{\cdot}m$ water little appears, the pitting number increases and the damage behavior, such as pitting aspect, gradually grow bigger with being low specific resistance.

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CORROSION CHARACTERISTICS BETWEEN IMPLANT FIXTURE AND ABUTMENT SCREW (임플랜트 고정체와 지대나사간의 부식특성에 관한 연구)

  • Kee, Su-Jin;Kweon, Hyeog-Sin;Choe, Han-Cheol
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.1
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    • pp.85-97
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    • 2000
  • The purpose of this study was to compare the corrosion characteristics between implant fixture and two types of abutment screw ; gold screw, titanium screw. The anodic polarization behavior, the galvanic corrosion behavior, and the crevice corrosion behavior of prepared samples were investigated using potentiostat and scanning electron microscope. The results were as follows: 1. Anodic polarization behavior of samples; The primary passivation potential of implant fixture was -420mV, implant abutment was -560mV. titanium screw was -370mV and gold screw was -230mV. All samples were shown to have a high corrosion potential and good formation of passive film. The critical passive current density of gold screw was higher than that of other samples and the sample of gold screw showed a unstable passive film formation at passive region. 2. Galvanic corrosion behavior of samples; Contact current density between implant fixture and titanium screw showed $8.023{\times}10^{-5}C/cm^2$. Contact current density between implant fixture and gold screw showed $5.142{\times}10^{-5}C/cm^2$. 3. Crevice corrosion behavior of samples; The crevice corrosion resistance of sample using titanium screw was higher than that of sample using gold screw, and a severe corrosion morphologies were observed at the fixture-screw interface by the scanning electron microscope.

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