• Title/Summary/Keyword: and passivity

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Effects of Environmental Variables on Hydrogen Generation from Alkaline Solutions using used Aluminum Cans (알칼리 용액에서 알루미늄 재활용 캔을 이용한 수소생산에 미치는 환경 인자의 영향)

  • Yun, Kwi-Sub;Park, Chan-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.1
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    • pp.29-34
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    • 2011
  • This study examined the effect of environmental variables, such as the NaOH concentration and solution temperature, on the rate of hydrogen generation from NaOH solutions through the corrosion of used aluminum cans as a potential candidate material for the safe and economic production of hydrogen. Corrosion of the used aluminum cans was promoted by increasing the NaOH concentration and solution temperature because of the loss of aluminum passivity. The measured rate of hydrogen generation from the NaOH solutions increased with increasing NaOH concentration due to the catalytic activity of NaOH in the hydrolysis process. However, at higher solution temperatures, the rate of hydrogen generation rate was less affected by the NaOH concentration than that at lower temperature.

Inhibition of Rebar Corrosion by Carbonate and Molybdate Anions

  • Tan, Y.T.;Wijesinghe, S.L.;Blackwood, D.J.
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.167-174
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    • 2017
  • Bicarbonate/carbonate and molybdate anions have been characterized for their inhibitive effect on pitting corrosion of carbon steel in simulated concrete pore solution by using electrochemical tests such as electrochemical impedance (EIS) and linear polarization (LP). It was revealed that bicarbonate/carbonate has a weak inhibitive effect on pitting corrosion that is approximately one order of magnitude lower compared to hydroxide. Molybdate is effective against pitting corrosion induced by the concentration of chloride as low as 113 mM and can increase the pitting potential of a previously pitted sample to the oxygen evolution potential by the concentration of molybdate as much as 14.6 mM only. The formation of a $CaMoO_4$ film on the surface hinders the reduction of dissolved oxygen on the steel surface, reducing corrosion potential and increasing the safety margin between corrosion potential and pitting potential further. In addition, pore-plugging by $FeMoO_4$ as a type of salt film within pits increases the likelihood of repassivation.

A Study on the 'Activity' in Spinoza and Toegye (스피노자와 퇴계의 '능동성'-논고)

  • Sung, Hoe-kyung
    • Journal of Korean Philosophical Society
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    • v.137
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    • pp.225-247
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    • 2016
  • This research examines the philosophy of Toegye and Spinoza in the postneo-Confucian and post-modern perspective in emphasizing the activity of Ri(理) and reason beyond the similarities of system in their thought. There is no disagreement in viewing Toegye and Spinoza as balanced opposites in their attempts to harmonize man and nature. In this discussion, I will infer the similarities of Toegye and Spinoza in terms of an 'activity-passivity' thesis.

Effects of Alloyed Carbon on the General Corrosion and the Pitting Corrosion Behavior of FeCrMnN Stainless Steels (FeCrMnN 계 스테인리스강의 일반부식 및 공식부식 거동에 미치는 고용 탄소의 영향)

  • Ha, Heon-Young;Lee, Tae-Ho;Kim, Sung-Joon
    • Korean Journal of Metals and Materials
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    • v.49 no.10
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    • pp.780-789
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    • 2011
  • The effects of alloyed carbon on the pitting corrosion, the general corrosion, and the passivity behavior of Fe18Cr10Mn0.4NxC (x=0~0.38 wt%) alloys were investigated by various electrochemical methods and XPS analysis. The alloyed carbon increased the general corrosion resistance of the FeCrMnN matrix. Carbon enhanced the corrosion potential, reduced the metal dissolution rate, and accelerated the hydrogen evolution reaction rate in various acidic solutions. In addition, carbon promoted the pitting corrosion resistance of the matrix in a chloride solution. The alloyed carbon in the matrix increased the chromium content in the passive film, and thus the passive film became more protective.

A Survey of Haptic Control Technology (햅틱 제어 기술 동향)

  • Ryu, Je-Ha;Kim, Jae-Ha;Seo, Chang-Hoon;Lim, Yo-An;Kim, Jong-Phil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.283-295
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    • 2009
  • Haptics technology allows one to interact with virtual environments, augmented environments, and real environments providing tactual sensory information. Science and technology of haptics can in general be classified into three groups: machine haptics, computer haptics, and human haptics. This paper surveys the state-of-the-art of haptic control technology for virtual environments and teleoperation (real environments) and then proposes possible future research directions in the following areas: haptic stability control, bilateral teleoperation control, and stability enhancement control.

The Performance of Cathodic Protection with ICCP

  • Oh, Jin-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.8
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    • pp.1286-1290
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    • 2004
  • This paper describes the anti-corrosion system on underwater structures of ships. Metals and alloys have several positions in the series such as immunity, corrosion and passivity. The iron potential has to change from the corrosion position to the anodic protection or cathodic protection for preventing corrosion by providing corrosion protection system such as ICCP(Impressed Current Cathodic Protection). The purpose of ICCP system is to eliminate the rusting or corrosion, which occurs on metal immersed in water. The system includes a power supply unit, which consists of a transformer, a converter. a controller, etc. This paper presents the protection performance of ICCP under dynamic condition such as velocity. The variation of potential and current density with time and environment factors are also described Finally, the experimental results will be explained and analysed.

Ellipso-Microscopic Observation of Titanium Surface under UV-Light Irradiation

  • Fushimi, K.;Kurauchi, K.;Nakanishi, T.;Hasegawa, Y.;Ueda, M.;Ohtsuka, T.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.265-270
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    • 2016
  • The ellipso-microscopic observation of a titanium surface undergoing anodization in $0.05mol\;dm^{-3}$ of $H_2SO_4$ was conducted. During irradiation by ultra-violet (UV) light with a wavelength of 325 nm, the titanium surface allowed for the flow of a photo-induced current and showed up as a bright, patch-like image on an ellipso-microscopic view. The brightness and patch-pattern in the image changed with flowing photo-induced current. The changes in the brightness and the image corresponded to the formation and/or degradation of titanium oxide due to the photo-electrochemical reaction of the oxide. An in situ monitoring using the ellipso-microscope revealed that the film change was dependent on the irradiation light power, by UV-light increases the anodic current and results in the initiation of pitting at lower potentials as compared with the non-irradiated condition.

Effect of Al content on coating adhesion of hot rolled galvanized iron manufactured without pickling process (무산세 열연 용융아연도금강판의 도금밀착성에 미치는 도금욕 Al농도의 영향)

  • 전선호;최진원
    • Journal of the Korean institute of surface engineering
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    • v.32 no.1
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    • pp.31-42
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    • 1999
  • The effect was investigated that aluminium in the zinc bath has on the coating adhesion of Hot-rolled Galvanized Iron(HGI) manufactured without pickling process. It is thought that the coating adhesion of HGI manufactured without pickling process is good due to the fact that increasing aluminium content in the zinc bath makes zinc and aluminium diffuse to the cracks or pores in the scale formed through the reduction heat treatment, and Fe-Zn-Al compound with good ductility is formed in the scale layer and plays a role of anchor between zinc coating and substrate. It is possible that HGI with the good coating adhesion was produced without pickling treatment in the zinc bath with more that 3wt% of Al content even at the $550^{\circ}C$ of conventional reduction heating temperature. In creasing the temperature of heating section and aluminium content in the zinc bath prevents the Zn-Fe alloy. The corrosion resistance of HGI manufactured without pickling process is excellent because of the mixed reaction of zinc sacrifice and aluminium passivity film.

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Effects of Time and Current Density in Anodizing of Mg-Al Alloy in Alkaline Solution (알카리 수용액에서 Mg-Al 합금의 양극산화시 전류밀도와 양극산화 시간의 효과)

  • Jang Seok-Ki;Kim Seong-Jong;Kim Jeong-Il
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.1
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    • pp.107-115
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    • 2005
  • The effects on the formation of anodic oxide films on Mg-Al alloy (AZ91) in 1M-NaOH solution was investigated using parameters of current density and time during anodizing The general tendency has been confirmed that the increase of anodizing time improves the corrosion resistance. It is considered that the formation of anodic oxide film was increased by increasing the applied current and the anodizing time to generate active dissolution reaction In anodizing at constant current density. passivity potentials shifted to noble direction with increasing current densities. It was confirmed that oxygen quantify in anodic oxide films increased with anodizing time. The compact films above 4 $mA/cm^2$ were formed with the shape of an island in grooves at early stage and then grew with combination of the islands

Passivity Bilateral Teleoperatio System with Time Delay (시간 지연을 가지는 수동성 양방향 텔레오퍼레이션 시스템)

  • Zhang, Changlei;Chong, Kil-To
    • Proceedings of the KIEE Conference
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    • 2006.10c
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    • pp.333-335
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    • 2006
  • This paper presents a force-reflecting teleoperation scheme with time delay. In reciprocal systems, to improve the stability and performance of the tleleoperation system, the network provides a wide bandwidth, no congestion. However, as use of Internet increases, congestion situation of network increased and transmission time and packet loss increased accordingly. This can make system unstable at remote control. In this paper, we present a passive control scheme for a force reflecting bilateral teleoperation system via the Internet and we investigated how a varying time delay affects the stability of a teleoperation system. A new approach based on a passive control scheme was designed for the system. The simulation results and the tracking performance of the implemented system are presented in this paper.

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