• 동력기계공학회지
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• 제17권1호
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• pp.71-76
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• 2013

This study is experimentally performed for using the oyster shell as a desiccant in the batch type system. The peltier element(thermoelectric device) is used for absorbing and releasing the adsorption and desorption heat generation. The cooling and heating effects of peltier element exist in this experiment and these effects are generally known phenomena among some references. The increase in electric current induced into peltier element is effectively release the heat generation of adsorption and desorption. Consequently, the non-dimensional adsorption and desorption amount would increase with increase in electric current. However, in the case of adsorption, the increase of induced current into peltier element, the heat of cold side can not release sufficiently. So the heat of hot side of peltier is transferred into the cold side.

• 한국응용과학기술학회지
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• 제23권4호
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• pp.280-289
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• 2006

Multilayer adsorptions and BET adsorption are analyzed statistical-mechanically. Which ensemble is selected for the analysis is unimportant, because each ensemble yields the same results. However, the amount of mathematical manipulations and the matter of convenience vary from ensemble to ensemble. Hence, multilayer adsorptions and BET adsorption are examined using a canonical and a grand canonical ensembles, and an ensemble of subsystems. Also, the characteristics of multilayer and BET adsorptions are delineated.

• 대한환경공학회지
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• 제39권1호
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• pp.19-25
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• 2017

본 연구에서는 도로환경에 적용 가능한 통기성 정전필터를 개발하여 흡착능을 평가하였다. 흡착특성은 ASHRAE 52.1, 52.2 등의 방법으로 입경별 제거율과 압력별 흡착량 등을 평가하였다. 평가 입경범위는 $0.3{\mu}m{\sim}10.0{\mu}m$로 12단계로 제거율을 평가하였다. 필터는 $2.5{\mu}m$ 이상에서 91.3%의 제거율을 보였으며 그 미만의 범위에서는 입경에 따라 감소하여 평균 53.5%의 제거율을 보였다. ASHRAE Dust 합성 분진에 의한 중량 제거율은 초기압력 22.6 mmaq에서 말기압력 35 mmaq까지 측정된 결과, 96.7%였으며 이때까지 흡착량은 $715.9g/m^2$ 이었다. 압력에 따른 흡착형태는 Langmuir 선도를 보였다. 말기압력까지 흡착된 필터를 물세정으로 1, 2차 재생한 후 흡착을 평가한 결과 제거효율에는 차이가 없었으나 초기압력과 흡착량은 약간의 저하가 발생하였다.

• 한국환경농학회지
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• 제26권4호
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• pp.286-296
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• 2007

To increase phosphate (P) availability in soils, the efficiency of silicate (Si) in reducing P adsorption was investigated by competitive adsorption tests under changing conditions of pH, ion concentrations, and order of anion addition along with single adsorption properties of each ion at $20^{\circ}C$. In the single ion adsorption study, P and Si ions showed the opposite reaction patterns: phosphate adsorption decreased with increasing pH and attained adsorption maximum however, silicate adsorption increased with increasing pH without attaining adsorption maximum. Phosphorus and Si adsorption were influenced by pH in the range of 5.0 - 9.0 and the type and amount of P and Si concentration. Silicate added to soil before P or in a mixture with P significantly reduced P adsorption above pH 7.0; however, there was no significant Si-induced decreased in P adsorption at pH 5.0 when anions were added as mixture. The efficiency of Si in reducing P adsorption increased with increasing Si concentration and pH. The effect of P on Si adsorption was relatively small at pH 5.0 and no effect of P on silicate adsorption was observed at pH 9.0. The presence of Si strongly depressed P adsorption when Si was added before P compared to P and Si added as a mixture. These results suggest that application of Si may decrease P adsorption and increase the availability of P in soils. Furthermore, a Si source would be better to add before P application to enhance the availability of P in soils.

• 상하수도학회지
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• 제14권1호
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• pp.76-83
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• 2000

This research is about wastewater containing non-biodegradable TDI(Toluene Diisocyanate) that is treated by the activated carbon adsorption method. In the case of the Fenton oxidation process being applied to the existing process, optimal pH, reaction time, chemical dosing amount, removal rate, and cost were investigated. A pilot plant test was applied after finding optimal conditions with lab experiments. The optimal conditions were pH 3~5(COD removal rate 84~88%) and reaction time 30min~1hr. In higher $H_2O_2$ dosing amount, COD removal rate was a little higher. But there was little difference in the removal rate according to $FeSO_4{\cdot}7H_2O$ dosing amount. Treatment cost was economical in the case of the Fenton oxidation process being operated earlier than activated carbon adsorption system. But chemical dosing point, chemical mixing effect, chemical dosing amount, removal rate, and the cost of facility and others must be considered in practical process.

• 대한화학회지
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• 제62권1호
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• pp.30-35
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• 2018

인공수정체로 사용되고 있는 소수성 아크릴 하이드로겔의 단백질 흡착 감소와 기능을 향상시키기 위한 하이드로겔을 제조하여 인공수정체로의 응용성을 살펴보고자 한다. 소수성 아크릴 인공수정체는 ethyleneglycol phenyletheracrylate(EGPEA), Styrene, 2-hydroxyethyl methacrylate(HEMA)를 사용하여 제작하였고 첨가제로 polyvinyl pyrrolidone(PVP)와 2-methacryloyloxyethyl phosphorylcholine(MPC)를 사용하였다. 인공수정체의 물리적 특성을 평가하기 위해 함수율, 습윤성, 광투과율 및 단백질 흡착량을 측정하였다. 첨가제를 넣은 모든 시료의 함수율과 습윤성은 증가하였고 단백질 흡착량은 감소하였다. 특히 MPC가 포함된 시료의 단백질 흡착량은 더욱 감소하였다. PVP와 MPC를 첨가한 소수성 아크릴 하이드로겔은 기본적인 물리적 특성을 가지면서 단백질 흡착을 감소시킴으로써 기능이 향상된 인공수정체로의 응용이 가능하다는 것을 확인하였다.

• 대한의용생체공학회:의공학회지
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• 제14권3호
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• pp.209-220
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• 1993

Microspheres are expected to be applied to biomedical areas such as solid-phase immunoassays, drug delivery systems, Immunomagnetic cell separation. To synthesize micro-spheres for biomedical application, "two stage shot growth method" was developed. The uniformity ratio or synthesized microspheres was always smatter than 1.05. And the surface charge density (or the number of ionizable functional groups) of the microspheres synthesized by "two stage shot growth method" was 6-13 times higher than thats of the ml crospheres synthesized by conventional seeded batch copolymerization. As a previous step for biomedical application, adsorption experiments of bovine albumin on microspheres were carried out under various conditions. The maximum adsorbed amount was obtained in the neighborhood of pH 4.5. Isoelectric point of bovine albumin Is pH 5.0, so experimental result shows that it shifted to acid area. The adsorption Isotherm was obtained, the plateau region was always reached at 2.Og/L (bulk concentration of bovine albumin ) . The effect of the kind and the amount of surface functional group was also examined.p was also examined.

• 한국잠사곤충학회지
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• 제27권1호
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• pp.42-46
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• 1985

반응성 염료의 하나인 vinylsulfone계 염료로 견섬유에 날염하여 증열시간, 호료의 점도, 알카리 농도에 의한 염료량 및 고착량의 변화를 측정하여 반응성 염료의 견에 대한 날염 특성을 검토하고 연구한 결과를 다음과 같이 요약한다. 1) 증열 시간과 더불어 염착량 및 고착량은 증가하였으며 염착량과 고착량은 비례관계를 나타내고 있다. 2) 고착율은 80% 이상으로 높은 고착율을 나타내고 있다. 3) 호료의 점도에 따라 염착량과 고착량이 달라지며 적당한 점도가 요구됨을 시사한다. 4) 알카리 농도는 염착량과 고착량의 변화에 큰 영향을 주는 요인이었으며 적당량의 알카리 첨가가 필요함을 나타낸다. 5) 세탁 견뢰도와 일광 견뢰도가 뛰어났으며 실용상 매우 우수한 염료임이 입증되었다. vinylsulfone계 염료는 우수한 발염성과 견뢰도를 가지고 있어서 견질물의 염색분야에 충분한 응용을 기할 수 있다.

• 한국물환경학회지
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• 제23권2호
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• pp.222-227
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• 2007

The adsorption features of fluoride ion on the oyster shell have been investigated for the purpose of the employment of waste oyster shell as an adsorbent for the treatment of fluoride ion-containing wastewater. The major component of oyster shell was examined to be Ca with minor components of Na, Si, Mg, Al, and Fe. As the initial concentration of fluoride ion was raised, its absorbed amount was enhanced at equilibrium, however, the adsorption ratio of fluoride ion compared with its initial concentration was shown to be decreased. Also, adsorption of fluoride ion onto the oyster shell resulted in the formation of $CaF_2$ in the morphological structure of adsorbent. Kinetic analysis showed that the adsorption reaction of fluoride ion generally followed a second order reaction with decreasing rate constant with the initial concentration of adsorbate. Freundlich model agreed well with the adsorption behavior of fluoride ion at equilibrium and the adsorption reaction of fluoride ion was examined to be endothermic. Several thermodynamic parameters for the adsorption reaction were calculated based on thermodynamic equations and the activation energy for the adsorption of fluoride ion onto oyster shell was estimated to be ca. 13.589 kJ/mole.

• 한국세라믹학회지
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• 제37권3호
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• pp.280-287
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• 2000

Adsorption behavior and amount of phenolic resin followed silica (SiO2) formation onto silicon nitride(Si3N4) surface were investigated using electrokinetic sonic amplitude (ESA) technique and with UV spectrometer, to fabricate Si3N4/SiC nano-composite based on reaction between SiO2 formed and phenolic resin absorbed onto Si3N4 particle. The amount of SiO2 formed and carbon from phenolic resin absorbed onto Si3N4 surface were calculated quantitatively to adjust the reaction between SiO2 and phenolic resin, resulting in no residual SiO2 and carbon. As a result, pre-heated tempeature for optimized reaction was below 25$0^{\circ}C$, in which there was no residual SiO2 and carbon.