• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.649-658
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• 2012

In this study, the influencing factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater removal were investigated by testing biochemical methane potential test. In the influencing factors, the trace metals which could increase activity of anaerobic microorganisms, microbial concentration and types were evaluated. In the results, trace metals supplementation showed gas production amount higher than those without addition of trace metals. Among the tested trace metals, B, Ni, and Se were preferable to gas production. In the result of gas production according to the microbial concentration, the amount of gas production was proportional to the microbial concentration. In addition, the shortest lag time and the fastest gas production rate were achieved when the highest microbial concentration was tested. granule-type microorganism produced more gas than suspended-type microorganism. In conclusion, the efficient anaerobic digestion for high strength ammonia-nitrogen wastewater removal could be achieved by applying necessary trace metals injection and high concentration granule type microorganism.

• Bulletin of the Korean Chemical Society
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• v.30 no.9
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• pp.2032-2038
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• 2009

The amount of phenol and NaOH for the colorimetric determination of ammonia in Korean standard methods (KSM) is found to be highly excessive compared to the standard methods of several other countries. The absorbance of indophenol formed by the Berthelot reaction for ammonia analysis was measured under the various reaction conditions classified in experiment groups 1, 2, 3, 4 and KSM and American standards methods (ASM), and the relationships between the absorbance of indophenol and concentration of ammonia were compared. The amount of phenol can be reduced to 10 g (current 25 g in KSM) and NaOH can be reduced to 1.76 g (current 11 g in KSM) for the preparation of 200 mL phenate solution, and the absorbance sensitivity increased. The concentration of the phenol and NaOH correlatively affect the pH of the solution, which is a critical variable in achieving the maximum sensitivity and rapid and stable color development.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.3
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• pp.75-80
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• 2019

The article is devoted to the interpretation of ammonia, one of the fine dust precursors, absorption behavior in water turbulent flow. The water flow was considered as a turbulent flow with Reynolds number more than $10^4$, because ammonia gas penetration depth was deeper at turbulent flow compared to laminar flow. For the interpretation, the dimensionless mass transfer governing-equation and the constant physical-properties at room temperature were used. The diffusivity of ammonia in water and the kinematic viscosity of water were $2{\times}10^{-9}m^2/s$ and $1{\times}10^{-6}m^2/s$, respectively. The concentration distribution of ammonia in water was estimated with respect to the position from the point where the water started to be exposed to ammonia. The quantitative distribution as a function of the mixing length was also acquired. The quantitative interpretation may provide the insight how much the turbulent flow was more efficient to remove ammonia rather than the laminar flow.

• Journal of the Korean Society for Heat Treatment
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• v.32 no.5
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• pp.201-211
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• 2019

Low carbon steel (S20C steel) and SPCC steel sheet have been austenitic nitrided at $700^{\circ}C$ in a closed pit type furnace by changing the flow rate of ammonia gas and heat treating time. When the flow rate of ammonia gas was low, the concentration of residual ammonia appeared low and the hardness value of transformed surface layer was high. The depth of the surface layer, however, was shallow. With increasing the concentration of residual ammonia by raising up the ammonia gas flow, both the depth of the surface layer and the pore depth increased, while the maximum hardness of the surface layer decreased. By introducing a large amount of ammonia gas in a short time, a deep surface layer with minimal pores on the outermost surface was obtained. In this experiment, while maintaining 10~12% of residual ammonia, the flow rate of inlet ammonia gas, 7 liter/min, was introduced at $700^{\circ}C$ for 1 hour. In this condition, the thickness of the surface layer without pores appeared about $60{\mu}m$ in S20C steel and $30{\mu}m$ in SPCC steel plate. Injecting additional methane gas (carburizing gas) to this condition played a deteriorating effect due to promoting the formation of vertical pores in the surface layer. For $1^{st}$ transformed surface layer for S20C steel, maintaining 10~12% residual ammonia condition via austenitic nitriding process resulted in ${\varepsilon}$ phase with relatively high nitrogen concentration (just below 4.23 wt.%N) among the mixed phases of ${\varepsilon}+{\gamma}$. The ${\varepsilon}$ phase was formed a specific orientation perpendicular to the surface. For $2^{nd}$ transformed layer for S20C steel, ${\gamma}$ phase was rather dominant (just above 2.63 wt.%N). For SPCC steel sheet, there appeared three phases, ${\gamma}$, ${\alpha}(M)$ and weak ${\varepsilon}$ phase. The nitrogen concentration would be approximately 2.6 wt.% in these phases condition.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.4
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• pp.432-442
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• 2010

Ammonia is a very important constituent of the atmospheric environment because it is the most dominant gaseous alkaline species present in the atmosphere. Ammonia is known to affect ecosystems at relatively low concentration. Ammonia flux from livestock facilities can be regulated by a number of environmental factors (pH, ammonium ion, temperature, wind speed, etc). The increases in wind speed above manure from 0.0 m/s to 1.0 7m/s resulted in 2.5 times increases in ammonia flux. Wind speed and ammonia flux showed 0.982. A linear relationship with a correlation coefficient (r=0.982). When manure temperature increased from $3^{\circ}C$ to $36^{\circ}C$, the manure pH decreased approximately 0.30 to 0.46. As wind speed above the manure increased from 0.0 m/s to 1.07 m/s, ammonia flux increased approximately 2.5 times. The increasing manure temperature from $3^{\circ}C$ to $10^{\circ}C$, raised ammonia flux from 2.0 to 3.6 times (2.6 times in average similarly). The increases of manure temperature from $3^{\circ}C$ to $25^{\circ}C$ increased ammonia flux from 5.7 to 12.9 times (8.5 times in average). In this study, the correlation coefficient between ammonia flux and manure temperature was found from 0.972 to 0.989. Results of our research showed that ammonium ion concentration, pH of manure and wind speed were important factors in controlling the ammonia flux from manure livestock facilities.

• Journal of Electrochemical Science and Technology
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• v.13 no.1
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• pp.63-70
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• 2022

Compared with hydrogen, ammonia has the advantages of high gravimetric hydrogen densities (17.8 wt.%), ease of storage and transportation as a chemical hydrogen storage medium, while its application in small-scale on-site hydrogen production scenarios is limited by the need for complex separation equipment during high purity hydrogen production. Therefore, the study of PEMFC, which can directly utilize ammonia decomposition gas, can greatly expand the application of fuel cells. In this paper, the output characteristics, fuel efficiency and the variation trend of hydrogen concentration and local current density in the anode channel of fuel cell with the output voltage of PEMFC fueled by ammonia decomposition gas were studied by experiment and simulation. The results indicate that the maximum output power of the hybrid fuel decreases by 9.6% compared with that of the pure hydrogen fuel at the same inlet hydrogen equivalent. When the molar concentration of hydrogen in the anode channel is less than 0.12, the output characteristics of PEMFC will be seriously affected. Employing ammonia decomposition gas as fuel, the efficiency corresponding to the maximum output power of PEMFC is approximately 47%, which is 10% lower than the maximum efficiency of pure hydrogen.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.47 no.6
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• pp.840-846
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• 2014

This study investigated growth and hematological changes in parrotfish Oplegnathus fasciatus (~200 g/fish) reared under different total ammonia nitrogen (TAN) concentrations (0, 4, or 8 mg/L) for 6 weeks. Survival rates of parrotfish in all experimental groups did not significantly differ, as they were all ~100%. Although specific growth rate (SGR), weight gain, and daily feed intake in the high TAN concentration group (TAN8) were significantly lower than in the other two groups, there was no significant difference between the TAN4 group and the control group, (TAN0), indicating that parrotfish have a strong resistance to ammonia toxicity. As for temporal changes of the major blood components, cortisol increased as a result of stress caused by the high ammonia concentration in the TAN8 group. For this reason, the concentrations of energy sources such as glucose and total cholesterol were reduced. However, there was little difference among all experimental groups in concentrations of liver function glutamic oxaloacetic transaminase (GOT) and glutamic pyruvic transaminase (GPT), and nutrient factors, such as total protein and albumin.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.33 no.4
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• pp.367-372
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• 2000

A series of experiment was conducted to investigate the relationship between ammoia removal rate and ammonia loading rates in seawater filtering system using rotating biological contactor (RBC). In this experiment, RBC system was consisted of rotating polyvinyl film disks, which provided $12 m^2$ of total effective surface area in $0.075 m^3$ of volume. $NH_4Cl$ was added by $10{\~}150 g$ as a ammonia nitrogen source to determine ammonia removal rate in RBC system. Relationship between time required for ammonia removal (y: hour) and nitrogen inputted ($x: NH_4-N mg/l$) in RBC system was as followed: $y=3.51+7.76 lnx (r^2=0.936)$. At ammonia concentration $2 mg/l$, it took 10 hour for removal of ammonia in the RBC system. However, at ammonia concentration of $5 and 16.5 mg/l$, it took 16 and 27 hours, respectively. There was a decreasing tencency of an increasing ammonia in the rearing water. Finally, the ammonia removal rate in the RBC system increased with the rise of total ammonia concentration up to $16.5 mg/l$.

• Journal of Biosystems Engineering
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• v.28 no.3
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• pp.225-230
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• 2003

This study was carried out to analyze the environmental variation of layer house at Iowa State in the USA. The analyzed seasons for this study were summer and winter. Analyzing factors are inside temperature and relative humidity, carbon dioxide concentration, ammonia concentration and emission. All factors were collected every 30 second from each house with portable monitoring units. In this study, two types of laying hen houses were monitored at the same season. One was a manure belt house, the other was a high-rise house. In order to estimate the ventilation rates of the laying hen houses, carbon dioxide concentration balance was used in this study. Ammonia concentrations and emission rates of the manure belt house are much lower than those of the high rise house. Daily mean ammonia concentrations in the manure belt house and high-rise house ranged from 3 to 7 ppm and 5 to 34 ppm, respectively. The daily ammonia emission rates averaged 0.68g/h$\cdot$500kg and 0.73g/h$\cdot$500kg for the manure belt house and 0.93g/h$\cdot$500kg and 2.89g/h$\cdot$500kg for the high-rise house in summertime and wintertime, respectively. Summertime is associated with much higher ammonia emission rates than wintertime because of much higher ventilation rates and ambient air temperature, even though the concentrations may be lower.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.53-60
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• 2000

The effects of ammonia loading on nitrification, especially on nitrite build-up, in an activated carbon fluidized bed reactor were investigated by increasing the ammonia loading rate stepwise from 0.1 to $7.5kg\;NH_3-N/m^3{\cdot}day$. Although effluent nitrite concentration and nitrification efficiency fluctuated at the loading rates above $1.8kg\;NH_3-N/m^3{\cdot}day$, an average nitrification efficiency of 90% was achieved. Nitrite build-up began at an ammonia loading rate of $l.8kg\;NH_3-N/m^3{\cdot}day$, at which the free ammonia concentration was estimated to be above 1 mg/L. During the nitrite build-up, the ratio of influent $NH_3-N$ concentration to the DO concentration of the reactor liquor and the ratio of effluent $NH_3-N$ concentration to the DO concentration of the reactor liquor was measured to be above 100 and 2, respectively. Considering the advantages of nitritation/denitrification, a fluidized bed reactor could be an effective means for biological nitrification of wastewaters with high ammonia concentration.