• Title/Summary/Keyword: aluminum dust

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Proposals for Revising the Occupational Exposure Limits for Aluminum in Korea (국내 알루미늄 노출실태 및 노출기준 개정 제안)

  • Seung Won Kim;Young Gyu Phee;Yong-Joon Baek;Taejin Chung;Hye-Sil Lee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.34 no.1
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    • pp.85-97
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    • 2024
  • Objectives: This study was intended to investigate the revision status of the occupational exposure standards for aluminum at home and abroad; to investigate worker exposure at domestic aluminum manufacturing and handling workplaces; to conduct social and economic evaluation for the revision of domestic aluminum exposure limits. Methods: We investigated the current status of occupational exposure limits for aluminum at home and abroad, and analyzed supporting data. An exposure survey was conducted targeting domestic aluminum manufacturing and handling workplaces. Based on these, revised aluminum occupational exposure limits were proposed. Results: The major aluminum exposure limits at home and abroad show a notable difference. The toxicity of aluminum, which was revealed through animal experiments and epidemiological investigations. The average concentration of aluminum in the air at 12 workplaces was 0.016 mg/m3, and the maximum was 0.0776 mg/m3. When total dust and respiratory dust were measured side by side and simultaneously for the same process, 12.1% of the total mass concentration of aluminum dust was respiratory dust. As a result of measuring and comparing the size distribution of dust with an optical particle counter in real time, 48.1% of the total dust in the form of welding fume and pyro-powder was respiratory dust. Based on the literature review and workplace survey, three proposals for changing the aluminum exposure limit were proposed. Proposal (1): For all types, 10 mg/m3 is unified as the exposure limit except for soluble salts and alkyls. Proposal (2): 1(R) mg/m3 as the exposure limit for all forms except soluble salts and alkyl. Proposal (3): 1(R) mg/m3 for pyro-powder and welding fume, and 10 mg/m3 for metal dust, aluminum oxide, and insoluble compounds as exposure standards. A pyro-powder was defined as dry aluminum powder of 200 mesh size (74 ㎛) or smaller (larger size classified as metal dust). Reason for setting: In the workplace survey, the ratio of respiratory dust to total dust was analyzed to be about 1:10, so it was judged that the domestic standard and the ACGIH standard were compatible. Conclusions: In all scenarios according to the revision of the exposure standard, the B/C ratio was greater than 1 or only benefits existed, so it was evaluated as sufficiently reasonable as a result of the socio-economic evaluation.

Preparation of Electrode Coated with Activated Carbon for Dust Removal (분진제거를 위한 활성탄 전극판의 제조)

  • Kim, Kwang Soo;Park, Jung O;Jun, Tae Hwan;Kim, Ilho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.815-820
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    • 2013
  • The purpose of this research is to prepare the aluminum electrode coated with activated carbon for removing air pollution dust. The experiments were studied on the selection of optimal polymer for binding aluminum plate with powdered activated carbon, preventing the pore blocking of activated carbon from polymer binder, and the dust treatability for the prepared activated carbon electrode. The optimal adhesive for coating activated carbon on an electric aluminum plate was polyvinyl acetate (PVA) with vinyl functional group. For the opening of the blocked pore with polymer, it was very effective to embed polymer solvent in pore of activated catbon firstly before mixing activated carbon with PVA, and then to devolatilize the embedded solvent of carbon pore at high temperature. The mass of trapped dust on aluminum electrode coated with activated carbon was about double of the trapped one on just aluminum electrode.

Physicochemical Characteristics of Particulate Matter Emitted from Aluminum Casting Process (알루미늄 주조과정에서 배출되는 입자상물질의 물리·화학적 특성)

  • Jeong-Min Suh;Jeong-Ho Park
    • Journal of Environmental Science International
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    • v.33 no.5
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    • pp.297-304
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    • 2024
  • PM (Particulate Matters) was collected from a bag filter dust collector at an aluminum foundries, and its physicochemical properties were investigated using particle size analyzer and scanning electron microscopy with energy dispersive X-ray spectrometer (SEM/EDS). The median volume diameter of the particles passing through the pretreatment dust collector of the cyclone was approximately 10 ㎛. The cyclone pretreatment dust collector was shown to significantly reduce the throughput of large particles with a particle size of 100 ㎛ or more. The chemical composition of the particles showed a high Al content, and trace amounts of Mg, Si, and Zn were detected.

Recycling of Ferro-manganese Furnace Dust Collected from Converter (페로망간 집진분(集塵粉)의 재활용(再活用)에 관한 연구(硏究))

  • Kim, Youn-Che;Song, Young-Jun;Park, Young-Koo
    • Resources Recycling
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    • v.21 no.3
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    • pp.21-27
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    • 2012
  • In order to make high-purity ferro-manganese from $Mn_3O_4$ dust, the application of aluminothermy process to the reduction of $Mn_3O_4$ dust was investigated in previous work. The result showed the fact that can be obtained high purity ferro-manganese which have over about 93% of manganese content and lower impurities such as C, P, S than those of KS D3712 specification. The addition of silicon powder instead of aluminum powder was investigated as reductant in the thermite reaction process of $Mn_3O_4$ dust in this work because its production cost is lower than that of aluminum powder. In case of addition of silicon powder only as reductant, the experimental result showed the unstable ignition and no thermite reaction of mixture, but in case of simultaneous addition of silicon and aluminum powders as reductant, showed the fact that can be obtained high purity ferro-manganese which have much low content of impurities such as C, P, S component.

Explosion Properties of Nano and Micro-sized Aluminium Particles (나노 및 마이크로 입자 알루미늄의 폭발 특성)

  • Han, Ou-Sup;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.20-25
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    • 2014
  • Explosion characteristics of micro-sized aluminum dusts had been studied by many researchers, but the research of nano-sized aluminum dusts were very insufficient. In this study, an experimental investigation was carried out on the influences of nano and micro-sized aluminum dusts (70 nm, 100 nm, $6{\mu}m$, $15{\mu}m$) on dust explosion properties of aluminum particles by using 20 L explosion apparatus. With decreasing of particle size in suspended aluminum dusts, the LEC (lower explosion concentration) of nano-sized aluminum is lower than that of micro-sized aluminum. The particle size change of nano-sized aluminum dusts seems no obvious explosion differences than that of micro-sized aluminum dusts. From the observation of nano-sized aluminum particles by TEM (Transmission Electron Microscopy), it is estimated that increase of particles aggregation may have effects on the explosion characteristics of aluminum nanopowders.

Numerical Analysis of Two-Phase Aluminum Dust Combustion according to Single Aluminum Particle Combustion Model (단일 알루미늄 입자 연소 모델에 따른 2상 알루미늄 분말 연소장 시뮬레이션)

  • Kim, Sang-Min;Yang, Hee-Sung;Yoon, Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.460-466
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    • 2010
  • 단일 알루미늄의 연소 모델을 사용하여 알루미늄 분말의 점화 과정에 대한 전산유체 해석 기법을 개발하였다. 유동의 계산은 Reynolds averaged Navier-Stokes식을 사용하였으며, $k-{\epsilon}$ 난류모델을 적용하였다. 입자는 Eulerian-Lagrangian 방법을 사용하여 유동과 독립적으로 계산을 수행하였으며 상용 전산유체해석 프로그램인 Fluent 6.3을 사용하여 해석을 수행하였다. 단일 모델에서 사용한 대류 및 복사 열전달, 표면이상반응, 알루미늄의 용융열을 입자 가열원으로 고려하였다. 같은 조건을 사용하여 단일 입자 모델 계산과 전산유체해석을 수행하였으며, 두 결과는 5% 이내로 잘 일치 하였다. 이를 통해 전산유체해석에서 알루미늄의 점화를 모사할 수 있음을 확인하였다.

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Exposure Assessment of Airborne Dust in Manufacturing Industries Using Silicon Carbide in Korea (우리나라 실리콘카바이드 취급사업장의 공기 중 분진 노출평가)

  • Lee, Jun Jung;Phee, Young Gyu
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.21 no.3
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    • pp.177-183
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    • 2011
  • Occupational exposure to silicon carbide dust of manufacturing industries has seldom been evaluated in Korea. Accordingly, we evaluated various silicon carbide dust concentrations in the breathing zone of workers between May 2010 and July 2010. To compare silicon carbide dust concentrations, three dust samplers including the Institute of Occupational Medicine (IOM) sampler, 37mm cassette sampler, and Aluminum cyclone sampler were used. A total of 5 manufacturing industries producing abrasive and refractory materials using silicon carbide were investigated. The geometric mean concentrations were 2.04, 0.97, and $0.48mg/m^3$ in inhalable, total and respirable silicon carbide dust, respectively. The geometric mean concentrations of silicon carbide in abrasive material manufacturing industries were slightly higher than that of refractory manufacturing industries, and finishing operations were higher than that of other operations. It was found that the results of exposure assessment in airborne dust at manufacturing industries using silicon carbide in Korea showed exceeding rate to American Conference of Governmental Industrial Hygienists Threshold Limit Value ($3mg/m^3$) was 10% in respirable dust samples. Therefore, with the consideration of the close relationship between smaller dust size and the occurrence of occupational respiratory diseases, it is suggested to promulgate the new occupational exposure limit for respirable silicon carbide dust.

Risk Assessment of Explosion of Mixed Dust Generated in Semiconductor Manufacturing (반도체 공정에서 발생하는 혼합분진의 폭발 위험성평가)

  • Park, Chang-Sup;Kim, Chan-O
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.3
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    • pp.474-478
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    • 2018
  • The use of metals such as aluminum and titanium and the related industrial facilities have been continuously increasing to meet the requirements of the improvement of high-tech products due to the development of industry, and explosion of metal dust. Semiconductor process Metal dust is essential, but research is insufficient. The purpose of this study is to identify risk by analyzing the quantitative risk such as maximum explosion pressure and minimum explosion concentration applied international test standard in order to select the semiconductor process facilities handling dust and to predict possible risk of accidents.

Explosion Hazards of Aluminum Powders with the Variation of Mean Diameter (알루미늄 분진의 평균입경 변화에 따른 폭발위험성)

  • Han, Ou-Sup;Han, In-Soo
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.21-26
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    • 2014
  • In this study, the explosion characteristic of aluminium powders have been investigated as a function of particle size using by a 20 L dust explosion apparatus (K$\ddot{u}$hner). The tested aluminium particle sizes were the volume mean diameter of 16, 33 and $88{\mu}m$. The lower explosion limit increases gradually with the increasing of dust particle diameter, respectively 40, 60, $125g/m^3$ in mean diameter of 16, 33 and $88{\mu}m$. Also the increase in particle size for each aluminum dusts was found to cause an decrease in explosion pressure and Kst of dust explosion index, and a increase in the lower explosion concentration. Research results may have important implications for aluminum powders utilization and safety operation.

Pyrolysis Hazard for Nano and Micro-sized Aluminium Dusts (알루미늄 나노 및 마이크로 입자의 열분해 위험성)

  • Han, Ou-Sup
    • Journal of the Korean Institute of Gas
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    • v.19 no.5
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    • pp.75-80
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    • 2015
  • Aluminum dusts, from micro to nano-scale, are widely used in various applications such as propulsion and pyrotechnic compounds because of high burning rate. In this study, the pyrolysis hazard of aluminum dusts with different median size (sized by 70 nm, 100 nm, $6{\mu}m$, $15{\mu}m$) were investigated experimentally. The thermal decomposition characteristics of aluminum dusts with the variation of heating rate were investigated using TGA (Thermo gravimetric analysis) and was estimated the minimum ignition temperature from temperature of weight gain in nano and micro-sized aluminum dusts with different diameter. In the same condition of heating rate, the temperature of weight gain in aluminum dust layers increased with increasing of particle size and increased with increasing of heating rates in air. From the results, it was estimated that the pyrolysis hazard of aluminum dusts decrease with increasing of mean diameter.