• Title/Summary/Keyword: aluminum, copper

Search Result 389, Processing Time 0.025 seconds

Electrochemical Characteristics of $LiMn_{2}O_{4}$/Lithium Cells in Organic Electrolyte (유기전해액 $LiMn_{2}O_{4}$/Lithium 전지의 전기화학적 특성)

  • 임정환;도칠훈;문성인;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.371-374
    • /
    • 2000
  • The electrochemical properties of LiM $n_2$ $O_4$as a cathode and an anode for the lithium secondary battery were evaluated. When LiM $n_2$ $O_4$ material was used as the cathode with the current collector of aluminum, the 1st specific capacity and the 1st Ah efficiency in LiM $n_2$ $O_4$/lithium cell were 123 mAh/g and 91.7%, respectively The anodic properties of LiM $n_2$ $O_4$ material was also evaluated in the LiM $n_2$ $O_4$/1ithium cell with the current collector of copper. It showed that the LiM $n_2$ $O_4$ was useful as the anode for the lithium secondary battery. During the 1st discharge, a potential plateau was observed at the potential of 0.3 $V_{Li}$ Li+/. The 1st specific charge capacity and the 1st specific discharge capacity were 790 mAh/s and 362 mAh/g, respectively. Therefore, the 1st Ah efficiency was 46%. The discharge capacity was gradually faded with the charge-discharge cycling to about 50th cycles. Thereafter, the discharge capacity was stabilized to about 110 mAh/g.

  • PDF

Effects of Specimen Preparation Method and Contact Resistance on the Formation of Anodizing Films on Aluminum Alloys (시편의 준비 방법 및 접촉저항이 알루미늄 합금의 아노다이징 피막 형성에 미치는 영향)

  • Moon, Sungmo
    • Journal of the Korean institute of surface engineering
    • /
    • v.53 no.1
    • /
    • pp.29-35
    • /
    • 2020
  • In this study, five different specimen preparation methods were introduced and their advantages and disadvantages were presented. One of them, an epoxy mounting method has advantages of constant exposure area, ease of surface preparation without touching the specimen surface during polishing or cleaning, use of small amount of material and ease of specimen reuse by polishing or etching. However, in order to eliminate unexpected errors resulting from preferable reaction at the specimen/epoxy interface and contact resistance between the specimen and copper conducting line for electrical connection, it is recommended to cover the wall side of the specimen with porous anodic oxide films and to remain the contact resistance lower than 1 ohm. The increased contact resistance between the specimen and Cu conducting line appeared to result in increases of anodizing voltage and solution temperature during anodizing by which thickness and hardness of anodizing film on Al2024 alloy were drastically decreased and color of the films became more brightened.

Production Processes of Porous Metals and Their Applications (다공질 금속의 제조와 응용)

  • Shim, Jae-Dong;Byun, Ji-Young
    • Korean Journal of Materials Research
    • /
    • v.25 no.3
    • /
    • pp.155-164
    • /
    • 2015
  • Porous metals are called as a new material of 21th century because they show not only extremely low density, but also novel physical, thermal, mechanical, electrical, and acoustic properties. Since the late in the 1990's, considerable progress has been made in the production technologies of many kinds of porous metals such as aluminum, titanium, nickel, copper, stainless steel, etc. The commercial applications of porous metals have been increased in the field of light weight structures, sound absorption, mechanical damping, bio-materials, thermal management for heat exchanger and heat sink. Especially, the porous metals are promising in automotive applications for light-weighting body sheets and various structural components due to the good relation between weight and stiffness. This paper reviews the recent progress of production techniques using molten metal bubbling, metal foaming, gas expansion, hollow sphere structure, unidirectional solidification, etc, which have been commercialized or under developing, and finally introduces several case studies on the potential applications of porous metals in the area of heat sink, automotive pannel, cathod for Ni-MH battery, golf putter and medical implant.

A Study on the Inhibition Effect of Metal Corrosion Using Organic Compound Containing an Amine Group (아민기를 가진 유기물을 사용한 금속의 부식억제효과)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
    • /
    • v.27 no.3
    • /
    • pp.361-369
    • /
    • 2010
  • A study on the corrosion inhibition of metals is important in many industrial applications (carbon steel, copper, aluminum, SUS 304, nickel). In this study, we investigated the C-V diagrams related to the surface corrosion of metals. It was observed through the SEM that the surface corrosion state of the various metals had the corrosion potential by the scan rate and the organic inhibitor containing an amine group. We determined to measure cyclic voltammetry using the three-electrode system. The measurement of oxidation and reduction ranged from -1350mV to 1650mV. The scan rate was 50, 100, 150, and 200mV/s. It turned out that the C-V characterization of SUS 304 was irreversible process caused by the oxidation current from the cyclic voltammogram. After adding organic inhibitors, the adsorption film was constituted, and the passive phenomena happened. As a result, it was revealed that the inhibition effect of metal corrosion depends on the molecular interaction, and the interaction has influence on the adsorption complex.

Design of 0.6~6 GHz Ultra Wideband Quad-ridge Horn Antenna (0.6~6 GHz 초 광대역 쿼드릿지 혼 안테나 설계)

  • Choi, Cheoljin;Lee, Moonhee;Son, Taeho
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.68 no.1
    • /
    • pp.77-82
    • /
    • 2019
  • In this paper, a 0.6~6GHz quad-ridge horn antenna which can be used for the antenna measurement of 5.8GHz WiFi system from lowest frequency band of mobile LTE (Long Term Evolution) is designed and implemented. The quad-ridge horn antenna has quadruple ridges of exponential function, a back-short and a cavity. Based on this structure, we design the cavity size, ridge gap and feed gap to have broadband characteristics. For implementation, the plates material of aluminum and copper are used for the horn and four ridges, respectively. And the insulator supports are used to maintain the gap between ridges. By measurement, antenna has the gain of 6.2~13.35dBi with the return loss of less than -6dB (under VSWR 3 : 1) in the entire design band. The results of this study can be widely used to the antenna studies on the mobile communication including low frequency band of LTE, the EMI measurement and the standard calibration measurement.

Atmospheric Corrosion Behavior of Carbon Steel by the Outdoor Exposure Test for 10 Years in Korea

  • Yoo, Y.R.;Choi, S.H.;Kim, Y.S.
    • Corrosion Science and Technology
    • /
    • v.21 no.3
    • /
    • pp.184-199
    • /
    • 2022
  • Steel was exposed in an atmospheric environment, and atmospheric environmental factors that include chloride, humidity, SO2, NO2 etc. induced the corrosion of steel. Corrosivity categories classified by SO2 and chloride deposition rate were low, but those classified by TOW were high in the Korean Peninsula, and on these environmental categories, the corrosivity of atmospheres classified by corrosion rate in carbon steel was low medium, C2-C3, and medium, C3 for zinc, copper, and aluminum. This work performed the outdoor exposure test for 10 years at 14 areas in Korea and calculated the atmospheric corrosion rate of carbon steel. The atmospheric corrosion behavior of carbon steel is discussed based on the various corrosion factors. When the corrosion product forms on carbon steel by atmospheric corrosion, cracks may also be formed, and through these cracks, the environmental factors can penetrate into the interior of the product, detach some of the corrosion products and finally corrode locally. Thus, the maximum corrosion rate was about 7.3 times greater than the average corrosion rate. The color difference and glossiness of carbon steel by the 10 year-outdoor exposure tests are discussed based on the corrosion rate and the environmental factors.

A Study on the Reflectivity according to the Material of Biopsy Gun Needle Used in Ultrasound Biopsy (초음파 조직검사에 사용되는 Biopsy Gun Needle의 재질에 따른 반사율 연구)

  • Hoon Kim;Cheong-Hwan Lim
    • Journal of radiological science and technology
    • /
    • v.47 no.2
    • /
    • pp.97-105
    • /
    • 2024
  • The examination needle used in ultrasound biopsy is a medical device used to determine whether there is an abnormality in the tissue. Typically, stainless steel is the standard material used for such needles; however, this study wanted to identify a material that could better enhance sound compared to traditional stainless steel. In this study, six types of needle materials available with the biopsy gun were inserted into pork and ultrasound images according to the curved probe and linear probe were evaluated using ultrasound equipment. The findings revealed significant improvements in ultrasound acoustic enhancement with alternative materials compared to stainless steel (p<0.05). The results regarding the depth of each ultrasound image using the curved probe showed that tungsten and brass had high sound enhancement(p<0.05), while with the linear probe, sound enhancement was high in brass, pla, aluminum, and copper(p<0.05). Due to these results, the previously used stainless needle showed lower ultrasound acoustic enhancement than the five types of materials being compared. Consequently, the outcomes of this study provide valuable insights for the development of new needle technologies aimed at minimizing patient risks and improving diagnostic accuracy.

The State of Marine Pollution in the Waters adjacent to Shipyards in Korea - 3. Evaluation of the Pollution of Heavy Metals in Offshore Surface Sediments around Major Shipyards in Summer 2010

  • Kim, Kwang-Soo
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.21 no.3
    • /
    • pp.223-233
    • /
    • 2015
  • In order to evaluate the pollution of heavy metals in offshore surface sediments around shipyards in Korea, surface sediment samples were collected at eleven stations around four major shipyards located in the southeastern coast of Korea in summer 2010 and nine kinds of heavy metals such as copper(Cu), zinc(Zn), cadmium(Cd), lead(Pb), chrome(Cr), arsenic(As), mercury(Hg), iron(Fe) and aluminum(Al) in sediments were analyzed. The concentrations of Cu at all sampling stations were in the range of 47.10~414.96 mg/kg and exceeded TEL(Threshold Effects Level) 20.6 mg-Cu/kg of Korean marine environmental standards for offshore sediments and ERL(Effect Range-Low) 34.0 mg-Cu/kg. The concentrations of Cu at seven stations around four shipyards were 65.18~414.96 mg/kg and exceeded PEL(Probable Effects Level) 64.4 mg-Cu/kg of Korean marine environmental standards for offshore sediments. The concentration of Cu at one station around B-shipyard was 414.96 mg/kg and exceeded ERM(Effect Range-Median) 270.0 mg-Cu/kg. The concentrations of Zn at all stations were in the range of 135.09~388.79 mg/kg which exceeded ERL 150.0 mg-Zn/kg. The concentrations of Zn at seven stations around four shipyards were 157.57~388.79 mg/kg and exceeded PEL 157.0 mg-Zn/kg. The concentration of Zn at one station around B-shipyard was 388.79 mg/kg and was approaching ERM 410.0 mg-Zn/kg. The concentrations of Cd at all stations were in the range of 0.11~0.54 mg/kg and were below TEL 0.75 mg-Cd/kg and ERL 1.2 mg-Cd/kg. The concentrations of Pb at all stations were in the range of 18.04~105.62 mg/kg. The concentrations of Pb at two stations around B-shipyard were 73.87~105.62 mg/kg which exceeded TEL 44.0 mg-Pb/kg and ERL 46.7 mg-Pb/kg, and were below PEL 119.0 mg-Pb/kg and ERM 218.0 mg-Pb/kg. The concentrations of Cr at all stations were in the range of 51.26~85.39 mg/kg. The concentration of Cr at one station around B-shipyard was 85.39 mg/kg and exceeded ERL 81.0 mg-Cr/kg. The concentrations of As at all stations were in the range of 8.70~22.15 mg/kg which exceeded ERL 8.2 mg-As/kg and were below ERM 70.0 mg-As/kg. The concentrations of As at eight stations around A-shipyard, B-shipyard and D-shipyard were 14.93~22.15 mg/kg which exceeded TEL 14.5 mg-As/kg and were below PEL 75.5 mg-As/kg. The concentrations of Hg at all stations were in the range of 0.02~0.35 mg/kg. The concentrations of Hg at three stations around A-shipyard were 0.11~0.13 mg/kg which were almost equal to TEL 0.11 mg-Hg/kg. Those at two stations around B-shipyard were 0.27~0.35 mg/kg which exceeded TEL 0.11 mg-Hg/kg and ERL 0.15 mg-Hg/kg, and were below PEL 0.62 mg-Hg/kg and ERM 0.71 mg-Hg/kg. The concentrations of Fe and Al at all stations were in the range of 2.90 3.66 % and 3.12 6.80 %, respectively. These results imply that heavy metals such as copper, zinc, lead, arsenic and mercury were likely to be transferred to marine environment from shipyards, especially from B-shipyard.

Evaluation of Fracture Toughness of Copper Thin Films by Combining Numerical Analyses and Experimental Tests (해석과 실험을 결합한 구리 박막의 파괴인성 평가)

  • Kim, Hyun-Gyu;Oh, Se-Young;Kim, Kwang-Soo;Lee, Haeng-Soo;Kim, Seong-Woong;Kim, Jae-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.37 no.2
    • /
    • pp.233-239
    • /
    • 2013
  • In this paper, a method of combining numerical analyses and experimental tests is used to evaluate fracture toughness of copper thin films of $15{\mu}m$ thickness. Far-field loadings of a global-local finite element model are inversely estimated by matching crack opening profiles in experiments with numerical results. The fracture toughness is then evaluated using the J-integral for cracks in thin films under far-field loadings. In experiments, Cu thin films attached to Aluminum sheets are loaded indirectly, and crack opening profiles are observed by microscope camera. Stress versus strain curves of Cu thin films are obtained through micro-tensile tests, and the grain size of Cu thin films is observed by TEM analysis. The results show that the fracture toughness of Cu thin films with $500nm{\sim}1{\mu}m$ sized grains is $6,962J/m^2$.

Electricity Generation and De-contamination Effect for Characteristic Electrode Material in a Microbial Fuel Cell System Using Bay Sediment (MFC의 금속 및 탄소전극에 의한 전기생산 특성과 오염저감 효과)

  • Kwon, Sung-Hyun;Song, Hyung-Jin;Lee, Eun-Mi;Cho, Dae-Chul;Rhee, In-Hyoung
    • Journal of Environmental Science International
    • /
    • v.19 no.8
    • /
    • pp.951-960
    • /
    • 2010
  • Sediment works as a resource for electric cells. This paper was designed in order to verify how sediment cells work with anodic material such as metal and carbon fiber. As known quite well, sediment under sea, rivers or streams provides a furbished environment for generating electrons via some electron transfer mechanism within specific microbial population or corrosive oxidation on the metal surfaces in the presence of oxygen or water molecules. We experimented with one type of sediment cell using different anodic material so as to attain prolonged, maximum electric power. Iron, Zinc, aluminum, copper, zinc/copper, and graphite felt were tested for anodes. Also, combined type of anodes-metal embedded in the graphite fiber matrix-was experimented for better performances. The results show that the combined type of anodes exhibited sustainable electricity production for ca. 600 h with max. $0.57\;W/m^2$ Al/Graphite. Meanwhile, graphite-only electrodes produced max. $0.11\;W/m^2$ along with quite stationary electric output, and for a zinc electrode, in which the electricity generated was not stable with time, therefore resulting in relatively sharp drop in that after 100 h or so, the maximum power density was $0.64\;W/m^2$. It was observed that the corrosive reaction rates in the metal electrodes might be varied, so that strength and stability in the electric performances(voltage and current density) could be affected by them. In addition to that, COD(chemical oxygen demand) of the sediment of the cell system was reduced by 17.5~36.7% in 600 h, which implied that the organic matter in the sediment would be partially converted into non-COD substances, that is, would suggest a way for decontamination of the aged, anaerobic sediment as well. The pH reduction for all electrodes could be a sign of organic acid production due to complicated chemical changes in the sediment.