Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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A Study on the Inhibition Effect of Metal Corrosion Using Organic Compound Containing an Amine Group

아민기를 가진 유기물을 사용한 금속의 부식억제효과

  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
  • 박근호 (창원대학교 화공시스템공학과)
  • Received : 2010.08.12
  • Accepted : 2010.09.24
  • Published : 2010.09.30
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Abstract

A study on the corrosion inhibition of metals is important in many industrial applications (carbon steel, copper, aluminum, SUS 304, nickel). In this study, we investigated the C-V diagrams related to the surface corrosion of metals. It was observed through the SEM that the surface corrosion state of the various metals had the corrosion potential by the scan rate and the organic inhibitor containing an amine group. We determined to measure cyclic voltammetry using the three-electrode system. The measurement of oxidation and reduction ranged from -1350mV to 1650mV. The scan rate was 50, 100, 150, and 200mV/s. It turned out that the C-V characterization of SUS 304 was irreversible process caused by the oxidation current from the cyclic voltammogram. After adding organic inhibitors, the adsorption film was constituted, and the passive phenomena happened. As a result, it was revealed that the inhibition effect of metal corrosion depends on the molecular interaction, and the interaction has influence on the adsorption complex.

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References

  1. J. E. Singley and D. W. Deberry, Corrosion Prevention and Control in Water Treatment and Supply Systems, Pollution Technology Review, 122, 8 (1985).
  2. D. Landolt, "Corrosion and surface Chemistry of metals", p.204, EPFL Press, Lausanne, Switzerland (2007).
  3. R. S. Nicholson and I. Shain, Theory of Stationary Electrode Polarography, Anal. Chem., 36, 706 (1964). https://doi.org/10.1021/ac60210a007
  4. H. S. Kim Y. I. Yun, E. J. Cho, Y. H. Choi, and M. Y. Oh, Analysis of Electrocoagulation Process using Faraday's Law, J. Ind. Tec., 21, 351 (2001).
  5. K. H. Park and B. C. Min, A Study on the behaviors of electrochemical polarization according to the organic inhibitor involved amine groups for carbon steel, The Research Bulletin of Changwon National University, 14, 379 (1992).
  6. E. E. Stansbury and R. A. Buchman, "Fundamentals of electrochemical corrosion", P.63, ASM International, Ohio, U.S.A.(2004).
  7. T. C. Son, N. S. Kim, and K. H. Park, The Electrochemical Characterization of Mixture LB Films of Fatty Acid and Phospholipids, J. Kor. Oil Chem. Soc., 20(2), 94 (2003).
  8. S. H. Choi and T. C. Son, J. Y. Song, K. H. Park, Electrochemical Properties of Organic Ultra Thin Films of Fatty Acid and Phospholipid Mixture, J. Kor. Oil Chem. Soc., 23(2), 137 (2006).
  9. T. C. Son, C. H. Mim, and K. H. Park, Electrochemical Properties of Langmuir-Blodgett(LB) Films of Alkyl Bromides, J. Kor. Oil Chem. Soc., 26(4), 451 (2009).
  10. C. H. Mim, T. C. Son, and K. H. Park, Electrochemical Properties of Ultrathin Film Functional Polyimide by Langmuir-Blodgett Method, J. Kor. Oil Chem. Soc., 26(4), 400 (2009).
  11. T. C. Son, D. S. Kim, and K. H. Park, Electrochemical Properties of Langmuir-Blodgett (LB) Monolayer Films of Alkyl Bromides Mixture, J. Kor. Oil Chem. Soc., 27(2), 202 (2010).
  12. J. M. Ko and H. C. Park, Principles and Applications of Cyclic Voltammetry, Poly. Sci. Tec., 10, 519 (1999).
  13. D. S. Park, Study for Electrode Reaction Characteristics by Cyclic Voltammetry, Poly. Sci. Tec., 14, 356 (2003).
  14. R. S. Nicholson and I. Shain, Theory of Stationary Electrode Polarography, Anal. Chem., 36, 706 (1964). https://doi.org/10.1021/ac60210a007
  15. H. S. Kim Y. I. Yun, E. J. Cho, Y. H. Choi, and M. Y. Oh, Analysis of Electrocoagulation Process using Faraday's Law, J. Ind.. Tec., 21, 351 (2001).