• Title/Summary/Keyword: aluminium-magnesium

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Chemical Compositio and Structure of Evaporated Alloying Element by Laser Welding Condition (레이저 용접조건에 따른 증발된 합금원소의 조성과 구조의 변화)

  • 조상명
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.4
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    • pp.523-532
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    • 1999
  • This study is aimed to obtain fundamental knowledge of pulse laser welding phenomena the authors investigated the structure and composition of evaporated particles of Al alloys in air and in the Ar atmosphere during pulsed laser welding. The ultra-fine particles of 5 to 100nm diameter in a globular or irregular shape were formed in laser-induced plasma and the main structure was $MgAl_2O_4$ The composition of particles was ifferent depending on the power density of a laser beam; namely under the low power density conditions magnesium was predominant in the parti-cles while aluminium content increased with an increase in the power density. These results were attributed to evaporation phenomena of metals with different boiling points and latent heats of vaporization. On the other hand the number density of laser-induced plasma species was obtained by Saha's equation. it was confirmed that the number density depends upon the plasma tempera-ture and total pressures.

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Preparation of Monodispersed, Sheperical Al2O3 and Mg-doped Al2O3 Powder and Sintering Characterization of These Powders (구형의 단분산 Alumina 및 Mg-doped Alumina의 합성과 소결에 관한 연구)

  • 이중윤;부재필;최상흘
    • Journal of the Korean Ceramic Society
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    • v.31 no.1
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    • pp.1-10
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    • 1994
  • Monodispersed alumina and Mg-doped alumina fine particles were prepared by controlled hydrolysis of alkoxides. Aluminium alkoxide and magnesium alkoxide were dissolved into complex solvent which was composed of hydrophobic n-octanol and hydrophilic acetonitrile. Hydroxypropyl cellulose(HPC) was used as a dispersant for the alumina particles. The size of these prepared powders was approximately 0.3 ${\mu}{\textrm}{m}$. In the case of sintering above 100$0^{\circ}C$, most of these prepared powders were transformed to $\alpha$-alumina. The relative density of the sintered body of these prepared powders at 1$600^{\circ}C$ was 98%. The sintered body of the Mg-doped alumina powder had more uniform grain size than that of the undoped alumina podwer.

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A Study on the Flame Retardant Effect for Metal Complexes-Cellulose Hybrid Insulator (금속착물-셀룰로오스 복합 단열재의 난연 효과 연구)

  • Kim, Hong;Kang, Young-Goo
    • Journal of the Korean Society of Safety
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    • v.10 no.3
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    • pp.62-67
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    • 1995
  • The combustion characteristics of cellulose Insulation treated with several metal complexes such as Aluminium hydroxide, Cupric sulfate pentahydrate, Magnesium sulfate heptahydrate, Manganese chloride tetrahydrate and Tnisodium phosphate dodecahydrate are studied to evaluate the effectiveness as a potential flame retardant for cellulosic materials. In this study, we found that LOI values of cellulosic materials treated with the metal complexes are generally increased with the increase of their content. At high concentration, CS(24% ) and SP(24% ) show high LOI values, suggesting resistance to flame spread, The materials examined in this study were found to be relatively more resistance to smouldering and flaming combustion in comparision with untreated cellulosic material. The flammability behavior of the materials exhibits combustion process as follows : LOI$\rightarrow$smouldering region$\rightarrow$smouldering-flaming spread region$\rightarrow$flame spread region.

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Effects of Metal Mg on Replacement Reaction of Molten Al for Fabrication of $Al_2$O$_3$//Al Composites (Al$_2$O$_3$/Al 복합체 제조시 용융 알루미늄의 치환반응에 미치는 금속 마그네슘의 영향)

  • 정두화;배원태
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.23-32
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    • 1998
  • Al2O3/Al composites were produced by immersing the sintered silica preform in molten aluminum which contained magnesium as impurity. Three distinct regions existed in the penetration behavior of molten me-tal with changing the reaction temperature. These regions are denoted as low temperature regime(75$0^{\circ}C$-85$0^{\circ}C$) intermediate regime(90$0^{\circ}C$-95$0^{\circ}C$) and high temperature regime(100$0^{\circ}C$$\leq$) In the low temperature regime the penetration speed of molten aluminum increased with increasing reaction temperature whereas it decreased in the intermediate regime due to the phase transition of alumina formed by displacement reac-tion. In the high temperature regime the penetration speed of molten aluminum was the highest at 100$0^{\circ}C$ which was 3.6 mm/hr But above 105$0^{\circ}C$ molten aluminum did not penetrate into the silica preform because of the formation of a dense spinel layer at the preform surface by magnesium in molten Al.

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Flame Retardancy of Plywood Treated with Various Water Glass Concentration and Additives (물유리의 농도와 첨가제 종류에 따른 방염제의 성능)

  • PARK, Sohyun;HAN, Yeonjung;SON, Dong Won
    • Journal of the Korean Wood Science and Technology
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    • v.49 no.1
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    • pp.44-56
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    • 2021
  • The carbonized length and area of plywood by the various spreading concentration of water glass and the type of additives were measured in accordance with the 45° MecKel's burner method of the fire protection performance standard of the Korean National Fire Agency. As a result of treating water glass with a concentration of 20 to 50 % on plywood, the flame retardancy tended to increase in proportion to the concentration of water glass. However, the optimum concentration of water glass was determined to be 30 % due to the efflorescence and sticky on the surface of plywood treated with high-concentration water glass of more than 30 %. As a result of the experiment by adding different proportions of additives to the water glass with concentration of 30 %, the standard of flame performance standard was satisfied under the conditions with the addition of 15% potassium hydroxide and 1-10% aluminum hydroxide, respectively. On the other hand, there were no significant difference in the flame retardancy by adding magnesium sulfate. These results about the flame retardancy of plywood by water glass and additives were expected to be basic data for improving flame-retardant treated wood.

A Study on the Effect of Expandable Graphite and Metal Hydroxides on the Properties of Wood Plastic Composites (WPCs) (팽창성 흑연과 금속수산화물이 목재·플라스틱 복합재의 특성에 미치는 영향에 관한 연구)

  • Kim, Seungkyun;Lee, Danbee;Lee, Sun-Young;Chun, Sang-Jin;Kim, Birm-June
    • Journal of the Korea Furniture Society
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    • v.27 no.4
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    • pp.392-398
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    • 2016
  • Wood-plastic composites (WPCs) composed of mainly wood flour and thermoplastics have attracted considerable attentions due to advantages of cost effectiveness, high durability, and microbial resistance. However, relatively poor fire resistance of WPCs from low thermal stability of wood and plastics prevents further uses. This study investigated the effect of expandable graphite (EG) and aluminium hydroxide (AH)/magnesium hydroxide (MH) on the properties of WPCs. The combined incorporation of both EG and metal hydroxide (i.e., AH or MH) into formulations leads to higher flexural modulus of filled composites compared to neat PP and WPC. In thermal properties, EG played an important role in improving thermal stability of filled composites by suppressing thermal decompositions of wood and PP. Moreover, EG showed better water absorption features. From this research, it can be said that EG and metal hydroxides have potentials as effective reinforcement, flame retardant, and moisture barrier.

Effects of Mg and Cu Amounts on the Casting Characteristics and Tensile Property of Al-Zn-Mg-Cu Alloys (Al-Zn-Mg-Cu 합금의 주조성 및 인장특성에 미치는 Mg 및 Cu 첨가량의 영향)

  • Kim, Ki-Tae;Lim, Young-Suk;Kim, Jeong-Min
    • Journal of Korea Foundry Society
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    • v.32 no.1
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    • pp.38-43
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    • 2012
  • The effects of Mg and Cu amounts on the casting characteristics and tensile property of Al-Zn-Mg-Cu alloys were investigated for the development of high strength aluminium alloys for gravity mold casting. Increase of copper amounts in Al-6%Zn-3%Mgy% Cu alloys resulted in reduction of the fluidity of these alloys and had little effects on the tensile property of these alloys. Increase of magnesium amounts from 1.0wt% to 3.3wt% in Al-6%Zn-x%Mg-0.5%Cu alloys resulted in reduction of the elongation of these alloys from 12% to 3% and increase of the tensile strength of these alloys from 340MPa to 450MPa, but had little effects on the fluidity of these alloys.

A Study on the Microstructure and Hardness of Al-Si-Mg Alloys upon Heat Treatments (Al-Si-Mg계 합금의 열처리에 의한 미세조직과 경도 변화)

  • Lee, Se-Jong;Lee, Sung-Kwan;Baik, Nam-Ik
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.2
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    • pp.108-114
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    • 2000
  • The effects of heat treatments in Al-Si-Mg alloys on the microstructure and hardness have been investigated by the optical microscope, scanning electron microscope(SEM), and Rockwell hardness tester. The materials of various compositions are melted in a vacuum induction furnace under argon atmosphere. Five different Al alloys are prepared from commercial purity aluminium, magnesium and Al-25Si alloy. Two types of aging treatments are performed: i) Isothermal aging of the specimens at $150^{\circ}C$, $170^{\circ}C$ and $190^{\circ}C$. ii) Pre-aging of the specimens at $60^{\circ}C$, $80^{\circ}C$ and $100^{\circ}C$, and followed by final-aging at $170^{\circ}C$ and $190^{\circ}C$. After the heat treatments, Rockwell hardness are measured with all the specimens.

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Effect of Aging on the Interfacial Characteristics of ${Al_{18}}{B_4}{O_{33}}$/AS52 Mg Matrix Composite by Squeeze infiltration (용탕가압침투법으로 제조한 ${Al_{18}}{B_4}{O_{33}}$/AS52 Mg기 복합재료의 계면 특성에 미치는 시효의 영향)

  • Park, Yong-Ha;Park, Yong-Ho;Cho, Kyung-Mox;Park, Ik-Min
    • Journal of Korea Foundry Society
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    • v.28 no.6
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    • pp.268-272
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    • 2008
  • Interfacial characteristics of aluminum borate whisker reinforced AS52 matrix composite was investigated. Peak hardness of AS52 composite was obtained aging at $170^{\circ}C$ for 15h and the aging process was accelerated by the presence of the aluminium borate whisker. The MgO layer, which was the interfacial reaction product between the reinforcement and the Mg matrix, was produced with 20 nm thickness in as-cast condition. As the aging time increased, the thickness of the interfacial reaction layer increased to 50 nm in peak aged condition. The nano-indentation test results indicated that the strength of interface was improved by the aging but over-aging degraded the reinforcement and decreased the interfacial strength which resulted in the decrease of overall composite strength.

Effect of Fluorides on Mullitization of $SiO_2-Al_2O_3$ System; Korean Kaolin (플루오르화물이 $SiO_2-Al_2O_3$계 원료의 물라이트화에 미치는 영향)

  • 최상욱;이철규
    • Journal of the Korean Ceramic Society
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    • v.17 no.2
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    • pp.61-68
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    • 1980
  • The effect of the addition of various fluoreides on the mullitization of Korean crude kaolin was studied by X-ray powder diffraction and scanning electron microscopic methods. Kaolin without any addition of fluoreides began to be transformed into the mullite at 1, 10$0^{\circ}C$. Mullite peaks were discernible in the X-ray diffraction patterns of the specimens which contained fluorides equivalent to about 2 wt % fluorine, and which were sintered at 1, 05$0^{\circ}C$. The higher the concentration of fluorine in kaolin, the lower was the initiatinig temperature of mullitization. Experiments , for example, showed that mullite could be formed at 95$0^{\circ}C$ from kaolin mixed with 3.4% fluorine. Of the fluoride, addtives, sodiumsiliconfluoride $(Na_2SiF_6)$ was must effective in mullite formation of kaolin. In order of accelerating mullitization, the fluorides except $Na_2SiF_6$ could be placed in following sequence ; (1) sodium (NaF) (2) aluminium$(AlF_3)$ (3)potassium(KF) (4) ammonium$(NH_4F)$ (5) magnesium$(MgF_2)$ (6) calcium$(CaF_2)$. It was considered that the intrinsic characteristics of fluorides, such as size of ionic radiu, charge , bond strength between cation and anion, and electronegativity of cation affected millitization of halloysite, a main constituent mineral of kaolin.

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