• Title/Summary/Keyword: aluminium sulfate

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Removal of sulfate ion from semiconductor wastewater by ettringite precipitation

  • Chung, Chong-Min
    • Membrane and Water Treatment
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    • v.13 no.4
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    • pp.183-189
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    • 2022
  • This study seeks towards an optimal way to control sulfate ions in semiconductor wastewater effluent with potential eco-toxicity. We developed a system based on ettringite (Ca6Al2(SO4)3(OH)12·26H2O). The basic idea is that the pH of the water is raised to approximately 12 with Ca(OH)2. After, aluminium salt is added, leading to the precipitation of ettringite. Lab-scale batch and continuous experiment results with real semiconductor wastewater demonstrated that 1.5 and 1 of stoichiometric quantities for Ca2+ and A3+ with pH above 12.7 could be considered as the optimal operation condition with 15% of sludge recycle to the influent. A mixed AlCl3 + Fe reagent was selected as the beneficial Al3+ source in ettringite process, which resulted in 80% of sludge volume reduction and improved sludge dewaterability. The results of continuous experiment showed that with precipitation as ettringite, sulfate concentration can be stably reduced to less than 50 mg/L in effluent from the influent 2,050 ± 175 mg/L on average (1,705 ~ 2,633 mg/L).

Treatment of cutting-oily wastewater by electrocoagulation-flotation (ECF) process: Modeling approach

  • Chawaloesphosiya, Nattawin;Mongkolnauwarat, Jittrapa;Prommajun, Chayanin;Wongwailikhit, Kritchart;Painmanakul, Pisut
    • Environmental Engineering Research
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    • v.20 no.4
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    • pp.392-396
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    • 2015
  • This work aims to investigate the oily wastewater treatment by the electrocoagulation-flotation (ECF) and propose a mathematical model for the efficiency prediction. Cutting oil was used to prepare the synthetic oily wastewater with submicron droplet sizes. The chemical coagulation by aluminium sulfate was firstly tested following by the electrocoagulation-flotation with aluminium electrodes. Both processes gave the effective treatment performance with the efficiencies higher than 90%. However, the ECF consumed less aluminium dosage as well as produced less sludge, which were its advantage on the chemical coagulation. The performance of the ECF was found to be affected by the current density, oil concentration, and reaction time according to the analysis by the design of experiment (DOE). Finally, the prediction model was proposed by two approaches, including linear and logarithm function. The latter model gave more accuracy prediction results in terms of treatment efficiency and duration in the lag and stable stages.

Chemical Coagulation Treatment Using Alum and PACl in Complex Wastewater (Alum과 PACl을 이용한 응집처리)

  • Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.35 no.1
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    • pp.53-57
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    • 2009
  • In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

Effect of Pretreatments and Holding Solutions on Vase Life and Quality of Cut 'Saphir' Rose (전처리와 보존용액이 절화장미 'Saphir'의 수명과 품질에 미치는 영향)

  • Bang, Chang-Seok;Lee, Jong-Suk;Song, Cheon-Young;Song, Jeong-Seob;Huh, Kun-Yang
    • Horticultural Science & Technology
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    • v.17 no.6
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    • pp.758-760
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    • 1999
  • This experiment was carried out to investigate the effect of pretreatments and holding solutions on quality and vase life of cut 'Saphir' rose (Rosa hybrida L.). Pulsing with aluminum sulfate or NaOCl prolonged vase life held in HQS+sucrose+ethionine. Solution absorption held in distilled water were more increased than held in HQS+sucrose+ethionine. Holding solution with 8-hydroxyquinoline sulfate (HQS)+sucrose+ethionine increased fresh weight compared with distilled water except pulsing with STS+sucrose. Pulsing with aluminium sulfate delayed bent-neck held in HQS+sucrose+ethionine. Flower diameter and dry weight of petal held in HQS+sucrose+ethionine were more increased than held in distilled water except pulsing with STS+sucrose. There were no significance in Hunter color value 'L' and value 'a', but value 'b' was decreased held in distilled water.

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Difference in Bonding Strength of RMGIC according to Type of Hemostatic Agent in Primary Tooth (지혈제의 종류에 따른 레진 강화형 글라스아이오노머 시멘트 결합력의 차이)

  • Back, Seolah;Lee, Joonhaeng;Kim, Jongbin;Han, Miran;Kim, Jong Soo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.48 no.4
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    • pp.460-466
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    • 2021
  • The purpose of this study was to compare the effect of the hemostatic agent containing aluminum chloride with hemostatic agent containing ferric sulfate on the shear bond strength of resin-modified glass ionomer cement(RMGIC) to dentin in primary tooth. Twenty extracted non-carious human primary teeth were collected in this study. The specimens were cut to expose dentin and polished. The specimens were randomly seperated into 3 groups for treatment; group I: polyacrylic acid(PAA), RMGIC; group II: aluminum chloride, PAA, RMGIC; group III: ferric sulfate, PAA, RMGIC Ten specimens from each group were subjected to shear bond strength test. The mean shear bond strength of each group was as follows: 10.07 ± 1.83 MPa in Group I, 7.62 ± 0.78 MPA in group II, 5.23 ± 0.78 MPa in group III. There were significant differences among all groups(p < 0.001). In conclusion, both aluminum chloride hemostatic agent and ferric sulfate hemostatic agent decreased the shear bond strength of RMGIC to dentin. And ferric sulfate hemostatic agent decreased the shear bond strength of RMGIC more than the aluminium chloride hemostatic agent.

A Study on the Flame Retardant Effect for Metal Complexes-Cellulose Hybrid Insulator (금속착물-셀룰로오스 복합 단열재의 난연 효과 연구)

  • Kim, Hong;Kang, Young-Goo
    • Journal of the Korean Society of Safety
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    • v.10 no.3
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    • pp.62-67
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    • 1995
  • The combustion characteristics of cellulose Insulation treated with several metal complexes such as Aluminium hydroxide, Cupric sulfate pentahydrate, Magnesium sulfate heptahydrate, Manganese chloride tetrahydrate and Tnisodium phosphate dodecahydrate are studied to evaluate the effectiveness as a potential flame retardant for cellulosic materials. In this study, we found that LOI values of cellulosic materials treated with the metal complexes are generally increased with the increase of their content. At high concentration, CS(24% ) and SP(24% ) show high LOI values, suggesting resistance to flame spread, The materials examined in this study were found to be relatively more resistance to smouldering and flaming combustion in comparision with untreated cellulosic material. The flammability behavior of the materials exhibits combustion process as follows : LOI$\rightarrow$smouldering region$\rightarrow$smouldering-flaming spread region$\rightarrow$flame spread region.

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Studies on the Determination of Optimal Flocculation Condition in Wastewater of Recycled Paper (재생지 폐수의 최적 응집조건 결정에 관한 연구)

  • 이성호;임택준;조준형
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.44-51
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    • 2001
  • Sedimentation characteristics such as SS, $BOD_5$, COD removal efficiency of waste water in the toilet paper mill using milk carton were examined. Optimum dosage of coagulant, rapid mixing time and slow mixing time were determined by turbidity, SS, COD, $BOD_5$ and then equation for treatment efficiency was suggested. Mechanical strength of floc was determined by turbidity. For the coagulant, polyacrylamide (PAM) is more efficient for removing pollution than the aluminium sulfate. Effective mixing ratios of PAM and aluminum sulfate to remove pollution are 70:30 and 30:70. The lowest turbidity was showed when rapid mixing at 300 rpm after coagulant injection was applied. That which indicates the highest point of flocs mechanical strength.

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Effect of Lime and Temperature on the Changes of Available Soil Nutrients in Acid Sulfate Soil under Submergence (특이산성토양(特異酸性土壤)에서 담수시(湛水時) 석회처리(石灰處理) 및 온도조절(溫度調節)이 토양(土壤)의 유효성분(有效成分) 변화(變化)에 미치는 영향(影響))

  • Kang, Ui-Gwm;Ha, Ho-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.3
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    • pp.282-288
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    • 1985
  • This experiment was conducted to investigate the changing patterns of the available elements by the control of lime addition amount and temperature in Acid Sulfate Soils under the submerged condition. The results obtained were summarized as follows: 1. pH and contents of available phosphate, soluble silicate, $NH_4-N$, and exchangeable iron in soils were decreased but exchangeable aluminium and manganese, and water soluble sulfur in soils increased after submergence. 2. Lime treatment increased pH, available phosphate, soluble silicate, $NH_4-N$, and water soluble sulfur, but that decreased exchangeable aluminium, iron, and manganese in soils. 3. Treatment with 12me/100gr of Ca as $CaCO_3$, showed the marked effect in increasing the exchangeable aluminium and iron, and increasing pH value to about 6.5 as well as available phosphate and $NH_4-N$. 4. Increases in available phosphate, $NH_4-N$, and exchangeable iron with aging of the soil flooded and lime treated were higher at $35^{\circ}C$ than those at $25^{\circ}C$. 5. Throughout submerged period a significant positive correlation was observed between pH and soluble silicate while the pH has negative correlation with exchangeable elements such as aluminium, iron, and manganese etc.

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New Catalyst for Durable Press Finish of Cotton Fabrics Treated with Glyoxsl (Glyoxal 처리에 의한 면직물의 DP가공시 새로운 촉매)

  • 유영하;방은숙;김승일;이의소
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.423-424
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    • 2003
  • 셀룰로스 직물은 easy care 성능을 부여하기 위하여 가교제로 처리된다. 현재 공업적으로 가장 많이 이용되고 있는 DMDHEU와 같은 N-methyol 가교제는 공정 중 또는 처리된 제품의 저장 중에 발암물질인 포름알데하이드를 유리시키는 경향이 있어 포름알데하이드를 유리시키지 않는 가교결합제의 개발이 활발하게 연구되고 있다. 이러한 비포르말린계 가교제 중 글리옥살은 그 성능은 매우 뛰어나지만 DP 처리시 사용되는 촉매인 aluminium sulfate는 처리직물의 강도저하와 황변을 일으키는 단점을 지니고 있다[1]. (중략)

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Dyeing of Wool and Nylon Fabrics with Chinese Scholar Tree Extract (괴화 추출물에 의한 모와 나일론직물의 염색성)

  • 배정숙;허만우
    • Journal of the Korean Home Economics Association
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    • v.41 no.2
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    • pp.107-121
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    • 2003
  • This study was discussed the dyeing of wool and nylon fabrics with Chinese Scholar Tree extract. The extracts of Chinese Scholar Tree was prepared in the condition of heating at $95{\pm}5C$, for 1 hour and cooling to 40C. And then the extracts of color matter treate with vacuum concentration at $60{\pm}2^{\circ}C$, 30mmHg and dried with spray dryer. The dyeing of wool and nylon fabric in this experiment was also employed the mordant dyeing method such as pre-mordant, post-mordant and simultaneous mordant method. The mordanting agents used in this study were as followings ; aluminium potassium sulfate, copper(II) acetate monohydrate, chromium potassium sulfate$.$$7H_2O$, Tin(II) chloride dihydrate, iron(II)sulfate $7H_2O$. For an evaluation of the dyeing property of the mordanting agents, the pre-mordant method, the repeat dyeing and the fastness of the light, dry cleaning, washing and rubbing measured respectively. From the results of the dye absorption, the optimum dyeing condition of the wool and nylon fabrics with Chinese Scholar Tree extract is at 80C dyeing temperature for 60 minutes. The optimum concentration of mordanting agent is Al, Cr, Sn 1%, Fe, Cu 2% solution. In general, the fastness property of the dyed wool and nylon fabrics had a comparatively high grade.