• Title/Summary/Keyword: alternative membrane

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Ammonia Removal Characteristics in Membrane Contactor System Using Tubular PTFE Membrane (관형 PTFE 분리막을 이용한 막 접촉기(Membrane Contactor) 시스템에서 암모니아의 제거 특성)

  • Ahn, Yong-Tae;Hwang, Yu-Hoon;Shin, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.353-358
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    • 2011
  • In this study, ammonia removal characteristics in membrane contactor system under various operating conditions were evaluated. The mass transfer coefficient was used to quantitatively compare the effect of various operation conditions on ammonia removal efficiency. Effective removal of ammonia was possible with the tubular PTFE membrane contactor system at all tested conditions. Among the various operation parameters, contact time and solution pH showed significant effect on ammonia removal mechanism. Overall ammonia removal rate was not significantly affected by influent suspended solution concentration unlike other pressure driven membrane filtration processes. Also the osmotic distillation phenomena which deteriorate the mass transfer efficiency can be minimized by preheating of strip solution. Membrane contactor system can be a possible alternative to treat high strength nitrogen wastewater by optimizing operation conditions such as stripping solution flow rate, influent wastewater temperature, and influent pH.

Effect of current density and contact time on membrane fouling in electrocoagulation-MBR and their kinetic studies on fouling reduction rate (전기응집-MBR 공정의 전류밀도와 접촉시간이 막 오염에 미치는 영향과 막 오염 저감 속도론적 고찰)

  • Um, Se-Eun;Chang, In-Soung
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.321-328
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    • 2017
  • Recently EC-MBR (Elctrocoagulation - Membrane Bio Reactor) has been suggested as one of alternative processes to overcome membrane fouling problems. Most important operational parameters in the EC-MBR are known to current density and contact time. Their effect on membrane filtration performances has been reported well, however, quantitative interrelationship between both parameters not been investigated yet. The purpose of this study is to give a kinetic model suggesting the current density and the contact time required to reduce the membrane fouling. The 4 different set of current densities (2.5, 6, 12 and $24A/m^2$) and contact times (0, 2, 6 and 12 hr) were selected as operational parameters. After each electro-coagulation under the 16 different conditions, a series of membrane filtration was carried out. The membrane fouling decreased as the current density and contact time increased, Total fouling resistances under different conditions, $R_t(=R_c+R_f)$ were calculated and compared to those of the controls ($R_0$), which were calculated from the data of experiments without electro-coagulation. A kinetic approach for the fouling reduction rate ($R_t/R_0$) was carried out and the equation ${\rho}^{0.46}_it=7.0$ was obtained, which means that the product of current density and the contact time needed to reduce the fouling in certain amounts (in this study, 10% of fouling reduction) is always constant.

How to Design Membrane Chromatography for Bioseparations: A Short Review (바이오분야 분리용 막크로마토그래피 설계 방안)

  • Park, Inho;Yoo, Seung Yeon;Park, Ho Bum
    • Membrane Journal
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    • v.31 no.2
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    • pp.145-152
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    • 2021
  • While there are increasing demands on biomolecules separation, resin chromatography lacks in terms of throughput and membrane chromatography is an alternative with high binding capacity and enhanced mass transfer properties. Unlike typical membrane processing, where the performance can only be empirically assessed, understanding how mechanisms work in membrane chromatography is decisive to design biospecific processing. This short review covers three separation mechanisms, including affinity interaction modes for selectively capturing bulk molecules using biospecific sites, ion exchange modes for binding biomolecules using net charges and hydrophobic interaction modes for binding targeted, hydrophobic species. The parameters in designing membrane chromatography that should be considered operation-wise or material-wise, are also further detailed in this paper.

Quantitative Real-Time PCR Assay for Detection of Paenibacillus polymyxa Using Membrane-Fusion Protein-Based Primers

  • Cho, Min Seok;Park, Dong Suk;Lee, Jung Won;Chi, Hee Youn;Sohn, Soo-In;Jeon, Bong-Kyun;Ma, Jong-Beom
    • Journal of Microbiology and Biotechnology
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    • v.22 no.11
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    • pp.1575-1579
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    • 2012
  • Paenibacillus polymyxa is known to be a plant-growth-promoting rhizobacterium. The present study describes a quantitative polymerase chain reaction (qPCR) assay for the specific detection and quantitation of P. polymyxa using a primer pair based on the sequence of a membrane-fusion protein for the amplification of a 268 bp DNA fragment. This study reports that the qPCR-based method is applicable for the rapid and sensitive detection of P. polymyxa and can be used as an alternative method for agricultural soil monitoring.

Polyamide-imide Torlon as Membrane Materials

  • Yoshikawa, Masakazu;Higuchi, Ako;Guiver, Michael D.;Robertson, Gilles P.
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.65-68
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    • 2004
  • Molecular imprinting, which was first proposed by Wulff and Sarhan in 1972 [1], is a facile way to construct molecular recognition sites by applying a simple radical polymerization [2]. Since 1994, the authors have proposed an alternative molecular imprinting method in which polymeric materials are directly converted into molecular recognition materials [3].(omitted)

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Insight into Complexation of Olefin with Silver Ions Dissolved in Poly(n-butyl methacrylate)

  • Dongkyun Ko;Lee, Kyung-Min;Lee, Kwi-Jong;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.136-139
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    • 2004
  • Olefin/paraffin separation by the facilitated transport membrane using silver salts as carriers has been considered as a promising alternative to the conventional energy intensive distillation process. The basis for the separation is the ability of silver ions to react reversibly with olefin forming silver-olefin complexes.(omitted)

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Cell attachment and proliferation of osteoblast-like MG63 cells on silk fibroin membrane for guided bone regeneration

  • Yoo, Chae-Kyung;Jeon, Jae-Yun;Kim, You-Jin;Kim, Seong-Gon;Hwang, Kyung-Gyun
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.38
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    • pp.17.1-17.6
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    • 2016
  • Background: The aim of this study is to verify the feasibility of using silk fibroin (SF) as a potential membrane for guided bone regeneration (GBR). Methods: Various cellular responses (i.e., cell attachment, viability, and proliferation) of osteoblast-like MG63 cells cultured on an SF membrane were quantified. After culturing on an SF membrane for 1, 5, and 7 days, the attachment and surface morphology of MG63 cells were examined by optical and scanning electron microscopy (SEM), cell viability was determined using a 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay, and cell proliferation was quantified using 4',6-diamidino-2-phenylindole (DAPI) fluorescence staining. Results: Optical microscopy revealed that MG63 cells cultured on the SF membrane proliferated over the 7-day observation period. The viability of cells cultured on SF membranes (SF group) and on control surfaces (control group) increased over time (P < 0.05); however, at respective time points, cell viability was not significantly different between the two groups (P > 0.05). In contrast, cell proliferation was significantly higher in the SF membrane group than in the control group at 7 days (P < 0.05). Conclusions: These results suggest that silk fibroin is a biocompatible material that could be used as a suitable alternative barrier membrane for GBR.

Characteristics of sPAES Membrane and sPEEK Membrane for Direct Formic Acid Fuel Cell (직접개미산 연료전지용 전해질막으로서 sPAES 막과 sPEEK 막의 특성)

  • Jeong, Jae-Hyeon;Song, Myung-Hyun;Chung, Hoi-Bum;Lee, Moo-Seok;Lee, Dong-Hoon;Chu, Cheun-Ho;Na, Il-Chai;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.690-694
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    • 2015
  • Recently, direct formic acid fuel cells (DFAFC) among direct liquid fuel cells is studied actively. Economical hydrocarbon membranes alternative to fluorinated membranes for DFAFC's membrane are receiving attention. In this study, characteristics of sulfonated poly(ether ether ketone, sPEEK) and sulfonated poly(arylene ether sulfone, PAES) membranes were compared with Nafion membrane at DFAFC operation condition. Formic acid crossover current density of hydrocarbon membranes were lower than that of Nafion 211 fluorinated membrane. I-V performance of sPEEK MEA(Membrane and Electrode Assembly) was similar to that of Nafion 211 MEA due to similar membrane resistance each other. sPEEK MEA with low formic acid crossover showed higher stability compared with Nafion 211 MEA.

Sensitivity Analysis of Initial Pressure and Upper Control Limit on the Pressure Decay Test for Membrane Integrity Evaluation (압력손실시험을 이용한 막 완결성 평가에서 초기압력 및 UCL 도출인자 민감도 분석)

  • Lee, Joohee;Hong, Seungkwan;Hur, Hyunchul;Lee, Kwangjae;Choi, Youngjune
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.793-800
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    • 2008
  • Recently domestic drinking water industry has recognized membrane-based technology as a promising alternative for water treatment. To ensure successful application of membrane processes, the integrity of membrane systems should be maintained. According to US EPA guidance, the pressure decay test based on the bubble point theory is recommended to detect any membrane defection of which size is close to the smallest diameter of Cryptosporidium oocysts, $3{\mu}m$. Proper implementation of the pressure decay test is greatly affected by initial test pressure, and the interpretation of the test results is associated with upper control limit. This study is conducted to investigate various factors affecting determination of initial test prtessure and upper control limit, including membrane-based parameters such as pore shape correction factor, surface tension and contact angle, and system-based parameters, such as volumetric concentration factor and total volume of system. In this paper, three different hollow fibers were used to perform the pressure decay test. With identical initial test pressure applied, their pressure decay tendency were different from each other. This finding can be explained by the micro-structure disparity of those membranes which is verified by FESEM images of those membranes. More specifically, FESEM images revealed that three hollow fibers have asymmetry, deep finger, shallow finger pore shape, respectively. In addition, sensitivity analysis was conducted on five parameters mentioned above to elucidate their relation to determination of initial test pressure and upper control limit. In case of initial pressure calculation, the pore shape correction factor has the highest value of sensitivity. For upper control limit determination, system factors have greater impact compared to membrane-based parameters.

Research Trend of Organic/Inorganic Composite Membrane for Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지용 유.무기 복합막의 연구개발동향)

  • Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.155-170
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    • 2012
  • Fuel cells have been considered as alternative power generation system in the twenty-first century because of eco-friendly system, high power density and efficiency compare with petroleum engine system. Proton exchange membranes (PEMs) are the key components in fuel cell system. Currently, Nafion has been used in fuel cell system. However, Nafion has disadvantages such as low conductivity at high temperature and high cost. The researchers have focused to reach the high properties such as high proton conductivity, low permeability to fuel, good chemical/thermal stability, good mechanical properties and low manufacturing cost. Various methods have been developed for preparation of proton exchange membrane with high performance and commercialization of fuel cell system. The hybrid organic/inorganic membrane has the potentials to provide a unique combination of organic and inorganic properties with improved proton conductivity and mechanical property at high temperatures. So, this paper presents an overview of research trend for the composite membranes prepared by organic/inorganic system using various inorganic materials.