• Title/Summary/Keyword: alkali soluble

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Changes of Sugar Components in Cell Wall Polysaccharides from Tomato Fruits during Ripening (토마토 과실의 성숙중 세포벽 구성다당류의 변화)

  • Mun, Gwang-Deok;Cheon, Seong-Ho;Kim, Jong-Guk
    • Food Science and Preservation
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    • v.3 no.2
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    • pp.113-120
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    • 1996
  • This study was conducted to understand the characteristics of fruit softening during ripening which causes deep loses in quality of horticultural products during storage and marketing process after harvest. The changes of cell wall components during ripening was investigated. The climacteric rise was between 42 and 49 days after anthesis and then decreased. Ethylene evolution was similar to respiration. The hardness of fruit decreased markedly at this climacteric period and significances of textural parameters among the ripening periods were recognized but the significance between 50 and 55 days after anthesis was not. Sugar components of cell wall polysaccharides were uronic acid, galactose, glucose, arabinose, xylose, rhamnose, mannose and fucose. The contents of arabinose and mannose in alcohol-insoluble solids fraction increased, but other sugars were not changed. In cell wall fraction, the contents of uronic acid, galactose, glucose and arabinose were comparatively high, but galactose, arabinose and ironic acid were decreased markedly during ripening. ironic acid occupied above 75% of total monosaccharide in pectin fraction and decreased markedly during ripening. In acid-soluble hemicellulose fraction, the contents of uronic acid, glucose, galactose and rhamnose were high and they decreased from 50 days after anthesis. The contents of glucose and xylose were high in a alkali-soluble hemicellulose fraction and they decreased markedly at 55days after anthesis.

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위령선의 성분연구 제2보 Clematis brachyura Maxim의 flavone에 대하야

  • heo, Geom;Park, Su-Seon
    • YAKHAK HOEJI
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    • v.2 no.1_2
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    • pp.11-15
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    • 1953
  • Two flavons, which are a new flavon (the Authors are going to call it "CLEMATISIN") and a yellow crystalline flavon, are isolated from leaves of Clematis brachura Maxim. Clamatisin : A colorless needle crystal which has a Slightly sweet taste, mp 225 .deg.C (decomp). It is positive (Cherry red) for the Mg-HCl(Hg) reaction and is positive (purple) for the $FeCL_{3}$ reagent. It is soluble easily in methanol, ether, acetone, prydine, ethylacetate, hot water and alkali-solutions. It is soluble slightly in cold water and is insoluble in chloroform, benzene and toluence. According to the results of elementry analysis and molecular weight determination the formula of clematisin agrees with $C_{18}H_{18}O_{7}$ when dried at $80^{\circ}C$, crystalline clematisin (from water) contains one molecule of crystalline water. The following derivatives are prepared ; Clematisin-oxim; a colorless needle crystal, mp 215-216 .deg.C, Clematisin methylate; prepared by diazomethan. mp 191-$192^{\circ}C$ a colorless needle crystal. Acethylmethylate; a colorless powder, It is not sharp in melting point and melts at approximately $215^{\circ}C$, Yellow Crystalline Flavon; mp 285-$286^{\circ}C$ (dexo-mp.), yellow needle crystal. It has a slightly sweet teste and shows positive reaction Acetate; a colorless needle crystal, mp $168^{\circ}C$.

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Solute patterns of four halophytic plant species at Suncheon Bay in Korea

  • Choi, Sung-Chul;Choi, Deok-Gyun;Hwang, Jeong-Sook;Kim, Jong-Guk;Choo, Yeon-Sik
    • Journal of Ecology and Environment
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    • v.37 no.3
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    • pp.131-137
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    • 2014
  • To investigate the solute pattern of salt marsh plants in Suncheon Bay in Korea, plants and soil samples were collected at three sites from July to September 2011. The soil pH around the investigated species was weakly alkaline, 6.9-8.1. The total ion and Cl- content of site 1 gradually increased, while those of site 2 and site 3 were lowest in August and highest in September. The exchangeable $Ca^{2+}$, $Mg^{2+}$ and $K^+$ in the soil were relatively constant during the study period, but the soil exchangeable $Na^+$ content was variable. Carex scabrifolia and Phragmites communis had constant leaf water content and very high concentrations of soluble carbohydrates during the study period. However, Suaeda malacosperma and S. japonica had high leaf water content and constant very low soluble carbohydrate concentrations. Carex scabrifolia accumulated similar amounts of $Na^+$ and $K^+$ ions in its leaves. Phragmites communis contained a high concentration of $K^+$ ions. Suada japonica and S. malacosperma had more $Na^+$ and $Cl^-$ ions than $K^+$ ions in their leaves. Suaeda japonica had higher levels of glycine betaine in its leaves under saline conditions than C. scabrifolia and P. communis. Consequently, the physiological characteristics of salt marsh chenopodiaceous plants (S. japonica and S. malacosperma) were the high storage capacity for inorganic ions (especially alkali cations and chloride) and accumulation of glycine betaine, but monocotyledonous plant species (C. scabrifolia and P. communis) showed high $K^+$concentrations, efficient regulation of ionic uptake, and accumulation of soluble carbohydrates. These characteristics might enable salt marsh plants to grow in saline habitats.

Elicitors which Induce the Accumulation of p-Coumaroylamino Acids in Ephedra distachya Cultures

  • Song, Kyung-Sik;Sankawa, Ushio;Ebizuka, Yutaka
    • Archives of Pharmacal Research
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    • v.17 no.1
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    • pp.26-30
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    • 1994
  • Some ammonium oxalate soluble pectic fragments prepared from cultured cell wall of Ephycla distrahya elicited the accumulation of p-coumarocylamino acids (p-CAA) in E. distachya cultures while water soluble and alkali soluble fractions had no activity. Partial purification of the pectic fragments fraction using DEAE-cellulose chromatography afforded two active fractions (PS-I and PS-II) which were composed of mainly uronic acids (98-99 w/w %). They elicited the accumulation of p-CAA in an amount of 52-60 nmol per gram fresh weight of cultures. The acidic sugar compositions of PS-I and PS-II were found to be galacturonic acid and glucuronic acid by TLC analysis. They were supposed to act as endogenous elicitors of p-CAA accumulation. In order to investigate the effect of ethylene on p-CAA accumulation, Ethrel, which is known as ethylene generator, and ACC(1-aminocyclopropane-1-carboxylic acid), a direct precusor of ethylene biosynthesis, were added to the culture. However, they did not glycopeptide elicitor [(Con A-II)], either. Consequently, no relationships between ethylene and p-CAA accumulation were recognized. Several tentative elicitors were teted for their activity. Commercial yeast glucan, $CuCl_2$, laminarin and laminariheptaose had slight activity whereas ${\alpha}$-methylmannopyranoside and commercial yeast mannan had no elicitor activity. ${\alpha}$-methylmannopyranoside which has been known as a tentative inhibitor of glucan elicitor in Glycine max did not affect on the elicitor activity of Con A-II.

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Studies on the cellular metabolism in microorganisms as influenced by gamma-irradiation.(IV) "on the carbohydrate metabolism of yeast irradiated by $\gamma$-ray." (미생물의 세포생리에 미치는 전이방사선의 영향에 관한 연구 (제 4 ) -효모균의 수화물대 에 대한 $\gamma$-의 영향에 대하여-)

  • 김종협
    • Korean Journal of Microbiology
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    • v.6 no.2
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    • pp.41-53
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    • 1968
  • Studies on the carbohydrate metabolism of yeast as influenced by gamma-irradiation from cobalt-60 have been carried, then the mechanisms of radiation effect on respiration and fermentation were discussed under considerations of permeable changes of irradiated cell membrane. The cells of baker's yeast (Saccharomyces cerevisiae) which had been gamma-irradiated of 240 k.r. doses for an hour, then were put into aerobic oxidation and anaerobic fermentation without substrate. Total and fractionated carbohydrates of irradiated yeast cells were determined by calorimetric method with anthrone and orcinol reagents, the amounts of total carbohydrate, trehalose, RNA-ribose, PCA-soluble glycogen, alkali-soluble glycogen, acetic acid-soluble glycogen, mannan and glucan were determined according to the course of aerobic oxidation and anaerobic fermentation. It is found that the carbohydrates of irradiated cells leak out and amount of the losses teaches eleven times more than that of control, the volume of losses are seems to be replaced by water, it can be suggested the damage of gamma-irradiation occurs in the site of passive transport of cell membrane. The endogeneous aerobic respiration of irradiated cells are increased much more than control, the synthesis of reserve glycogen, glucan and RNA-ribose promoted much more than control. The anaerobic fermentation of irradiated cells are also increased than that of control, but the breakdown of carbohydrate is less than endogeneous respiration of irradiated cells. The synthetic rate is also less than that of aerobic oxidation. In irradiated yeast cells, trehalose is revealed to be primary substrate for endogeneous carbohydrate metabolism, so it is proved that the enzymic patterns are not changed but the activities of enzymes relating endogeneous respiration and autofermentation is activated. It is to be considerable to distiguish endogeneous respiration and autofermentation from exogeneous respiration and fermentation on irradiation, for membrane permeability changes and loses out carbohydrate by ionizing radiation.

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Valorization of bottom ash with geopolymer synthesis: Optimization of pastes and mortar

  • Froener, Muriel S.;Longhi, Marlon A.;de Souza, Fabiana;Rodriguez, Erich D.;Kirchheim, Ana Paula
    • Advances in concrete construction
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    • v.14 no.1
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    • pp.1-13
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    • 2022
  • Due to the physical-chemical characteristics of some bottom ash (BA), there are technical, economic and environmental limitations to find a destination that will add value to it. In Brazil, this residue is eventually used for filling coal extraction pits or remains in sedimentation ponds, creating a susceptible panorama to environmental issues. The geopolymers binders are one of the alternatives to the proper use high amounts of these materials. In this work, geopolymeric binder pastes were produced with BA mixed to activators with different alkali contents (expressed as %Na2O), as well as the incorporation of soluble silicates (Ms content). The production of binary geopolymeric pastes based on the use of two industrial wastes: fluid catalytic cracking (FCC) and aluminum anodizing sludge (AAS), was also assessed. The content in mass of BA/FCC and BA/AAS ranged from 100/0, 90/10; 80/20 and 70/30. Systems with soluble silicates as activator in a molar ratio SiO2/Na2O of 1.0 (Ms = 1.0) and Na2O content of 15%, showed the best results of mechanical strength (42 MPa at day 28th). The improvement is up to 5X when compared to NaOH based systems. For systems with partial replacement of BA of 10% of AAS and 20% of FCC (80/20), the presence of soluble silicates was also effective to increase compressive strength.

Properties and Glue Shear Strength of the Water Soluble Urea-Phenol Copolymer Adhesive as a High Temperature Curing Binder for Plywood (합판용(合板用) 고온경화형(高温硬化型) 수용성(水溶性) 요소(尿素)·페놀공축합수지(共縮合樹脂)의 성질(性質)과 그 접착강도(接着強度))

  • Lee, Hwa Hyoung
    • Journal of Korean Society of Forest Science
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    • v.60 no.1
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    • pp.51-57
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    • 1983
  • Properties and glue shear strength of each water soluble rues-phenol copolymer adhesive and phenolic resin adhesive were examined as a high temperature curing binder through the manufacture of plywood made of Kapur veneer. The former has different molar ratio and the latter was made from different catalyst method. The results are summarized as follows: 1) Specific gravities of air dried plywood manufactured from each adhesive ranged from 0.67 to 0.82 and their moisture contents met the K.S. standard 2) In dry and wet shear strength, adhesives with 60 percent of non volatile content showed higher values than those with 50 percent except phenolic resin. Urea-phenol copolymer resin with 20 percent of phenol content exhibited the highest, and that with 70 percent the lowest. Filling effect of wood flour on the bonding strength is great in urea-phenol copolymer resin with more than 50 percent of phenol content, especially significant in 50 percent of non volatile content including alkali catalyst phenolic resin. Alkali and acid catalyst methods were the highest among the adhesive manufacture methods. In wet strength, urea resin belongs to the lowest group. 3) In glue shear strength after boiling and drying test, no method for manufacturing phenolic formaldehyde resin adhesive was stronger than alkali and acid catalyst methods. Phenolic resin made from alkali catalyst method needs a wood flour filler to improve the bonding quality. Urea-phenol copolymer resin with 10 percent of phenol content showed the reasonable water resistance.

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Contents of $\beta$-Glucan in Various Cereals and Its Functional Properties

  • Whang, Key
    • Preventive Nutrition and Food Science
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    • v.3 no.4
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    • pp.382-386
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    • 1998
  • A soluble dietary fiber, $\beta$-glucan, contained in oat and barley has nutritional benefits such as hypocholesterolemic effects and influences blood glucose regulation. The contents of $\beta$-glucan in both cereals range from 3 to 7% with the exception of a certain barley genotype which contains up to 16% $\beta$-glucan. $\beta$-Glucan is distributed mainly in the cell walls of endosperm and the distal (bran) portion of kernel. Various procedures have been developed for increasing the extraction yield of $\beta$-glucan. Oat gum prepared with weak alkali extractionand alcohol proecipitation following protein removal usually contains 80% $\beta$-glucan.The most commonly used method for $\beta$-glucan quantitiation is an enzymatic procedure combining lichenase plus $\beta$-glucosidase followed by measuring the amount of glucos released by glucose oxidase-peroxidase treatment. The increase in foam-and emulsion-stabilizing capacity of $\beta$-glucan is due to the increase in viscosity of the aqueous phase. Therefore, $\beta$-glucan shows great potentials as a thickener and a stabilizer.

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Food Components of Coho Salmon and Rainbowtrout (은연어와 무지개 송어의 식품성분)

  • 김경삼;최영준
    • The Korean Journal of Food And Nutrition
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    • v.6 no.2
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    • pp.73-80
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    • 1993
  • In order to examine food components of coho salmon and rainbow-trout, We analyzed the composition of protein, amino acids and total lipids. The coho salmon muscle contained about 19.3% of protein with the composition of 29.9% in sarcoplasmic protein, 56.3oA in myofibrillar protein 12.5% alkali soluble protein and 2.6% in stroma. Those of rainbow-trout contained 34.1%, 56.4%, 8.3% and 2.9%, respectively. The sarcoplasmic and myofibrillar protein were composed of 13 subunits in coho salmon, and 16 and 15 subunits in rainbow-trout. Judging from the contents of essential amino acids, both muscle proteins were complete proteins. The most remarkable feature of free amino acids was that a large amount of dipeptide anserine was present with fairly lower levels of 1 methyl histidine, taurine, histidine, alanine and glycine in both muscle extracts. The total fatty acids of coho salmon was composed of 31.49% polyenes, 43.79% monoenes and 24.73% saturates. The composition of total fatty acid of coho salmon muscle was not different from that of rainbow-trout muscle.

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Alkali Hydrolysis of Insoluble Sericin (불용성 세리신의 알칼리 가수분해)

  • 김정호;배도규
    • Journal of Sericultural and Entomological Science
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    • v.42 no.1
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    • pp.31-35
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    • 2000
  • When insoluble sericin was hydrolyzed by treatment of NaOH solution, the solubility was increased with higher treatment temperature and longer treatment time. Whereas it was decreased in addition of NaHSO$_3$. As the results of electrophoresis in sericin powder obtained by the NaOH treatment, a distinguishable band was not confirmed. Average degree of polymerizations(A.D.P.) of sericin hydrolyzed by NaOH solutions were about 19.6∼22.1 and average molecular weight(M.W.) were about 2,200∼2,500. The longer hydrolysis time increased the whiteness of sericin powder. As the results of amino acid analysis, the contents of Thr., Tyr., and Ser. were decreased in NaOH hydrolysis as compared to HCl hydrolysis. In DSC analysis, thermal deformation and pyrolysis peak located at near 230$\^{C}$ and 320$\^{C}$, respectively.

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