Alkali Hydrolysis of Insoluble Sericin

불용성 세리신의 알칼리 가수분해

  • 김정호 (경북대학교 천연섬유학과) ;
  • 배도규 (경북대학교 천연섬유학과)
  • Published : 2000.06.01

Abstract

When insoluble sericin was hydrolyzed by treatment of NaOH solution, the solubility was increased with higher treatment temperature and longer treatment time. Whereas it was decreased in addition of NaHSO$_3$. As the results of electrophoresis in sericin powder obtained by the NaOH treatment, a distinguishable band was not confirmed. Average degree of polymerizations(A.D.P.) of sericin hydrolyzed by NaOH solutions were about 19.6∼22.1 and average molecular weight(M.W.) were about 2,200∼2,500. The longer hydrolysis time increased the whiteness of sericin powder. As the results of amino acid analysis, the contents of Thr., Tyr., and Ser. were decreased in NaOH hydrolysis as compared to HCl hydrolysis. In DSC analysis, thermal deformation and pyrolysis peak located at near 230$\^{C}$ and 320$\^{C}$, respectively.

Keywords

References

  1. Chemistry of Natural Protein Fibers Asquith R. A.
  2. 北條舒正編 續絹絲の構造 小松計一
  3. Biosci. Biotechnol. Biochem. v.62 no.1 Silk Protein, Sericin, Inhibits Lipid Peroxidation and Tyrosinase Activity Kato Norithisa;Sato Seiji;Yamanaka Atsusshi;Yamada Hideyuki;Fuwa Naozumi;Nomura Masakazu
  4. 이화학사전 김병희(외15인)
  5. 신정력표백 김인규
  6. 韓蠶學誌 v.41 no.1 불용성 세리신의 산 가수분해 김정호;배도규
  7. 人にやさしぃ纖維と加工 山本和秀