• Title/Summary/Keyword: alcohol mixture

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Effect of Red Ginseng Water Extract on Trypsin Activity (홍삼 물추출물이 Trypsin 활성에 미치는 영향)

  • Lee, Jong-Won;Kim, Na-Mi;Do, Jae-Ho
    • Journal of Ginseng Research
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    • v.28 no.3
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    • pp.127-131
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    • 2004
  • This study was carried out to investigate the effect of red ginseng water extract (RGWE) on trypsin activity. After extraction of fat soluble and saponin component from red ginseng powder by methyl alcohol, the residue was extracted with distilled water, and manufactured to water extract. The extract was dialyzed with different molecular cut off membrane. Trypsin activity demonstrated the highest level at the RGWE concentration of 9${\times}$10$\^$-2/% in reaction mixture, and also increased to 15% at 2.9${\times}$10$\^$-3/%. Km value was decreased and Vmax was increased in the present of red ginseng water extract. Red ginseng water extract was partially purified by dialysis, Bio-Gel P-I0 and DEAE-cellulose column chromatography. The active fraction demonstrated positive reaction to ninhydrin, DNS and folin reaction.

Basic Mixing and Mechanical Tests on High Ductile Fiber Reinforced Cementless Composites (고인성 섬유보강 무시멘트 복합체의 기초 배합 및 역학 실험)

  • Cho, Chang-Geun;Lim, Hyun-Jin;Yang, Keun-Hyeok;Song, Jin-Kyu;Lee, Bang-Yeon
    • Journal of the Korea Concrete Institute
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    • v.24 no.2
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    • pp.121-127
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    • 2012
  • Cement has been traditionally used as a main binding material of high ductile fiber reinforced cementitious composites. The purpose of this paper is to investigate the feasibility of using alkali-activated slag and polyvinyl alcohol (PVA) fibers for manufacturing high ductile fiber reinforced cementless composites. Two mixture proportions with proper flowability and mortar viscosity for easy fiber mixing and uniform fiber dispersion were selected based on alkali activators. Then, the slump flow, compression, uniaxial tension and bending tests were performed on the mixes to evaluate the basic properties of the composites. The cementless composites showed an average slump flow of 465 mm and tensile strain capacity of approximately 2% of due to formation of multiple micro-cracks. Test results demonstrated a feasibility of manufacturing high ductile fiber reinforced composites without using cement.

A Novel Method for Preparing of Oxoruthenates Complexes: trans-[RuO3(OH)2]2-, [RuO4]-, (n-Pr4N)+[RuO4]- and [RuO4 and Their Use as Catalytic Oxidants

  • Shoair, Abdel-Ghany F.
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1525-1528
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    • 2005
  • The synthesis and characterization of ${K_3[Ru(C_2O_4)3]{\cdot}4H_2O\;(C_2O_4}^{2-}$ = oxalato anoin) complex are described, and its redox properties (in buffer solution of pH = 12) have been investigated. This complex is used for in situ generation of oxoruthenates complexes which have been characterized by electronic spectroscopy. Reaction of ${K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ with excess ${S_2O_8}^{2-}$ in molar KOH generates trans-${[RuO_3(OH)_2]^{2-}/S_2O_8}^{2-}$ reagent while with excess ${BrO_3}^-$ in molar $Na_2CO_3$ generates ${[RuO_4]^-/BrO_3}^-$ reagent. Avoiding the direct use of [$RuO_4$] the organic-soluble $(n-Pr_4N)^+[RuO_4]^-$, (TPAP) has been isolated by reaction of $K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ with excess ${BrO_3}^-$ in molar carbonate and n-$Pr_4$NOH. In a mixture of $H_2O/CCl_4$ ruthenium tetraoxide can be generated by reaction of $K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ with excess ${IO_4}^-$. The catalytic activities of oxoruthenates that have been made from $K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ towards the oxidation of benzyl alcohol, piperonyl alcohol, benzaldehyde and benzyl amine at room temperature have been studied.

The Preparation of NiCuZn Ferrite Slurry Using the Water Mixed Binder System (수계 바인더를 이용한 NiCuZn Ferrite의 슬러리 제조)

  • 류병환;이정민;고재천
    • Resources Recycling
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    • v.7 no.4
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    • pp.35-42
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    • 1998
  • Surface mount technology is the biggest theme in the area of deιIronic component. To miniatunze an electronic component, s such as ferrite chip inductor, the cer뼈lic wet process for green-sheet lamination and/or screen printing method through a s solvent medium system is widely used. The preparation and characterization of NiCuZn Ferrite (NCZF) shurry and the green s sheet using the water mixed binder system has been studied. The 21 vol% of NCZF slurry was prepared by a ball milling. The p polyacrylic vinyl copolymer (Mw; 60,000) was used as a binder. Th$\xi$ mixture of distilled water, isopropyl alcohol (IPA) and 2l butoxy ethanol was used as a dispersion medium. The water content of medium varied from about 40% to 80%. As the results. Thc disp$\xi$rston stability of the NCZF slurry was attributed to the free polymer rather than the electrostatic force of the particle. T The viscosity of the NCZF slurry was greatly depended on the ratio of water content in the medium.

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Effects of Type of Synthetic Fiber on Material Properties of Cementless Composite (합성섬유 종류가 무시멘트 복합재료의 재료 거동에 미치는 영향)

  • Choi, Jeong-Il;Park, Se-Eon;Cha, Sang Lyul;Lee, Bang Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.255-261
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    • 2019
  • The purpose of this study is to investigate effects of types of synthetic fibers on mechanical properties of alkali-activated slag composite. Materials and mixture proportion for matrix are determined, and the compressive strength, tensile performance, and cracking patterns of three composites reinforced by polypropylene, polyvinyl-alcohol, and polyethylene fibers. From the test results, it was observed that polyvinyl-alcohol fiber-reinforced composite and polyethylene fiber-reinforced composite had similar tensile performance. On the other hand, polypropylene fiber-reinforced composite showed low tensile performance. And it was exhibited that other factors except tensile strength and aspect ratio of fiber influence significantly tensile behavior of composite.

Pervaporation of binary Water/Methanol and Water/Butanol Mixtures through Zeolite 4A Membranes: Experiments and Modeling (제올라이트 4A 분리막을 이용한 물/메탄올, 물/부탄올 혼합물의 투과증발 특성 연구: 실험 및 모형)

  • Oh, Woong-Jin;Jung, Jae-Chil;Yeo, Jeong-gu;Lee, Jung Hyun;Kim, Hyunuk;Park, Young Cheol;Lee, Dong-Ho;Moon, Jong-Ho;Cho, Churl-Hee
    • Membrane Journal
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    • v.27 no.6
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    • pp.487-498
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    • 2017
  • In this study, pervaporation performances of water/methanol and water/butanol mixture were evaluated using zeolite 4A membranes manufacutred by FINETECH by experimental works and numerical modeling. Permeation and separation characteristics, such as flux and separation factor, were analyzed by gas chromatography (TCD) and liquid nitrogen traps. Experiments have shown that water is selectively separated from a mixture of water and methanol (separation factor up to approximately 250) and water and butanol (separation factor up to approximately 1,500). Generalized Maxwell Stefan (GMS) theory was implemented to predict pervaporation behaviors of water/alcohol mixtures and diffusional coefficients of zeolite layer were obtained through parameter estimation using $MATLAB^{(R)}$ optimization toolbox. Since the pore size of zeolite 4A are much larger than kinetic diameter of water molecules and smaller than those of methanol and butanol, zeolite 4A membranes can be applied to in situ water removal process such as membrane reactors or hybrid reaction-dehydration process.

Homogeneous Preparation of Barium Titanate by Dimethyl Oxalate in Ethanol Solution (에탄올 용액에서 Dimethyl Oxalate에 의한 티탄산바륨의 균일한 제조)

  • Ryu, Kyoung-Youl;Lim, Myoung-Hee;Huh, Woo-Young;Lee, Chul
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.382-386
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    • 1999
  • Spherical particles of barium titanyl oxalate(BTO) were homogeneously precipitated by thermal decomposition of dimethyl oxalate in hydrochloric mixture solutions of water and ethanol. The experimental parameters such as composition of the mixture solvents. the eoncentration of hydrochloric acid and reaction temperature had the paramount effect on the size of panicles collected from the bottom of the reaction vessel at the aging time of 120 min and the composition of BTO. Stoichiometric BTO powders were obtained under certain conditions as relatively low alcohol content in the mixtures, high chloride concentration and high temperature, Monosized, submicrometer, but titanium excess particles were obtained under certain reverse conditions.

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Preparation and Characterization of PVAL/PVP/Hexylene Glycol/Chitosan Hydrogels by $\gamma$-Ray ($\gamma$-선을 이용한 PVAL/PVP/헥실렌 글리콜/키토산 수화젤의 제조 및 특성)

  • 최은경;김형일;노영창
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.349-357
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    • 2003
  • Hydrogels for wound dressing from a mixture of poly(vinyl alcohol) (PVAL), poly(N-vinyl pyrrolidone) (PVP), hexylene glycol (HG) and chitosan were made. The hydrogels were obtained by physical crosslinking of freezing and thawing, chemical crosslinking of irradiation, and irradiation after freezing and thawing of mixture solutions. The solid concentration of PVAL/PVP/HG/chitosan was 15 wt%. The concentration of chitosan was 0.3 wt%, and the ratio of PVAL/PVP was 6:4. The concentration of HG was in the range of 1∼5 wt%. The number of repeated freezing and thawing was in the range of 1∼3 times, and gamma irradiation doses were 25, 35 and 50 kGy. The physical properties such as gelation, water absorption and gel strength of hydrogels were examined. Gel content and gel strength decreased as HG concentration increased, whereas degree of swelling increased. Gel content and gel strength increased as irradiation dose and the number of freezing and thawing increased, whereas degree of swelling decreased. The hydrogels were evaluated for the healing effect for animals and for the antibacterial effect.

Determination of Air Fuel Ratio according to Fuel Composition (I) -Eltinge Chart as a Reference Exhaust Composition- (연료 조성에 따른 공연비 산정 (I) -기준 배기 조성으로서 Eltinge 차트-)

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.11
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    • pp.1548-1562
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    • 2003
  • This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

Effects of Vehicles and Penetration Enhancers on the Percutaneous Absorption of Apomorphine (기제와 피부투과촉진제가 아포모르핀의 피부투과에 미치는 영향)

  • Choi, Young-Geun;Cui, Yu;Kim, Keun-Nam;Park, Eun-Seok;Chi, Sang-Cheol
    • Journal of Pharmaceutical Investigation
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    • v.33 no.2
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    • pp.129-133
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    • 2003
  • In order to evaluate the effects of vehicles and penetration enhancers on skin permeation of apomorphine, the skin permeation rates of apomorphine from vehicles of different composition were determined using Franz diffusion cells fitted with excised rat skins. Solubility of apomorphine in various solvents was investigated to select a vehicle suitable for the percutaneous absorption of apomorphine. The solvents used were propylene glycol (PG), $Transcutol^{\circledR},\;Labrasol^{\circledR},\;Labrafac hydro WL^{\circledR},\;Labrafil WL 2609 BS^{\circledR}$ and isopropyl alcohol. Even though permeation rates of apomorphine from each vehicle were low $(0.008-0.36\;{\mu}g/cm^2/hr)$, the combination of PG and $Labrafac^{\circledR}$ increased it significantly. The permeation rates of apomorphine from $PG/Labrafac^{\circledR}$ mixtures increased as the volume fraction of PG in the mixture increased. The maximum permeation rate of $18\;{\mu}g/cm^2/hr$ was achieved at 30% of PG, which decreased with further increase of PG fraction. A series of fatty acids, alcohols and monoterpenes were employed as penetration enhancers. Incorporation of each enhancer in the $PG/Labrafac^{\circledR}$ (30:70) mixture at the level of 10% improved the skin permeation significantly. The highest permeation rate, $117\;{\mu}g/cm^2/hr$, was attained with myristic acid.