• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1659-1664
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• 2014

A porous metal-organic framework (MOF), MIL-101, was synthesized in the presence of sulfated zirconia (SZ) to produce acidic SZ/MIL-101 composites for the first time. The composites were characterized with XRD, nitrogen adsorption, FT-IR, scanning electron microscope, chemical analysis and so on. The composites (SZ/MIL-101s) were successfully applied in a liquid-phase esterification for a high yield of ester. This catalytic result of SZ/MIL-101, compared with that of pure SZ or MIL-101 (showing a negligible yield of ester), suggests that the SZ in the composite is highly active in the acid catalysis probably because of the well-dispersed active species of SZ. Moreover, the esterification is catalyzed in heterogeneous mode as confirmed by negligible esterification after filtration of the catalyst. Finally, microwaves can be efficiently applied both in the synthesis of the composites and the esterification reaction to accelerate the two processes of synthesis and esterification by about 5 times.

• 한국자동차공학회논문집
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• 제16권6호
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• pp.168-175
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• 2008

In-use light duty diesel vehicles are considered as one of major sources of particulate emissions in many cities, and the start of the retrofit program for the light duty diesel vehicles is expected in near future in Korea. One of the problems of the retrofit of the light duty diesel vehicles is that the exhaust gas temperature is too low to apply passive regeneration DPF systems. This study introduces a catalytic combustor as a new active DPF regeneration technology. This study shows the principle and characteristics of DPF regeneration by the catalytic combustor and suggests it's proper control method for better regeneration.

• 건축역사연구
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• 제1권1호
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• pp.117-128
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• 1992

The purpose of this paper is to clarify the introduction of foreigner's architectural engineering such as building materials techniques engineers, focused on the Late Yi-dynasty. Such all kind of building materials as timber brick tile cement lime glass window furniture and so on was imported from the foreign company in opening period of ports in Cho-son. The timer of these materials was imported from Japan, the brick tile from China, and others directly from Western counteries indirectly from Japan China. As it was active in an inflow of building materials and machines about 1890's, the modern building techniques were introduced and elementarily mastered such as timber sewing, manufacturing baking of brick glass, and masonry, The above modern techniques became the direct background in the formation of Korean modern architecture. Building engineers can be divided into three classes : architect engineer apprentice. But It could be apparently not divided the relation between architect and engineer at that time. They could be classified into job-architects who were engaged by the Korean government and leaded an active life in their settlement, and missonaries, They introduced the construction and style of modern architecture in our country, And so many skilled laborers and laborers participated in the construction of their settlement.

• International Journal of Industrial Entomology and Biomaterials
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• 제29권2호
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• pp.179-184
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• 2014

Silkworm (Bombyx mori ) feces have long been used in the pharmaceutical and food industries as a natural colorant. However, there is limited data on the bioactive compounds that constitute silkworm feces. This research emphasizes the antioxidant activity of different solvent and flavonoid extracts of silkworm feces. The solvents were ethanol, butanol, and water, while the methods utilized included ultrasonification, stirrer, reflux, and reflux after ultrasonification extraction. Results showed that butanol ultrasonification extraction (BUE) yield the lowest extraction (1.75%), while the other methods yielded 7 to 14%. The total polyphenol content utilizing BUE was 3.3 mg TAE/g, while water ultrasonification extraction (WUE) yielded the highest extraction rate with 51.6 mg TAE/g. The total flavonoid content was significantly higher using ethanol reflux extraction (EUE) at 266.8 mg QRE/g BUE, which was 158.3 and 151.3 mg QRE/g. Both DPPH radical scavenging activity and SOD-like (superoxide dismutase) activity, showed significant antioxidant effects. Finally, all other extracts except for BUE had a-glucosidase inhibition at 60%. Therefore, an effective extraction method for physiologically active substances must be selected.

• Journal of Electrochemical Science and Technology
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• 제9권4호
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• pp.251-259
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• 2018

In general, the charge storage characteristics and overall performance of electrochemical energy devices (such as lithiumion batteries and supercapacitors) significantly depends on the structural and geometrical factors of the electrodes' active materials. The most widely used active materials of electrochemical energy storage devices are based on carbons of various forms. Each carbon type has drawbacks and advantages when used as the electrode material. Studies have been recently carried out to combine different types of carbons, in particular nanostructured carbons, in order to overcome the structure-originated limitations and thus enhance the overall electrochemical performances. In this feature article, we report the recent progress on the development of this novel class of materials (multidimensional nanocarbons), and their applications for supercapacitors. Multidimensional nanocarbons include graphenes/carbon nanotubes (CNTs), CNTs/carbon films, CNTs/fullerenes, and ternary carbon nanostructures. Various applications using these multidimensional nanocarbons have been proposed and demonstrated in the literature. Owing to the recent extensive studies on electrochemical energy storage devices and considering that carbons are their most fundamental electrode materials, the number of reports on nanocarbons employed as electrodes of the electrochemical energy storage devices is rapidly increasing. Recently, numerous multidimensional nanocarbons have been designed, prepared, and utilized as electrodes of electrochemical capacitors or supercapacitors, which are considered next-generation energy devices owing to their unique merits compared to the conventional structures. In this review, we summarize the basic motivations, preparation methods, and resultant supercapacitor performances of each class of multidimensional nanocarbons published in the literature, focusing on recent reports.

• 한국포장학회지
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• 제24권3호
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• pp.141-148
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• 2018

Photo-oxidation is one of the main causes of food deterioration of great variety of foods, such as dairy products, nuts, meat products, and wine. It causes a loss of both nutritional value and sensorial quality of products and may even leads to the formation of toxic compounds. Active packaging for food and beverages has been investigated and developed with embedding light absorbers or blocking materials into the plastics. In recent years, several novel light barrier materials have been proposed as an alternative option for different applications. This article reviews the up-to-date technology in light absorber and blocking material with special emphasis on chemical compound and mechanism. Inorganic, organic, hybrid organic-inorganic, and natural light absorbers were scoped. The challenges and future perspectives of light barrier materials are also discussed.

• 한국세라믹학회지
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• 제42권1호
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• pp.56-61
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• 2005

아나타제 $TiO_{2}$, 활성탄, 세라믹섬유를 포함하는 VOC 흡착과 광산화분해 특성을 동시에 갖는 내구성이 우수한 광촉매 종이를 제조하여 그 특성을 분석하였다. 광촉매 종이 제조용 슬러리 내에 함유되어 있는 $TiO_{2}$를 활성탄 및 세라믹섬유 표면에 선택적으로 결합시키기 위한 PDADMAC의 적정농도범위는 $10{\~}15ppm$이었으며, 제지방법에 의해 만들어진 광촉매 종이는 두께 0.4mm, 평량 $380g/m^{2}$을 나타내었다. 제조된 광촉매 종이는 활성탄에 의한 흡착과 $TiO_{2}$에 의한 광산화 분해 반응이 동시에 진행되어 이들 두 반응이 각각 단독으로 진행되는 VOC 제거용 소재에 비하여 아세트알에히드의 제거속도를 크게 증가시켰다. 또한 세라믹섬유-$TiO_{2}$, 활성탄-$TiO_{2}$의 선택적인 결합은 UV 조사시 $TiO_{2}$에 의한 기지내 유기물의 분해를 방지하여 내구성을 개선하는데 효과적이었다.

• 한국의상디자인학회지
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• 제7권1호
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• pp.55-63
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• 2005

The outcome of modem sports events are reliant on not only the athletic ability and technology of individual players but their sportswear proterties. State-of-the-Hitech sportswear has started to be introduced in the 1950s, and in addition to the athletic capability of players, sportswear is one of the primary factors to affect the results of sports games, as a wide variety of Hi-Tech functional materials have come out since the 1990s. The purpose of this study was to development into the concept of active sportswear, to sort out hitech functional product lines in this field, to look into sports stars and Hi-Tech functional sports brands, and finally to identify the major characteristics of recent active sportswear. The result of this study were as follows: 1. There were largely four characteristics in recent functional sportswear materials: fast-drying cooling, minimized resistance, ultralight comfortableness, and water vapor permeable/waterproof function. 2. Besides the athletic capability and technology of players, Hi-Tech functional products are one of the major factors to determine the outcome of modem sports events. Functional synthetic fiber is preferred, instead of cotton, since the former is easier to manage and retains humidity better. 3. The major features of recent trend in active sportswear products are, functional, diversity and value. That is, those products are functional, since they are easy to manage and retain proper humidity, and they are for multipurpose, since they are fashionable and practical at the same time. And they are valuable, being expensive but appropriate for the movement of the body and having a high quality.

• Carbon letters
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• 제6권3호
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• pp.158-165
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• 2005

Room temperature kinetics of degradation of nerve agent simulants and sarin, an actual nerve agent at the surface of different carbon based adsorbent materials such as active carbon grade 80 CTC, modified whetlerite containing 2.0 and 4.0 % NaOH, active carbon with 4.0 % NaOH, active carbon with 10.0 % Cu (II) ethylenediamine and active carbon with 10.0 % Cu (II) 1,1,1,5,5,5-hexafluoroacetylacetonate were studied. The used adsorbent materials were characterized for surface area and micropore volume by $N_2$ BET. For degradation studies solution of simulants of nerve agent such as dimethyl methylphosphonate (DMMP), diethyl chlorophosphate (DEClP), diethyl cyanophosphate (DECnP) and nerve agent, i.e., sarin in chloroform were prepared and used for the uniform adsorption on the adsorbent systems using their incipient volume at room temperature. Degradation kinetics was monitored by GC/FID and was found to be following pseudo first order reaction. Kinetics parameters such as rate constant and half life were calculated. Half life of degradation with modified whetlerite (MWh/NaOH) system having 4.0 % NaOH was found to be 1.5, 7.9, 1206 and 20 minutes for DECnP, DEClP, DMMP and sarin respectively. MWh/NaOH system showed maximum degradation of simulants of nerve agents and sarin to their hydrolysis products. The reaction products were characterized using NMR technique. MWh/NaOH adsorbent was also found to be active against sulphur mustard.

• 공학논문집
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• 제4권1호
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• pp.93-107
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• 2002

본 연구에서는 정수장에서 사용후 폐기된 활성탄을 전자파로 조사 capillary 복원 능력을 조사하였고 활성화제의 종류 및 량에 따른 비표면적 변화에 대하여 연구하였다. 수증기를 활성화제로 사용한 경우에는 재생의 능력은 우수하나, 폐활성탄에 함유하고 있는 수분과 반응하여 자동이송에 문제점이 있는 것으로 나타났다. 또한 $CO_2$ gas로 재생한 결과 이송의 문제점도 해결되고 비표면적도 신탄에 비해 10-20%향상된 것으로 나타났다. 전자파의 세기에 있어서는 2.75kw 공급시 제일 좋은 재생효과가 나타났다. 각 변수에 의한 실험 후 반응물을 ASAP, SEM등을 이용하여 분석한 결과 전자파의 세기와 활성화제 종류 및 양에 따라 복원 능력이 다르게 나타났다. 특히 공기를 활성화제로 사용한 경우에는 복원능력의 오차가 심하게 나타났다. 이는 전자파에 의해 활성탄이 가열된 상태에서 공기의 량이 과다하게 투입, 산화, 연소되어 수율이 떨어지는 것으로 확인되었다. Microwave를 이용하여 폐활성탄을 재생시킨 결과 일반적으로 사용하고 있는 rotary kiln보다 우수한 재생효과가 나타났고, 경제성에서도 앞서는 것으로 나타났으나 대량 생산이 어렵다는 것이 단점으로 나타났다.