• 대한화학회지
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• 제6권2호
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• pp.170-175
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• 1962

The ultraviolet and visable absorption spectra of trans, cis-azoxybenzene, substituted azoxybenzenes and their conjugate acids have been studied. The 320-350$m{\mu}$ main bands of free-base of azoxybenzenes are due to ${\pi}{\to}{\pi}^{\ast}$ transition. These bands of their conjugate acids shown bathochromic shift into visible range. The following emperical relationship between absorption maxima of the main bands was found. ${\lambda}_{max}={\lambda}^{\circ}_{max}+{\Delta}{\lambda}_x+{\Delta}{\lambda}_y$ This relationship in terms of wave number is also hold in good agreement. ${\nu}={\nu}_{\circ}-({\Delta}{\nu}_x+{\Delta}{\nu}_y)$

• 한국지진공학회:학술대회논문집
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• 한국지진공학회 1997년도 추계 학술발표회 논문집 Proceedings of EESK Conference-Fall 1997
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• pp.217-224
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• 1997

One way in which a comparison can be mode between various reinforced concrete structures is to compare the rate of energy absorption capacity. It is useful to use a well-known standard hysteretic rule as a benchmark for comparisons. The concept of energy absorption efficiency with respect to an elaste-perfectly plastic (EPP) system has been adopted. The normalized cumulative energy, cumulative plastic drift and energy response spectra are used for the method. The previous study using the energy spectra developed by Chang and Mander (1994) indicates the cumulative plastic demand for most earthquakes to be 0.1 rad., but a conservative upper bound of 0.2 rad. could be expected for a maximum credible earthquake. From the present study, the energy absorption efficiency in R.C. structures with respect to the EPP system may range in 30%-45% for most cases.

• 천문학회보
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• 제46권1호
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• pp.57.1-57.1
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• 2021

The icy mantles of interstellar grains are developed by the freeze-out of interstellar molecules and atoms onto grain surfaces. The ice molecules become more complex by surface chemistry induced directly by high energy photons or by the thermal energy diffused over heated grain surface. Therefore, the ice composition is an important tracer of physical conditions where the ices form. Ices have been studied via their absorption features against continuum sources, such as young stellar objects or evolved background stars, in infrared wavelengths. The Spitzer IRS was the most sensitive spectrometer for the observations of infrared ice absorption features. We has been developing an automated analysis tool for the Spitzer IRS spectra, especially for the 15 ㎛ CO₂ bending mode. The 15 ㎛ CO₂ absorption feature is very useful for the study of accretion process in star formation since its spectral shape varies with thermal condition of the dust grains. Eventually, this tool will cover the whole range of the Spitzer IRS spectrum (5~20 ㎛).

• Bulletin of the Korean Chemical Society
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• 제23권9호
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• pp.1315-1327
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• 2002

The model compounds, 8-methoxypsoralen-CH2O(CH2)n-adenine (MOPCH2OCnAd, n=2, 3, 5, 6, 8, and 10) in which 5 position of 8-methoxypsoralen (8-MOP) is linked by various lengths of polymethylene bridge to N9 of adenine. UV absorption spectra are identical with the sum of MOPCH2OC3 and adenine absorption spectra. Solvent effects on the UV absorption and fluorescence emission spectra indicate that the lowest excited singlet state is the $(\pi${\rightarrow}$\pi*)$ state. The spectral characteristics of the fluorescence of MOPCH2OCnAd are strongly dependent upon the nature of the solvents. The fluorescence emission spectra in aprotic solvents are broad and structureless due to the excimer formation through the folded conformation accelerated by hydrophobic ${\pi}-{\pi}$ stacking interaction. Increasing polarity of the protic solvents leads to higher population of unfolded conformation stabilized through favorable solvation and H-bonding, and consequently to an increase in the fluorescence intensity, fluorescence lifetime, and a shift of fluorescence maximum to longer wavelengths. The decay characteristics of the fluorescence in polar protic solvents shows two exponential decays with the lifetimes of 0.6-0.8 and 1.6-1.9 ns in 5% ethanol/water, while MOPCH2OC3 shows 0.5 and 1.7 ns fluorescence lifetimes. The long-lived component of fluorescence can be attributed to the relaxed species (i.e., the species for which the solvent reorientation (or relaxation) has occurred), while the short-lived components can be associated with the unrelaxed, or only partially relaxed, species.

• Bulletin of the Korean Chemical Society
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• 제32권7호
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• pp.2358-2368
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• 2011

Density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations, employing the B3LYP method and the LANL2DZ, 6-31G$^*$(LANL2DZ for Tc), 6-31G$^*$(cc-pVDZ-pp for Tc) and DGDZVP basis sets, have been performed to investigate the electronic structures and absorption spectra of the technetium-99m-labeled methylenediphosphonate ($^{99m}Tc$-MDP) complex of the simplest diphosphonate ligand. The bonding situations and natural bond orbital compositions were studied by the Mulliken population analysis (MPA) and natural bond orbital (NBO) analysis. The results indicate that the ${\sigma}$ and ${\pi}$ contributions to the Tc-O bonds are strongly polarized towards the oxygen atoms and the ionic contribution to the Tc-O bonding is larger than the covalent contribution. The electronic transitions investigated by TDDFT calculations and molecular orbital analyses show that the origin of all absorption bands is ascribed to the ligand-to-metal charge transfer (LMCT) character. The solvent effect on the electronic structures and absorption spectra has also been studied by performing DFT and TDDFT calculations at the B3LYP/6-31G$^*$(cc-pVDZ-pp for Tc) level with the integral equation formalism polarized continuum model (IEFPCM) in different media. It is found that the absorption spectra display blue shift in different extents with the increase of solvent polarity.

• 대한화학회지
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• 제16권6호
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• pp.378-384
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• 1972

Copper phthalocyanine과 그것에 azo基가 도입된 몇가지 錯鹽들의 UV 吸收 spectra를 對稱論, ligand field theory 그리고 分子軌道論的見地에서 考察하였으며 또한 이들 錯鹽의 構造를 論하였다.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 1998년도 Proceedings of International Symposium on Remote Sensing
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• pp.89-94
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• 1998

Seasonal variation of attenuation coefficient spectra in Japan sea was extracted from underwater radiance/irradiance spectra observed by a moored buoy system developed by National Space Development Agency of Japan (NASDA). The buoy was deployed 9 months from August 31, 1996 to June 1, 1997. Throughout this period, it was collecting downward irradiance and upward radiance spectra under water at the depth of 1.5m and 6.5m everyday. The dairy averaged diffused attenuation coefficient spectra and underwater reflectance spectra were calculated. The results were compared with the absorption spectra of filtered samples obtained by validation cruises, which carried out 5 times during the moored period. Also, the natural fluorescence of chlorophyll a were extracted from the upward radiance spectra observed at 1.5m depth. The seasonal variation of the calculated attenuation coefficient spectra and the natural fluorescence were examined. The result shows a weak blooming of phytoplankton on November and a large blooming on April.

• Journal of the Korean Wood Science and Technology
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• 제15권4호
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• pp.26-31
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• 1987

맹종죽, 왕대, 솜대 Dioxane Lignin의 UV, IR spectrum의 특징(特徵)을 조사(調査)하여 본 바, 그 결과(給果)를 요약하면 다음과 같다. 1. UV spectrum에 있어서는 일반적(一般的)인 Lignin spectrum과 같이 Maximum peak, Shallow minium peak, Minimum peak의 3개소(個所)를 보였는데 Max. peak는 210nm 부근(附近), Shallow peak는 260-270nm에, Minimum peak는 280nm부근(附近)에 있었다. 2. 280nm부근(附近)의 Minimum peak는 Lignin이 갖는 특징적(特徵的)인 peak로서 일반(一般) 침엽수재(針棄樹材) Lignin이나 활엽수(闊葉樹) Lignin과는 달리 282-285nm에서 흡광도(吸光度)가 꼭 같아 아주 완만한 peak 를 보여 주었다. 3. IR spectrum에 있어서는 방향핵(芳香核) 흡수대(吸收帶)는 $1550cm^{-1}$ 부근(附近)에 있고 1040-$1130cm^{-1}$부근(附近)과 1230-$1275cm^{-1}$에서의 Spectrum 형태(形態)는 활엽수(闊葉樹)에 가깝고 침엽수재(針葉樹材) Lignin의 spectrum과는 상반되는 모습을 보여 주었다.

• E2M - 전기 전자와 첨단 소재
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• 제9권2호
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• pp.152-158
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• 1996

Optical absorption and photoconductivity spectra of undoped and Co-doped Cd$_{4}$GeSe$_{6}$ single crystals, grown by the chemical transport reaction using iodine as a transporting agent, were investigated. At 20K, the optical energy gaps of the single crystals are 1.934eV for Cd$_{4}$GeSe$_{6}$ and 1.815eV for Cd$_{4}$GeSe$_{6}$ :Co$^{2+}$. The photoconductivity spectra of these single crystals were closely investigated over the temperature range 20-290K. At 20K, the photoconductivity peaks were located at 1.797eV, 1.347eV for Cd$_{4}$GeSe$_{6}$ and 1.815eV, I,.57eV, 1.46eV and 1.38eV for Cd$_{4}$GeSe$_{6}$ :Co$^{2+}$, respectively.ely.

• 천문학회보
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• 제40권2호
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• pp.44.2-44.2
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• 2015

Radiative transfer programs have been developed to simulate near-IR spectra of Titan. The formalism of the radiative transfer calculations includes the absorption and emission lines of $CH_4$, $C_2H_2$, $C_2H_6$, and HCN, and continua produced by Titanian haze particles. Absorption and scattering of sunlight by haze particles are considered by employing a two-stream approximation and a spherical-shell model for the atmospheric layers of Titan. Various constraints on the radiative transfer calculations for generating synthetic spectra will be discussed and presented. Several examples of comparisons between the synthetic spectra and recent spectral observations of Titan will also be presented.