• 제목/요약/키워드: a.c. impedance

검색결과 713건 처리시간 0.029초

Characterization of RF Sputter-deposited Sodium Phosphorous Oxynitride Thin Films as a Solid-state Sodium-ion Conductor

  • Chun, Sang-Eun
    • 한국표면공학회지
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    • 제50권4호
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    • pp.237-243
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    • 2017
  • We demonstrated the thin film deposition of sodium phosphorous oxynitride (NaPON) via RF magnetron sputtering of $Na_3PO_4$, as a solid-state Na-ion conductor similar to lithium phosphorous oxynitride (LiPON), which is a commonly used solid electrolyte. The deposited NaPON thin film was characterized by scanning electron microscopy, X-ray diffractometry, and electrochemical impedance spectroscopy, to investigate the feasibility of the solid-state electrolyte in several different cell configurations. The key properties of a solidstate electrolyte, i.e., ionic conductivity and activation energy, were estimated from the complex non-linear least square fitting of the measured impedance spectra at various temperatures in the range of $27-90^{\circ}C$. The ionic conductivity of the NaPON film was measured to be $8.73{\times}10^{-6}S\;cm^{-1}$ at $27^{\circ}C$, which was comparable to that of the LiPON film. The activation energy was estimated to be 0.164 eV, which was lower than that of the LiPON film (0.672 eV). The obtained values encourage the use of a NaPON thin film in the future as a reasonable solid-state electrolyte.

Electrochemical Performance of LSCF Cathode with GDC lnterlayer on ScSZ Electrolyte

  • Hwang, Hae-Jin;Moon, Ji-Woong;Lim, Yongho;Lee, Seunghun;Lee, Eun-A
    • 한국세라믹학회지
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    • 제42권12호
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    • pp.787-792
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    • 2005
  • A symmetrical LSCF $(La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta})\;ScSZ(89ZrO_2-10Sc_2O_3-1CeO_2)/LSCF$ electrochemical cell with a GDC (Gadolinium-Doped Ceria, $90CeO_2-10Gd_2O_3$) interlayer that was inserted between the LSCF cathode and ScSZ electrolyte was fabricated, and the electrochemical performance of these cells was evaluated. The GDC interlayer was deposited on a ScSZ electrolyte using a screen-printing technique. The GDC interlayer prevented the unfavorable solid-state reactions at the LSCF/ScSZ interfaces. The LSCF cathode on the GDC interlayer had excellent electrocatalytic performance even at $650^{\circ}C$. The Area Specific Resistance (ASR) was strongly dependent on the thickness and heat-treatment temperature of the GDC interlayer. The impedance spectra showed that the cell with a $15\~27{\mu}m$ thick GDC interlayer heat-treated at $1200^{\circ}C$ had the lowest ASR.

리튬폴리머전지의 충/방전 특성해석을 위한 진기적모델링에 관한 연구 (A Study on Electrical Modeling for Charge/Discharge Analysis of Li-Polymer Battery)

  • 최해룡;반한식;목형수;신우석;고장면
    • 전력전자학회논문지
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    • 제5권5호
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    • pp.435-442
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    • 2000
  • 리튬폴리머전지의 전기적인 특성을 평가하고 이것을 시스템 측면에서 고찰할 수 있는 이론적인 토대를 마련하기 위하여 본 논문에서는 전지의 전기적인 특성평가를 위한 전기적모델링 기법에 관하여 고찰하였다. 실제 제작된 리튬폴리머전지의 특성자료를 바탕으로 R-L-C 모델을 이용한 동적해석방식과 PSpice 모델을 이용한 정적해석방식을 통하여 리튬폴리머전지의 전기적 특성을 해석하였다. 각 모델의 풍/방전시의 전기적 특성을 고찰하고 충/방전조건에 따른 전지의 단자전압등 특성변수의 변화를 실제 제작된 리튬폴리머전지와 비친, 검토하여 그 타당성을 검증하였다.

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Analysis of the Cross Talk Mechanism in Capacitive Micromachined Ultrasonic Transducers

  • Rho, Yongrae;Khuri-Yakub, Butrus T.
    • The Journal of the Acoustical Society of Korea
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    • 제20권3E호
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    • pp.31-37
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    • 2001
  • Finite element model of a cMUT is constructed using the commercial code ANSYS to analyze the cross talk mechanism. Calculation results of the complex load impedance seen by single capacitor cells are presented, and then followed by a calculation of the plane wave real load impedance seen by a parallel combination of many cells that are used to make a transducer. Cross talk between 1-D array elements is found to be due to two main sources: coupling through a Stoneley wave propagating at the transducer-water interface and coupling through Lamb waves propagating in the substrate. To reduce the cross talk level, the effect of various structural variations of the substrate are investigated, which include a change of its thickness and etched trenches or polymer walls between array elements.

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신경회로망을 이용한 거리 계전기의 속도 개선 방법 (A Method to Improve the Speed of a Distance Relay Using Artificial Neural Networks)

  • 조경래;강용철;깅성수;남순열;박종근;강상희;김광호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 B
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    • pp.677-679
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    • 1996
  • This paper describes a method to improve the speed of a distance relay based on a differential equation of transmission lines using feedforward artificial neural networks (ANN) on an EHV system. For the impedance calculation an integration approximation to the differential equation is used and then an ANN is trained with the impedance convergence characteristic. The ANN predicts the fault distance with some calculated resistances and reactances before they reach trip zone. Thus, the proposed method can improve the speed of distance relays, significantly if a high sampling rate such as 48 samples per cycle is employed.

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엔진 흡기계에 쓰이는 다공형 직조관의 음향특성 측정 및 성능예측 (Measurement of Acoustic Properties and Prediction of Acoustic Performance of Porous Woven Hoses for Engine Intake Systems)

  • 박철민;이정권
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2000년도 추계학술대회논문집
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    • pp.182-186
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    • 2000
  • The porous woven hose is recently considered as an effective element of automotive intake systems. In order to predict the acoustic performance of an intake system with a porous woven hose, the information on the acoustic wall impedance is required. In this article, a measurement technique that is valid over the low frequency range and without mean flow condition is presented. The measurement is performed in a cylindrical chamber with a concentric layout of the sample and the resistance is estimated from measured reactance and transmission loss data. It is observed that the measured transmission loss for a porous woven hose with an arbitrary length agrees well with the predicted one that uses the estimated impedance for a small sample length.

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Interval Scan Inspection Technique for Contact Failure of Advanced DRAM Process using Electron Beam-Inspection System

  • Oh, J.H.;Kwon, G.;Mun, D.Y.;Kim, D.J.;Han, I.K.;Yoo, H.W.;Jo, J.C.;Ominami, Y.;Ninomiya, T.;Nozoe, M.
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제12권1호
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    • pp.34-40
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    • 2012
  • We have developed a highly sensitive inspection technique based on an electron beam inspection for detecting the contact failure of a poly-Si plugged layer. It was difficult to distinguish the contact failure from normal landing plugs with high impedance. Normally, the thermal annealing method has been used to decrease the impedance of poly-Si plugs and this method increases the difference of charged characteristics and voltage contrast. However, the additional process made the loss of time and broke down the device characteristics. Here, the interval scanning method without thermal annealing was effectively applied to enhance the difference of surface voltage between well-contacted poly-Si plugs and incomplete contact plugs. It is extremely useful to detect the contact failures of non-annealed plug contacts with high impedance.

임피던스법을 적용한 연료전지의 성능평가 (Analysis on the Fuel Cell Performance by the Impedance Method)

  • 김귀열
    • 한국전기전자재료학회논문지
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    • 제20권10호
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    • pp.918-923
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    • 2007
  • Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. Corrosions in molten electrolytes and the electric conductivity across the oxide scale have crucial characteristics. When molten salts are involved, high temperature corrosions become severe. In this sense, corrosions of alloys with molten carbonates have the most severe material problems. Systematic investigation on corrosion behavior of Fe/21Cr/Ti or Al alloy has been done in (62+38)mol% (Li+K)$CO_3$ melt at $650^{\circ}C$ using the electrochemical impedance spectroscopy method. It was found that the corrosion current of these Fe-based alloys decreased with increasing Al or Ti. And Al addition improved the corrosion resistance of this type of specimen and more improvement of corrosion resistance was observed at the specimen added with Al.

Performance evaluation of 80 GHz FMCW Radar for level measurement of cryogenic fluid

  • Mun, J.M.;Lee, J.H.;Lee, S.C.;Sim, K.D.;Kim, S.H.
    • 한국초전도ㆍ저온공학회논문지
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    • 제23권4호
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    • pp.56-60
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    • 2021
  • The microwave Radar used for special purposes in the past is being applied in various areas due to the technological advancement and cost reduction, and is particularly applied to autonomous driving in the automobile field. The FMCW (Frequency Modulated Continuous Wave) Radar can acquire level information of liquid in vessel based on the beat frequency obtained by continuously transmitting and receiving signals by modulating the frequency over time. However, for cryogenic fluids with small impedance differences between liquid medium and gas medium, such as liquid nitrogen and liquid hydrogen, it is difficult to apply a typical Radar-based level meter. In this study, we develop an 80 GHz FMCW Radar for level measurement of cryogenic fluids with small impedance differences between media and analyze its characteristics. Here, because of the low intrinsic impedance difference, most of the transmitted signal passes through the liquid nitrogen interface and is reflected at the bottom of the vessel. To solve this problem, a radar measurement algorithm was designed to detect multiple targets and separate the distance signal to the bottom of the vessel in order to estimate the precise position on the liquid nitrogen interface. Thereafter, performance verification experiments were performed according to the liquid nitrogen level using the developed radar level meter.

The Corrosion Behavior of Anti-Graffiti Polyurethane Powder Coatings

  • Rossi, S.;Fedel, M.;Deflorian, F.;Feriotti, A.
    • Corrosion Science and Technology
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    • 제17권6호
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    • pp.257-264
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    • 2018
  • Anti-graffiti coatings have become more important. These layers must guarantee excellent corrosion protection properties, and graffiti must be easily removable, without reducing protection and aesthetic properties. In this study, anti-graffiti and corrosion behavior of two anti-graffiti polyurethane powder coatings were studied. These layers were deposited on aluminum substrate, with two different surface finishes, smooth, and wrinkled. The action of four different removers are investigated. Graffiti were drawn on coatings by means of red acrylic spray paint. Methyl-ethyl-ketone (MEK) and a "commercial" remover were the most effective solvents, in terms of graffiti removal capability, producing limited change in aesthetical surface aspect for smooth finishing. The wrinkled surface was less resistant. Corrosion protection properties, after removal action and contact with the remover, were evaluate by electrochemical impedance spectroscopy. After approximately 5 hours, coatings were no longer protective due to formation of defects. To simulate the weathering effect, UV-B cyclic test (4 hours of UV exposure followed by 4 hours of saturated humidity at $50^{\circ}C$) were performed for 2000 hours. Gloss and color changes were measured, and electrochemical impedance spectroscopy measurements were performed after aging and graffiti removal.