Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
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Characterization of RF Sputter-deposited Sodium Phosphorous Oxynitride Thin Films as a Solid-state Sodium-ion Conductor

  • Chun, Sang-Eun (School of Materials Sciences and Engineering, Kyungpook National University)
  • Received : 2017.08.21
  • Accepted : 2017.08.28
  • Published : 2017.08.31
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Abstract

We demonstrated the thin film deposition of sodium phosphorous oxynitride (NaPON) via RF magnetron sputtering of $Na_3PO_4$, as a solid-state Na-ion conductor similar to lithium phosphorous oxynitride (LiPON), which is a commonly used solid electrolyte. The deposited NaPON thin film was characterized by scanning electron microscopy, X-ray diffractometry, and electrochemical impedance spectroscopy, to investigate the feasibility of the solid-state electrolyte in several different cell configurations. The key properties of a solidstate electrolyte, i.e., ionic conductivity and activation energy, were estimated from the complex non-linear least square fitting of the measured impedance spectra at various temperatures in the range of $27-90^{\circ}C$. The ionic conductivity of the NaPON film was measured to be $8.73{\times}10^{-6}S\;cm^{-1}$ at $27^{\circ}C$, which was comparable to that of the LiPON film. The activation energy was estimated to be 0.164 eV, which was lower than that of the LiPON film (0.672 eV). The obtained values encourage the use of a NaPON thin film in the future as a reasonable solid-state electrolyte.

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References

  1. J. Freed, in, AP, https://www.usatoday.com/story/todayinthesky/2014/01/15/boeing-confirms-new-787-battery-incident/4494157/, 2014.
  2. S. Kovach, in, http://www.businessinsider.com/samsung-issues-galaxy-note-7-battery-report-2017-1, 2017.
  3. C. Lethien, M. Zegaoui, P. Roussel, P. Tilmant, N. Rolland, P.A. Rolland, Microelectron. Eng., 88 (2011) 3172-3177. https://doi.org/10.1016/j.mee.2011.06.022
  4. F. Xu, N.J. Dudney, G.M. Veith, Y. Kim, C. Erdonmez, W. Lai, Y.-M. Chiang, J. Mater. Res., 25 (2011) 1507-1515.
  5. S.D. Jones, J.R. Akridge, Solid State Ion., 53 (1992) 628-634.
  6. X. Yu, J.B. Bates, G.E. Jellison, F.X. Hart, J. Electrochem. Soc., 144 (1997) 524-532. https://doi.org/10.1149/1.1837443
  7. J.B. Bates, N.J. Dudney, G.R. Gruzalski, R.A. Zuhr, A. Choudhury, C.F. Luck, J.D. Robertson, J. Power Sources, 43 (1993) 103-110. https://doi.org/10.1016/0378-7753(93)80106-Y
  8. N. Kamaya, K. Homma, Y. Yamakawa, M. Hirayama, R. Kanno, M. Yonemura, T. Kamiyama, Y. Kato, S. Hama, K. Kawamoto, A. Mitsui, Nat. Mater., 10 (2011) 682-686. https://doi.org/10.1038/nmat3066
  9. B. Wang, J.B. Bates, F.X. Hart, B.C. Sales, R.A. Zuhr, J.D. Robertson, J. Electrochem. Soc., 143 (1996) 3203-3213. https://doi.org/10.1149/1.1837188
  10. J.B. Bates, D. Lubben, N.J. Dudney, F.X. Hart, J. Electrochem. Soc., 142 (1995) L149-L151. https://doi.org/10.1149/1.2048729
  11. C. Sun, J. Liu, Y. Gong, D.P. Wilkinson, J. Zhang, Nano Energy, 33 (2017) 363-386. https://doi.org/10.1016/j.nanoen.2017.01.028
  12. Y.G. Kim, H.N.G. Wadley, J. Vac. Sci. Technol. A, 26 (2008) 174-183. https://doi.org/10.1116/1.2823491
  13. C.H. Choi, W.I. Cho, B.W. Cho, H.S. Kim, Y.S. Yoon, Y.S. Tak, Electrochem. Solid State Lett., 5 (2002) A14-A17. https://doi.org/10.1149/1.1420926
  14. R. Marchand, D. Agliz, L. Boukbir, A. Quemerais, J. Non-Cryst. Solids, 103 (1988) 35-44. https://doi.org/10.1016/0022-3093(88)90413-9
  15. R.K. Evans, Energy, 3 (1978) 379-385. https://doi.org/10.1016/0360-5442(78)90034-8
  16. S.E. Kesler, P.W. Gruber, P.A. Medina, G.A. Keoleian, M.P. Everson, T.J. Wallington, Ore Geol. Rev., 48 (2012) 55-69. https://doi.org/10.1016/j.oregeorev.2012.05.006
  17. C. Grosjean, P.H. Miranda, M. Perrin, P. Poggi, Sust. Energ. Rev., 16 (2012) 1735-1744. https://doi.org/10.1016/j.rser.2011.11.023
  18. T.C. Wanger, Conser. Lett., 4 (2011) 202-206. https://doi.org/10.1111/j.1755-263X.2011.00166.x
  19. J.F. Whitacre, T. Wiley, S. Shanbhag, Y. Wenzhuo, A. Mohamed, S.E. Chun, E. Weber, D. Blackwood, E. Lynch-Bell, J. Gulakowski, C. Smith, D. Humphreys, J. Power Sources, 213 (2012) 255-264. https://doi.org/10.1016/j.jpowsour.2012.04.018
  20. Z. Zeng, X. Jiang, R. Li, D. Yuan, X. Ai, H. Yang, Y. Cao, Adv. Sci., 3 (2016) 1600066-n/a.
  21. F. Wu, N. Zhu, Y. Bai, L. Liu, H. Zhou, C. Wu, ACS Appl. Mater. Interfaces, 8 (2016) 21381-21386. https://doi.org/10.1021/acsami.6b07054
  22. B.L. Ellis, L.F. Nazar, Curr. Opin. Solid State Mater. Sci., 16 (2012) 168-177. https://doi.org/10.1016/j.cossms.2012.04.002
  23. D. Kundu, E. Talaie, V. Duffort, L.F. Nazar, Angew. Chem. Int. Ed., 54 (2015) 3431-3448. https://doi.org/10.1002/anie.201410376
  24. V. Palomares, P. Serras, I. Villaluenga, K.B. Hueso, J. Carretero-Gonzalez, T. Rojo, Energy Environ. Sci., 5 (2012) 5884-5901. https://doi.org/10.1039/c2ee02781j
  25. R. Marchand, J. Non-Cryst. Solids, 56 (1983) 173-178. https://doi.org/10.1016/0022-3093(83)90464-7
  26. A. Le Sauze, E. Gueguen, R. Marchand, J. Non-Cryst. Solids, 217 (1997) 83-91. https://doi.org/10.1016/S0022-3093(97)00152-X
  27. J.R. Macdonald, W.R. Kenan, Impedance Spectroscopy: Emphasizing Solid Materials and Systems, Wiley, 1987.
  28. J.B. Bates, N.J. Dudney, G.R. Gruzalski, R.A. Zuhr, A. Choudhury, C.F. Luck, J.D. Robertson, Solid State Ion., 53 (1992) 647-654.
  29. B. Put, P.M. Vereecken, J. Meersschaut, A. Sepulveda, A. Stesmans, ACS Appl. Mater. Interfaces, 8 (2016) 7060-7069. https://doi.org/10.1021/acsami.5b12500
  30. P. Shewmon, Diffusion in Solids, Wiley, 1991.