• Title/Summary/Keyword: a property of matter

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Mesoporous Carbon as a Metal-Free Catalyst for the Reduction of Nitroaromatics with Hydrazine Hydrate

  • Wang, Hui-Chun;Li, Bao-Lin;Zheng, Yan-Jun;Wang, Wen-Ying
    • Bulletin of the Korean Chemical Society
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    • 제33권9호
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    • pp.2961-2965
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    • 2012
  • Mesoporous carbons with tailored pore size were prepared by using sucrose as the carbon source and silicas as the templates. The silica templates were obtained from a hydroxypropyl-${\beta}$-cyclodextrin-silica hybrids using ammonium perchlorate oxidation at different temperatures to remove the organic matter. The structures and surface chemistry properties of these carbon materials were characterized by $N_2$ adsorption, TEM, SEM and FTIR measurements. The catalytic performances of these carbon materials were investigated through the reduction of nitroaromatic using hydrazine hydrate as the reducing agent. Compared with other carbon materials, such as active carbon, and carbon materials from the silica templates obtained by using calcination to remove the organic matter, these carbon materials exhibited much higher catalytic activity, no obvious deactivation was observed after recycling the catalyst four times. Higher surface area and pore volume, and the presence of abundant surface oxygen-containing functional groups, which originate from the special preparation process of carbon material, are likely responsible for the high catalytic property of these mesoporous carbon materials.

하해혼성 충적층 유기물 연용 논토양의 화학성 및 양분 집적형태 변화 (Changes of Nutrient Accumulation Type and Chemical Property on Annual Dressing Paddy Soil in Fluvio-marine deposit)

  • 양창휴;유영석;류철현;정지호;김재덕;정광용
    • 한국토양비료학회지
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    • 제39권6호
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    • pp.351-356
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    • 2006
  • 본 연구는 유기물 및 동일비료를 하해혼성 충적토 전북통에서 24년 연용 후 주구인 유기물(무시용, 볏짚, 퇴비)에 세구인 질소시비량(0, 100, 150, 200, $250kg\;ha^{-1}$)을 5수준으로 처리하여 년차별 토양화학성과 유기태 질소 및 무기태 인산의 형태별 집적량을 분석한 결과는 다음과 같다. 유기물 시용으로 토양산도는 다소 낮아졌으며 그 정도는 볏짚을 준 경우가 퇴비를 줄 경우보다 컸다. 토양 중 유기물 함량은 연차적으로 증가하는 경향을 보였으며 퇴비 시용 구에서 더 증가했다. 유효인산 함량은 관행(NPK)의 경우 감소하였고 유기물 시용으로 증가했으며 퇴비 시용 구에서 더 증가하였다. 토양 중 총유기태질소 함량은 퇴비>볏짚>무시용 순으로 높았으며 유기태 질소 중 산가용 비유출성질소(아미노산태 질소)>산불용성질소(미동정태질소)>산가용 유출성질소(아미노당태 질소) 순으로 많았다. 산가용 비유출성질소는 볏짚+질소시비에서 $918mg\;kg^{-1}$로 총유기태질소의 52.7%를 차지하였고 산가용유출성질소는 볏짚+질소 무시비, 산불용성질소 및 산가용 유출성질소는 퇴비+질소시비에서 많았다. 또한 토양 중 총무기태인산 함량은 볏짚+질소시비>퇴비+질소시비>퇴비+질소무시비>무시용+질소시비>볏짚+질소시비 순으로 많았다. 볏짚+질소 무시비에서는 무기태 인산이 모두 높았고 특히 Fe-P 함량이 $425mg\;kg^{-1}$로 가장 높았다. 퇴비+질소시비 및 무시용+질소시비에서는 Fe-P 및 Al-P 함량이 높은 반면에 질소 무시비와 큰 차이를 나타내지 않았다. Ca-P 함량이 볏짚과 퇴비 시용으로 높아진 것은 유기물의 인산집적 뿐만 아니라 토양환경의 변화 즉 환원이 높게 진행된 결과로 생각된다.

ADR을 통한 저작권분쟁 해결에 관한 검토 (The Role of ADR in the Resolution of the Copyright Disputes)

  • 김선정
    • 한국중재학회지:중재연구
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    • 제21권2호
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    • pp.85-112
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    • 2011
  • These days utilization of copyright in daily life and economic activities is becoming more important than ever, and IT technology is developing day by day. Along with those fact, copyright infringement and dispute is naturally increasing. This thesis dealt with the 3 different issues of ADR on copyright. The First part, introduce ADR system that was performed by Korea Copyright Committee according to Copyright law. This paper evaluate the committee's efforts to provide resolution of copyright disputes via conciliation was effective. So it needs to be look over several countries' ADR, beside conventional judicial remedy. And Korea's copyright conciliation system which is successfully operating also introduced. Second, In many countries, including South Korea are take advantage of conciliation as the way to settle down the dispute over copyright. Furthermore, looked over if we can use arbitration as tool to settle dispute or not. Currently in Korea, patent dispute is handled by Industrial Property Dispute Conciliation Committee(The Invention Promotion Act Ch.5) and Layout-design Review and Mediation Committee(The Act on the Layout-designs of Semiconductor Integrated Circuits Art.29-34), but using performance of those two committee is still too low. In comparison, the copyright committee, a affiliation organization of the ministry of culture, sports and tourism has much more result in conciliation compare with patent dispute. Copyright disputes has arbitrability of it's subject-matter and many regulating organs are interested in it. (especially, binding of arbitral award and final resolution). Take advantage of both conciliation and arbitration could be good way to resolve copyright disputes. Third, the writer look at the proposal on the creation of Northeast Regional Center for Intellectual Property ADR. Because of the nature of copyright and rapid development of internet technology, international use of work become more frequent and accordingly infringement cases are increasing. The role of commercial arbitration regimes and institutions which has progressed significantly worldwide level, but which has only just begun in the intellectual property ADR area, leads also to a clash of often very different legal cultures and protection in a market economy. International cooperation in regional area with conflict interests becomes an important alternative. But it will depend on the building of regional institutions and mechanisms. The feasibility of this proposal and preconditions were examined. Establishment of new international organization requires a lot of time, cost and efforts. And risk of failure is much too high. Therefore factual, statistical review should be preceded. In addition, technical measures, such as on-line arbitration is necessary to review also. Furthermore in order to establish new organization, the relative law, legal environment, public sentiment and international compliance must be carefully considered with factual review about the needs and economic benefits of each country Yet on complex regulatory matters such as IP and ADR, a great deal of the potential benefits from international standards arises not from the international legal framework nor even the formal content of national legislation, but from the informed and effective use made of the possibilities within the system, including by policymakers and regulators.

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고품질 순환모래 제조를 위한 샌드플럭스 장치의 최적 운전조건 설정에 관한 실험적 연구 (An Experimental Study on the Establishment of Optimum Operating Conditions in Sand Flux Apparatus for High-Quality Recycled Sand Manufacture)

  • 이종석;임현웅;김재환;이도헌;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2007년도 추계 학술논문 발표대회
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    • pp.23-26
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    • 2007
  • In this study, recently it is urgently required that demolition waste concrete has to be recycled on the construction because urban development is accelerated and redevelopment project is rapidly expanded, production quantity of construction and demolition waste concrete is being increased. On the other hand, it has to be solved urgently the unbalance of demand and supply about the fine aggregate because the sea sand is restricted by exhaustion of river sand and intensification of environment influence evaluation. Therefore, the purpose of the study was to show the performance of the apparatus developed by the study and to propose the direction of the optimum operating conditions by having an experimental and positive evaluation about quality of recycled sand produced to develop a separating and selecting device of impurities for recycling of construction wastes which can have a bigger improvement of economical efficiency, productivity, environmental property and quality through a basic property of matter of recycled sand by each operating condition of sand flux in comparison with the existing production system of recycled sand.

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Thermal and Hygroscopic Properties of Indoor Particulate Matter Collected on an Underground Subway Platform

  • Ma, Chang-Jin;Lee, Kyoung-Bin;Zhang, Daizhou;Yamamoto, Mariko;Kim, Shin-Do
    • Asian Journal of Atmospheric Environment
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    • 제9권3호
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    • pp.228-235
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    • 2015
  • In order to clarify the thermal and hygroscopic properties of indoor particulate matter (PM) in a semiclosed subway space, which is critically important for understanding of the distinctive particle formation processes as well as the assessment of their health effects, the size-resolved PMs (i.e., $PM_{2.5}$ and $PM_{10-2.5}$) were intensively collected on the platform of Miasageori station on the Seoul Subway Line-4. The elemental concentrations in soluble and insoluble fractions were determined by PIXE from the bulkily pretreated $PM_{2.5}$. The thermal and hygroscopic characteristics of individual particles were investigated via a combination of the unique pretreatment techniques (i.e., the high-temperature rapid thermal process and the water dialysis) and SEM-EDX analysis. Iron and calcium were unequaled in insoluble and soluble $PM_{2.5}$ fractions, respectively, with overwhelming concentration. The SEM-EDX's elemental net-counts for the pre- and post-pyrolyzed PMs newly suggest that magnesium and several elements (i.e., silica, aluminum, and calcium) may be readily involved in the newly generated subway fine PM by a high-temperature thermal processing when trains are breaking and starting. Through the water dialysis technique, it turned out that calcium has meaningful amount of water soluble fraction. Furthermore, the concentrations of the counter-ions associated with the calcium in subway $PM_{10-2.5}$ were theoretically estimated.

Hydraulic Property and Solute Breakthrough from Salt Accumulated Soils under Various Head Pressures

  • Lee, Sanghun;Chung, Doug-Young;Hwang, Seon-Woong;Lee, Kyeong-Bo;Yang, Chang-Hyu;Kim, Hong-Kyu
    • 한국토양비료학회지
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    • 제45권5호
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    • pp.717-724
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    • 2012
  • Salt accumulated soil should be reclaimed to lower salt level for crop production. This study was carried out to investigate the characteristics of water flow and transport of mono and divalent solutes on salt accumulated soils with different head pressures. Saturated hydraulic conductivity was measured by constant and falling head methods with maintaining different head pressures. Saturated hydraulic conductivity was influenced by bulk density and organic matter contents in soils, but it had different elusion patterns between saline and sodic soil. While the quantity of water necessary for reclamation could be varies with soil type, it was considered that the supply of one pore volume of water was affordable and economic. Additional head pressure significantly increased the volume of leachate at a given time and it was more effective at low organic matter soils. The results indicate that additional head pressure would be one of the best irrigation practices on desalination method for salt accumulated soils.

Long-term Variations of Chemical Properties in Controlled Horticultural Soils of Gyeongnam Province

  • Lee, Young-Han;Lee, Seong-Tae;Hong, Kang-Pyo;Lee, Sang-Dae;Kim, Je-Hong;Ok, Yong-Sik;Kim, Min-Keun;Kim, HyeRan
    • 한국토양비료학회지
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    • 제46권5호
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    • pp.308-312
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    • 2013
  • The monitoring of chemical dynamic changes in controlled horticultural lands is very important for agricultural sustainability. Field monitoring was performed to evaluate the soil chemical properties of 200 controlled horticultural soil samples in Gyeongnam province every 4 years from 2000 to 2012. Soil chemical properties such as pH, amount of organic matter, available phosphate, nitrate nitrogen, and exchangeable potassium, calcium, magnesium, and sodium were analyzed. The amount of exchangeable calcium and soil pH were significantly higher in 2012 than in 2000. In 2012, the frequency distribution for values of pH, organic matter, available phosphate, and exchangeable potassium, calcium, and magnesium that were within the optimum range was 16.0%, 22.5%, 11.5%, 3.5%, 2.5%, and 5.0%, respectively. Especially, available phosphate and exchangeable calcium were excess level with portions of 76.0% and 96.5%, respectively. These results indicated that a balanced management of soil chemical properties can reduce the amount of fertilizer applied for sustainable agriculture in controlled horticultural lands.

마이크로파를 적용한 에너지 효율적인 오염토양 정화를 위한 예비연구 (A Preliminary Study for Microwave Application to Energy Efficient Contaminated Soil Cleanup)

  • 함석진;양인호;오현상;조현조;김건인;정상조
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권3호
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    • pp.28-37
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    • 2011
  • A preliminary study for energy efficient soil heating and contaminant removal using microwave was conducted. Soils sampled from floodplain were heated with microwave oven, and soil heating property and energy efficiency were compared to those heated with electrical furnace. In addition the effects of water, soil organic matter, and contaminated diesel on soil heating with microwave were investigated. Even though the electrical power consumption of electrical furnace and microwave oven were similar, temperature of soil heated with microwave oven was significantly higher than that of soil heated with electrical furnace. The increase of soil moisture content delays the raise of soil temperature during heating it with microwave oven. However, the effects of total petroleum hydrocarbon (TPH) (<10%) in contaminated soil matrix and small amount of soil organic matter (<5%) on the increase of soil temperature by microwave were not significant. Further studies for contaminated soils with different texture using pilot scale microwave reactor are required for application of this technique in the field.

CNT/Cu 나노복합체의 제조 및 전기적 특성평가 (Electrical Characteristics and Fabrication of CNT/Cu Nanocomposite)

  • 흥윤정;김혜진;이규만;김인우
    • 반도체디스플레이기술학회지
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    • 제6권4호
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    • pp.59-63
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    • 2007
  • The CNTs are the most extensively studied material which are characterized by the complete property of matter, structure, and the large thermal conductivity (thermal conductivity of CNTs ~>2000W/mK vs. thermal conductivity of Aluminum ~> 204W/mK). Thus, they are successfully applied to the various fields. However, due to the strong agglomeration caused by the van der waal's force, their applications are limited. In the present study, a new method for CNTs dispersion was developed by using the mechanical dispersion, acid treatment, and then Cu was coated. This process produces CNTs/Cu nanocomposite powders, whereby the CNTs are homogeneously located within the Cu powders. The electrical properties of the CNTs/Cu nanocomposite were investigated.

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SERVQUAL 측정과 SERVPERF 측정 이론 연구 -관광 서비스 품질을 중심으로- (A Study on Measurement of SERVQUAL and SERVPERF Measurement - A Sightsee- ing quality of Service to the centers -)

  • 김철중
    • 정보학연구
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    • 제9권3호
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    • pp.33-47
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    • 2006
  • We will can do quality of measurement of service that thing is quite abstract concept. Generally, we speak Service of quality that property of a product, usability of use, social quality requirement to a quality of service by wide meaning. A purpose of this study was comparison regarding a way to measure of service quality, and in the insufficient section there was anything, and progress of model study of service left no matter how much focus to it. There is comparative study a few progress of literature of a PZB, SERVQUAL, SERVPERF, model. Desarbo, Huff, Rolandelli, & Choi, (1994: 125-131) proposed that to solve the above model contradiction point, and Presentation called a plan based on to Conjoint analysis. There is Critical point to decide on priority order of proposed model of service measurement. This study has a lot of the pieces which are short by absence of empirical study, but will make a supplementation in next term study.

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