• 제목/요약/키워드: Z. O. E.

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配置와 形態에 關한 分子軌道論的 硏究 (第1報). Methyl Benzamidoxime의 配置와 形態 (MO Studies of Configuration and Conformation (Ⅰ). Configuration and Conformation of Methyl Benzamidoxime)

  • 김시준;이익춘
    • 대한화학회지
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    • 제20권2호
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    • pp.111-117
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    • 1976
  • Methyl benzamidoxime의 C=N 결합에 의한 configuration 과 N-O 및 C-N 결합에 대한 conformation 에 관하여 확장 Huckel 분자궤도법 계산을 실시하였다. 계산 결과는 C-N 결합의 conformation이 sp-형이면 E-configuration이 Z-configuration보다 더 안정하다. ap-형이면 Z-configuration이 더 안정하다. C=N 결합의 configuration과 C-N 의 conformation이 같으면 N-O의 conformation이 ap-형인 것이 더 안정하다. 이 안정화 에너지의 대부분은 정전기적인 원자간에 힘에 기인하는 것임을 밝혔다.

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ON A CENTRAL LIMIT THEOREM FOR A STATIONARY MULTIVARIATE LINEAR PROCESS GENERATED BY LINEARLY POSITIVE QUADRANT DEPENDENT RANDOM VECTORS

  • Kim, Tae-Sung
    • 대한수학회지
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    • 제39권1호
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    • pp.119-126
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    • 2002
  • For a stationary multivariate linear process of the form X$_{t}$ = (equation omitted), where {Z$_{t}$ : t = 0$\pm$1$\pm$2ㆍㆍㆍ} is a sequence of stationary linearly positive quadrant dependent m-dimensional random vectors with E(Z$_{t}$) = O and E∥Z$_{t}$$^2$< $\infty$, we prove a central limit theorem.theorem.

Differential Subordination Properties of Sokół-Stankiewicz Starlike Functions

  • Omar, Rashidah;Halim, Suzeini Abdul
    • Kyungpook Mathematical Journal
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    • 제53권3호
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    • pp.459-465
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    • 2013
  • Let $p(z)$ be an analytic function defined on the open unit disk D and $p(0)=1$. Condition ${\beta}$ in terms of complex numbers D and real E with -1 < E < 1 and ${\mid}D{\mid}{\leq}1$ is determined such that $1+{\beta}{\prec}\frac{1+Dz}{1+Ez}$ implies $p(z){\prec}\sqrt{1+z}$. Furthermore, the expression $1+\frac{{\beta}zp^{\prime}(z)}{p(z)}$ and $1+\frac{{\beta}zp^{\prime}(z)}{p^2(z)}$ are considered in obtaining similar results.

Heterostructured Nanophotocatalysts for Degradation of Organophosphate Pesticides from Aqueous Streams

  • Kaur, Paramjeet;Bansal, Priti;Sud, Dhiraj
    • 대한화학회지
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    • 제57권3호
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    • pp.382-388
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    • 2013
  • The present paper focuses on the synthesis, characterization and application of nanophotocatalyst for degradation of quinalphos and monocrotophos. Novel heterostructured ZnO/$TiO_2$ photocatalyst ($Z_9T$) was prepared and characterized with X-ray diffraction (XRD), SEM and UV-vis diffuses reflectance spectroscopy. The average crystalline size of synthesized $Z_9T$ was found to be 21.48 nm. The pesticides were degraded in the presence of nanophotocatalysts i.e., $TiO_2$, ZnO, $TiO_2$/ZnO mixed in various proportions and heterostructured nanophotocatalyst synthesized by Sol-Gel method. The batch experiments were performed by adding photocatalyst to 100 ml of pesticide solution and suspension was subjected to irradiation under UV light. In case of mixed catalyst, the maximum degradation of monocrotophos and quinalphos has been observed when ZnO and $TiO_2$ were in the ratio of 7:3 and 8:2 respectively. The degradation efficiency with synthesized heterostructured nanophotocatalyst ($Z_9T$) was found to be comparable with $TiO_2$.

고주파 마그네트론 스퍼터링 방법으로 증착한 PDP용 ${Mg_{1-x}}{Zn_x}$O 보호막의 전기광학적 특성연구 (Electro-optical Properties of ${Mg_{1-x}}{Zn_x}$O Thin Films Grown by a RF Magnetron Sputtering Method as a Protective Layer for AC PDPs)

  • 정은영;이상걸;이도경;이교중;손상호
    • 한국재료학회지
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    • 제11권3호
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    • pp.197-202
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    • 2001
  • 교류구동형 플라즈마 표시소자의 보호막으로 사용되는 MgO의 특성향상을 위하여 기존의 MgO에 양이온이 등전적으로 치환될 수 있는 ZnO를 소량 첨가하여 고주파 마그네트론 스퍼터링 방법으로 $Mg_{1-x}$Z $n_{x}$O박막을 성장시키고 박막의 전기적, 광학적 특성을 조사하였다. ZnO농도가 0.5 at%, 1at%인 $Mg_{1-x}$Z $n_{x}$O 박막을 보호막으로 갖는 PDP 테스트 판넬을 제작하고 ZnO의 첨가가 소자의 방전전압과 메모리 이득에 미치는 영향을 살펴보았다. ZnO농도가 0at%, 0.5 at%, 1at%인 $Mg_{1-x}$Z $n_{x}$O 박막의 광투과율은 ZnO 첨가에 따라 변화를 보이지 않으나 유전상수는 다소 증가하는 경향을 보였다. ZnO의 농도가 0.5 at%인 $Mg_{1-x}$Z $n_{x}$O 박막을 보호막으로 갖는 PDP 소자의 방전개시전압과 방전유지 전압이 MgO 박막을 보호막으로 갖는 소자에 비해 20V까지 낮아졌고, 결과적으로 메모리계수는 다소 증가하였다. ZnO농도가 0.5 at%, 1at%인 $Mg_{1-x}$Z $n_{x}$O 박막을 보호막으로 갖는 소자에서 ZHO의 첨가에 비례하여 방전세기 (플라즈마 밀도)가 증가하였다.도)가 증가하였다.도)가 증가하였다.

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Effect of Bi4Zr3O12 on the properties of (KxNa1-x)NbO3 based ceramics

  • Mgbemere, Henry. E.;Akano, Theddeus T.;Schneider, Gerold. A.
    • Advances in materials Research
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    • 제5권2호
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    • pp.93-105
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    • 2016
  • KNN-based ceramics modified with small amounts of $Bi_4Zr_3O_{12}$ (BiZ) has been synthesized using high-throughput experimentation (HTE). The results from X-ray diffraction show that for samples with base composition $(K_{0.5}Na_{0.5})NbO_3$ (KNN), the phase present changes from orthorhombic to pseudo-cubic with more than 0.2 mol% BiZ addition; for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.9}Ta_{0.1})O_3$ (KNNLT), the phase present changes from a mixture of orthorhombic and tetragonal symmetry to pseudo-cubic with more than 0.4 mol % while for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.86}Ta_{0.1}Sb_{0.04})O_3$ (KNNLST), the phase present is tetragonal with <0.3 mol% BiZ addition and transforms to pseudo-cubic with more dopant addition. The microstructures of the samples show that addition of BiZ decreases the average grain size and increases the volume of pores at the grain boundaries. The values of dielectric constant for KNN and KNNLT compositions increase slightly with BiZ addition while that for KNNLST decreases gradually with BiZ addition. The dielectric loss values are between 0.02 and 0.04 for KNNLT and KNNLST compositions while they are ~ 0.05 for KNN samples. The resistivity values increases with BiZ addition and values in the range of $10^{10}{\Omega}cm$ and $10^{12}{\Omega}cm$ are obtained. The piezoelectric charge coefficient ($d{^*}_{33}$) is highest for KNNLST samples and decreases gradually from ~400 pm/V to ~100 pm/V with BiZ addition.

영어 치찰음 발음에 미치는 모음의 영향 연구 (A Study of the Effects of Vowels on the Pronunciation of English Sibilants)

  • 구희산
    • 음성과학
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    • 제15권3호
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    • pp.31-38
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    • 2008
  • The aim of this study was to find how English vowels affect the pronunciation of English sibilants /$d_3,\;{_3}$, z/ by Korean learners of English. Fifteen nonsense syllables composed by five vowels /a, e, i, o, u/ were pronounced six times by twelve Korean learners of English. Test scores were measured from the scoreboard made by a speech training software program, which was designed for English pronunciation practice and improvement. Results show that 1) the subjects had the lowest scores in /a_a/ position, and 2) subjects had lower scores in the /i_i/ position than in /e_e/, /o_o/ and /u_u/ positions when they pronounced $/d_3/,\;/{_3}/$, and /z/ in their respective inter-vocalic position. This study found that for the group studied Korean learners of English have more difficulty in pronouncing sibilants in /a_a/ and /i_i/ positions than in the other positions.

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A FUNCTIONAL CENTRAL LIMIT THEOREM FOR MULTIVARIATE LINEAR PROCESS WITH POSITIVELY DEPENDENT RANDOM VECTORS

  • KO, MI-HWA;KIM, TAE-SUNG;KIM, HYUN-CHULL
    • 호남수학학술지
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    • 제27권2호
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    • pp.301-315
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    • 2005
  • Let $\{A_u,\;u=0,\;1,\;2,\;{\cdots}\}$ be a sequence of coefficient matrices such that ${\sum}_{u=0}^{\infty}{\parallel}A_u{\parallel}<{\infty}$ and ${\sum}_{u=0}^{\infty}\;A_u{\neq}O_{m{\times}m}$, where for any $m{\times}m(m{\geq}1)$, matrix $A=(a_{ij})$, ${\parallel}A{\parallel}={\sum}_{i=1}^m{\sum}_{j=1}^m{\mid}a_{ij}{\mid}$ and $O_{m{\times}m}$ denotes the $m{\times}m$ zero matrix. In this paper, a functional central limit theorem is derived for a stationary m-dimensional linear process ${\mathbb{X}}_t$ of the form ${\mathbb{X}_t}={\sum}_{u=0}^{\infty}A_u{\mathbb{Z}_{t-u}}$, where $\{\mathbb{Z}_t,\;t=0,\;{\pm}1,\;{\pm}2,\;{\cdots}\}$ is a stationary sequence of linearly positive quadrant dependent m-dimensional random vectors with $E({\mathbb{Z}_t})={{\mathbb{O}}$ and $E{\parallel}{\mathbb{Z}_t}{\parallel}^2<{\infty}$.

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Chemical Constituents from Artemisia iwayomogi Increase the Function of Osteoblastic MC3T3-E1 Cells

  • Ding, Yan;Liang, Chun;Choi, Eun-Mi;Ra, Jeong-Chan;Kim, Young-Ho
    • Natural Product Sciences
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    • 제15권4호
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    • pp.192-197
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    • 2009
  • Chemical investigation of the aerial parts of Artemisia iwayomogi has afforded five glycoside compounds. Their chemical structures were characterized by spectroscopic methods to be turpinionoside A (1), (Z)-3-hexenyl O-${\alpha}$-arabinopyranosyl-(1${\rightarrow}$6)-O-${\beta}$-D-glucopyranoside (2), (Z)-5'-hydroxyjasmone 5'-O-${\beta}$-Dglucopyranoside (3), (-)-syringaresinol-4-O-${\beta}$-D-glucopyranoside (4), and methyl 3,5-di-O-caffeoyl quinate (5). All of them were isolated for the first time from Artemisia species. The effect of compounds 1 - 5 on the function of osteoblastic MC3T3-E1 cells was examined by checking the cell viability, alkaline phosphatase (ALP) activity, collagen synthesis, and mineralization. Turpinionoside A (1) significantly increased the function of osteoblastic MC3T3-E1 cells. Cell viability, ALP activity, collagen synthesis, and mineralization were increased up to 117.2% (2 ${\mu}M$), 110.7% (0.4 ${\mu}M$), 156.0% (0.4 ${\mu}M$), and 143.0 % (2 ${\mu}M$), respectively.