• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1516-1518
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• 1998

$YBa_2Cu_3O_x$(Yl23) Superconducting thick films on $Y_2BaCuO_5$(Y211) substrate were Prepared by surface diffusion process between $BaCuO_2$+CuO composite coating powder and a Y2ll substrate. X-ray diffraction shows that the Yl23 layer onto Y2ll substrate is the orthorhombic crystal structure. The specimen heated at $940^{\circ}C$ for 2h showed the maximum $J_c$ fo 500A/$cm^2$. Based on optimal condition, the superconducting fault current limiter(FCL) having a current limiting area 1mm wide and 66mm long was fabricated on Y211 substrate. A typical current limiting waveform was measured. When a voltage of 3V was applied, the fault current with a peak of 15A was limited to about 0.11A.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권4호
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• pp.221-225
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• 1999

This paper shows the parameters to affect the critical characteristic of YBaCuO superconducting bulk fabricated by MPMG (Melt Powdered Melt Growth)process. In order to investigate proper processing variables, the effect of the holding time at the melting temperature and that of the slow cooling time in $O_2\; ambient\; on\; the\; J_c$ were experimented. And then with the above obtained heat treatment conditions, the effects of addition of $Y_2BaCuO_5\; and\; Ag\; on\; the\; J_c$ were also investigated. A proper slow cooling time yields phase transformation from Tetragonal $(YBa_2Cu_3O_6)$ to Orthorhombic $(YBa_2Cu_3O_7)$ during an annealing time in $O_2$. Ag addition plays a role in increasing the $T_c\; and\; the J_c$, but the magnetization decreases. The $J_c$ and the magnetization increase with addition of Y211. $J_c$ of the sample added Ag 10wt% is superiorover 3000 G. Proper holding time, slow cooling time and amount of impurity addition are important parameters in fabricating the YBaCuO bulk by MPMG process with high $J_c$.

• Progress in Superconductivity
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• 제6권1호
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• pp.41-45
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• 2004

Polycrystalline Tl-1223 superconductors with a chemical composition of (Tl, Pb, Bi)TEX>$ (Sr, Ba)<_2$$Ca_2$$Cu_3$$O_{x}$ were synthesized by the solid state reaction method. The optimum chemical composition was $Tl_{0.8}$ $Pb_{0.2}$ $Bi_{0.2}$ $Sr_{1.8}$ $Ba_{0.2}$ $Ca_{2.2}$ $Cu_3$$O_{x}$ And the optimum sintering temperature and time were $905^{\circ}C$ and 7.5h, respectively. The sample was evaluated for their superconducting properties by magnetization measurement. The critical temperature $T_{c}$ is 120 K and the critical current density $J_{c}$ (T=5K, 0T) is estimated to be ∼ $10^{5}$ A/$\textrm{cm}^2$ for $Tl_{0.8}$ $Pb_{0.2}$ $Bi_{0.2}$ $Sr_{1.8}$ $Ba_{0.2}$ $Ca_{2.2}$$Cu_3$$O_{x}$ .

• E2M - 전기 전자와 첨단 소재
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• 제5권3호
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• pp.278-283
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• 1992

123 초전도체에 마그네틱 모멘트가 큰 Ni불순물을 도핑하여 제작한 $Y_{1}$ Ba(C $u_{2.9}$ $N_{0.1}$) $O_{7-{\delta}}$ 초전도체의 X-ray diffraction pattern, susceptibility, 온도변화등에 따른 전류-전압관계, 임계온도 등에 대하여 연구하였다. 제작된 시료는 매우 뚜렷한 orthorhombic 피크를 가진 123상을 나타내고 있었다. N=0.1의 시료에서는 적은 양의 Ni 불순물과 단면적인 무정형상태의 잘 반응된 YBa(Cu, Ni)$_{3}$ $O_{7-{\delta}}$의 orthorhombic구조를 나타내고 있다. 전반적인 실험 결과로 부터 Ni는 Y-Ba-Cu-O 초전도 시스템에서 초전도에 중요한 역할을 담당하지 않는다는 결론을 얻었다.얻었다.다.

• 한국분말재료학회지
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• 제20권2호
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• pp.142-147
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• 2013

$YBa_2Cu_3O_{7-y}$ (Y123) powders for the fabrication of bulk superconductors were synthesized by the powder reaction method using $Y_2O_3$ (99.9% purity), $BaCO_3$ (99.75%) and CuO (99.9%) powders. The raw powders were weighed to the cation ratio of Y:Ba:Cu=1:2:3, mixed and calcined at $880^{\circ}C-930^{\circ}C$ in air with intermediate repeated crushing steps. It was found that the formation of Y123 powder was more sensitive to reaction temperature than reaction time. The calcined Y123 powder and a mixture of (Y123 + 0.25 mole $Y_2O_3$ + 1 wt.% $CeO_2$, $Y_{1.5}Ba_2Cu_3O_x$ (Y1.5)) were used as raw powders for the fabrication of poly-grain or single grain superconductors. The superconducting transition temperature ($T_{c,onset}$) of the sintered Y123 sample was 91 K and the transition width was as large as 11 K, whereas the $T_{c,onset}$ of the melt-grown Y1.5 sample was 90.5 K and the transition width was 3.5 K. The critical current density ($J_c$) at 77 K and 0 T of the sintered Y123 was 700 $A/cm^2$, whereas the $J_c$ of the top-seeded melt growth (TSMG) processed Y1.5 sample was $3.2{\times}10^4\;A/cm^2$. The magnetic flux density (H) at 77 K of the TSMG-processed Y123 and Y1.5 sample showed the 0.53 kG and 2.45 kG, respectively, which are 15% and 71% of the applied magnetic field of 3.5 kG. The high H value of the TSMG-processed Y1.5 sample is attributed to the formation of the larger superconducting grain with fine Y211 dispersion.

• 한국초전도ㆍ저온공학회논문지
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• 제13권4호
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• pp.22-25
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• 2011

A single-coat $YBa_2Cu_3O_{7-{\delta}}$ (YBCO) film of high critical currents ($I_c$) could be successfully fabricated by optimizing the viscosity of the coating solution in the metal-organic deposition (MOD) process. From a Ba-deficient coating solution (Y: Ba: Cu = 1: 1.5: 3) having the viscosity of 212 $mPa{\cdot}sec$, 0.9 ${\mu}m$-thick single coat YBCO film with the $I_c$ value of 289 A/cm-width ($J_c$ = 3.2 MA/$cm^2$) at 77 K was achievable on the $SrTiO_3$ (STO) substrate, which was superior to that of our previous report for 0.8 ${\mu}m$-thick single coat YBCO film from a stoichiometric coating solution (Y: Ba: Cu = 1: 2: 3) on the $LaAlO_3$ (LAO) substrate. This result might be attributed to denser and more homogeneous microstrcuture in the case of the YBCO film from the Ba-deficient coating solution.

• 한국진공학회지
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• 제1권3호
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• pp.389-394
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• 1992

용액분무법으로 (100) MgO 단결정 기판위에 YBa2Cu3O7-x 초전도박막을 제조하 였다. YBa2Cu3O7-x 초전도 박막의 Y, Ba, Cu 원자의 상대적인 비는 EDX의 검출 한계내에 서 1 : 2 : 3이었고, 이는 분무 용액속의 금속이온의 비와 같았다. YBa2Cu3O7-x 초전도 박 막의 결정구조는 단일 상의 사방구조였으며, 기판에 수직인 c축의 방향으로 grain이 성장되 었고, 격자상수 c0는 11.678$\AA$였다. 95$0^{\circ}C$의 공기중에서 10분간 열처리한 박막의 Tc-on=100K, Tc-zero=80K, Jc=2.5 $\times$ 104A/cm2였고, 95$0^{\circ}C$의 흐르는 산소분위기에서 10분간 열처리한 박막의 Tc-on=103K, Tc-zero=80K, Jc=1.0 $\times$ 105A/cm2였다. 초전도 박막의 미세구 조, grain 크기와 grain 경계폭은 제조후 열처리(post-annealing) 시간과 가스 분위기에 강 한 영향을 받았다.

• The Korean Journal of Ceramics
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• 제6권2호
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• pp.164-167
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• 2000

The barium rich region of the Y-Ba-Cu-O-C system includes a tetragonal perovskite-like phase, which possesses a wide homogeneity region toward yttrium, copper and carbonate ion on the one hand, and toward oxygen, on the other hand. Accounting for vacancies ($\square$-vacancy) this phase could be described by the general formula per unit cell: {Ba$_8$}[Y$_{3-z}$Cu$_{5-x}$$(CO_3)_n$ $\square$$_{x+x-n}$]O$_{y{\pm}{\delta}y}$ (*). Here, cube-octahedral sites are represented in braces, while quasioctahedral ones with proper octahedral (Y, Cul), square (Cu2) and triangular (CO$_3$) configuration are shown in square brackets. The formula (*) was confirmed by full-profile Rietveld refinement based on X-ray diffraction data of YBa$_{5}$Cu$_2$O$_y$ (1-5-2 phase). Homogeneity region limits of the phase (*) at 96$0^{\circ}C$ in air were determined to be -0.33$\leq$x$\leq$1.80, 0.33$\leq$z$\leq$2.00, 0$\leq$n$\leq$3.

• 한국초전도ㆍ저온공학회논문지
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• 제1권1호
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• pp.1-6
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• 1999

The microstructures of top seed mult processde $\textrm{YBa}_2\textrm{Cu}_3\textrm{O}_7$.$\delta$ single crystal were studied. Although shape of the seed was not faceted. the growth shape of Y123 single crystal was faceted. It was observed that Y211 phases were trapped in specific spaces of the faceted region. From the microstructural investigation. it was suggested that the segregation of Y211 is due to the difference of growth rates in crystal direction. When a single crystal was grown by the single seed with stepped multi surfaces. a microstrue was grown from multi-seed. The microstructure show the possibility of multi-seed growth. Corn kernel like structure without Y211 phase was observed and seemed to be formed by the diffusion reaction between Y211 phase in crystal and liquid wetted on the crystal. the diagonal line on Y123 crystal was observed that it was formed by the corn kernel like structure.

• Progress in Superconductivity
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• 제14권1호
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• pp.39-44
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• 2012

The fabrications condition and superconducting properties of top-seeded melt growth (TSMG) processed $GdBa_2Cu_3O_{7-y}$ (Gd123) bulk superconductors were studied. Processing parameters (a maximum temperature ($T_{max}$), a temperature for crystal growth ($T_G$) and a cooling rate ($R_G$) through a peritectic temperature ($T_P$) for the fabrication of single grain Gd123 superconductors were optimized. The magnetic levitation forces, trapped magnetic fields, superconducting transition temperature ($T_c$) and critical current density ($J_c$) of the Gd123 bulks superconductors were estimated. Single grain Gd123 bulk superconductors were successfully fabricated at the optimized processing condition. The $T_c$ of a TSMG processed Gd123 sample was 92.5 K and the $J_c$ at 77 K and 0 T was approximately $50kA/cm^2$. The trapped magnetic field contour and magnetic levitation forces were dependent on the top surface morphology of TSMG processed Gd123 samples. The single grain Gd123 samples, field-cooled at 77 K using a Nd-B-Fe permanent magnet with 5.27 kG and 30 mm dia., showed the trapped magnetic field contour of a single grain with a maximum of 4 kG at the sample center. The maximum magnetic levitation forces of the single grain Gd123 sample, field-cooled or zero field-cooled, were 40 N and 107 N, respectively.