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Preparation of Hard Magnetic $Sm_2Fe_{17}N_x$ Compound by Mechanical Alloying (기계적 합금화법에 의한 영구자석용 $Sm_2Fe_{17}N_x$ 화합물의 제조)

  • 이충효;김명근;석명진;김지순;윤석길;권영순
    • Journal of Powder Materials
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    • v.8 no.1
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    • pp.55-60
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    • 2001
  • Mechanical alloying technique was applied to prepare hard magnetic $Sm_2Fe_{17}N_x$ compound powders. Staring from pure Fe and Sm powders, the formation process of hard magnetic $Sm_2Fe_{17}N_x$ phase by mechanical alloying and subsequent solid state reaction was studied. As milled powders were found to consist of Sm-Fe amorphous and $\alpha$-Fe phases in all compositions of $Sm_xFe_{100-x}$(x = 11, 13, 15, 17). The effects of starting composition on the formation of $Sm_2Fe_{17}$ intermetallic compound was investigated by heat treatment of mechanically-alloyed powders. When Sm content was 15 at.%, heat-treated powders consisted of nearly $Sm_2Fe_{17}$ single phase. For preparation of hard magnetic $Sm_2Fe_{17}N_x$ powders, additional nitriding treatment was performed under $N_2$ gas flow at 45$0^{\circ}C$. The increase in the coercivity and remanence was proportional to the nitrogen content which increased drastically at first and then increased gradually as the nitriding time was extended to 3 hours.

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Molecular Study of X-Chromosome Mosaicism in Turner Syndrome Patients using DNAs Extracted from Archives Cytogenetic Slides

  • Cho, Eun-Hee;Kim, Jin-Woo;Kim, Young-Mi;Ryu, Hyun-Mee;Park, So-Yeon
    • Journal of Genetic Medicine
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    • v.3 no.1
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    • pp.21-24
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    • 1999
  • To study the X chromesome mosaicism in the cytogenetically pure 45,X Turner syndrome patients, we applied PCR technique using DNAs extracted from archived cytogenetic slides. We amplified the DNAs using nested primers targeted to a highly polymorphic short tandem repeat(STR) of the human androgen receptor gene(HUMARA) for the detection of X chromosome mosaicism. This assay is a very sensitive and useful method which can be applied to the DNAs extracted from archived cytogenetic slides to detect X mosaicism. We have tested 50 normal Korean females to determine whether the HUMARA locus is highly polymorphic among Koreans. 85% of Korean population showed heterozygosity in the HUMARA locus. We analysed the 24 DNAs extracted from archived slides of patients and abortuses with Turner syndrome in cytogenetic analysis. We observed the heterozygosities of 50% from pure 45,X patients, 83% from the patients with mosaic Turner syndrome and 8.3% from the abortuses of pure 45,X. Using the PCR technique of the HUMARA locus in the archived cytogenetic slides, we detected X chromosome mosaicism which could not be detected in cytogenetic analysis.

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A GENERALIZATION OF MAYNARD'S RESULTS ON THE BRUN-TITCHMARSH THEOREM TO NUMBER FIELDS

  • Ahn, Jeoung-Hwan;Kwon, Soun-Hi
    • Journal of the Korean Mathematical Society
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    • v.59 no.5
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    • pp.843-867
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    • 2022
  • Maynard proved that there exists an effectively computable constant q1 such that if q ≥ q1, then $\frac{{\log}\;q}{\sqrt{q}{\phi}(q)}Li(x){\ll}{\pi}(x;\;q,\;m)<\frac{2}{{\phi}(q)}Li(x)$ for x ≥ q8. In this paper, we will show the following. Let 𝛿1 and 𝛿2 be positive constants with 0 < 𝛿1, 𝛿2 < 1 and 𝛿1 + 𝛿2 > 1. Assume that L ≠ ℚ is a number field. Then there exist effectively computable constants c0 and d1 such that for dL ≥ d1 and x ≥ exp (326n𝛿1L(log dL)1+𝛿2), we have $$\|{\pi}_C(x)-\frac{{\mid}C{\mid}}{{\mid}G{\mid}}Li(x)\|\;{\leq}\;\(1-c_0\frac{1og\;d_L}{d^{7.072}_L}\)\;\frac{{\mid}C{\mid}}{{\mid}G{\mid}}Li(x)$$.

MECHANICAL PROPERTIES AND CORROSION BEHAVIORS OF AGED Ti-4Mo-4Cr-X (X = Sn, V, Zr) ALLOYS FOR METALLIC BIOMATERIALS

  • KWANGMIN LEE;GUNHEE LEE
    • Archives of Metallurgy and Materials
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    • v.65 no.4
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    • pp.1297-1301
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    • 2020
  • The purpose of this study was to investigate the mechanical properties of beta type aged Ti-4Mo-4Cr-X (X = V, Sn, Zr) quaternary alloy for use as a cardiovascular stent. Titanium (Ti) alloys were fabricated using a vacuum arc remelting furnace process. To homogenize the specimens of each composition and remove the micro segregation, all cast specimens were subjected to homogenization at 850℃ for 4 h, which was 100℃ higher than the β-transus temperature of 750℃. The tensile strength and elongation of the aged Ti-4Mo-4Cr-X (X = V, Sn, Zr) alloys were increased as compared to the homogenized alloys. In addition, many α/β interface boundaries formed after aging treatment at 450℃, which acted as inhibitors of strain and caused an increase in tensile strength. The elongation of Ti-4Mo-4Cr-X alloys consisting of α + β phases after aging treatment was improved by greater than 30%. Results of a potentiodynamic polarization test showed that the lowest current density of Ti-4Mo-4Cr-4Sn with 1.05 × 10-8 A/cm2 was obtained. The present Ti-4Mo-4Cr-X alloys showed better corrosion characteristics as compared to the 316L stainless steel and L605 (Co-Cr alloy) cardiovascular stent alloys.

A Study of cut off effect of ultraviolet in sunglasses lens coated with nickel-ferrite thin film NxFe3-xO4 (니켈페라이트 박막 NxFe3-xO4를 이용한 선글라스 렌즈의 자외선 차단효과에 대한 연구)

  • Ha, T.W.;Lee, Y.H.;Choi, K.S.;Cha, J.W.
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.2
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    • pp.25-29
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    • 2003
  • Nickel-ferrite $Ni_xFe_{3-x}O_4$ thin films with several composition for Ni on glass substrate was prepared by ferrite plating method in order to make sunglass which cut off ultraviolet and shield electromagnetic field. It has single phase of polycrystalline spinel structure and has gloss as mirror and has high hardness which is no scratch while scraping by using nail. The transmittance of nickel-ferrite thin film is lowered to zero below 400 nm manifestly. And it shows that the nickel-ferrite thin film in nickel composition rate x = 0.09 was most cut oil ultraviolet when compared with goods of other company in the cut off effect of ultraviolet. Therefore, sunglasses coated with $Ni_xFe_{3-x}O_4$ thin film can be used in removing ultraviolet and electromagnetic field.

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Transport parameters in a-Se:As films for digital X-ray conversion material (디지털 X-선 변환물질 a-Se:As의 수송변수)

  • Park, Chang-Hee
    • Korean Journal of Digital Imaging in Medicine
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    • v.8 no.1
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    • pp.51-55
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    • 2006
  • The effects of Asaddition in amorphous selenium(a-Se) films for digital X-ray conversion material have been studied using the moving photocarrier grating(MPG) technique. This method utilizes the moving interference pattern generated by the superposition of the two frequency shifted laser beams for the illumination of the sample. This moving intensity grating induces a short circuit current, j$_{sc}$ in a-Se:As film. The transport parameters of the sample are extracted from the grating-velocity dependent short circuit current induced in the sample along the modulation direction. The electron and hole mobility, and recombination lifetime of a-Se films with arsenic(As) additions have been obtained. We have found an Increase in hole drift mobility and recombination lifetime, especially when 0.3% As is added into a-Se film, whereas electron mobility decreases with As addition due to the defect density. The transport properties for As doped a-Se films obtained by using MPG technique have been compared with X-ray sensitivity for a-Se:As device. The fabricated a-Se(0.3% As) device film exhibited the highest X-ray sensitivity out of 5 samples.

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Leakage and scattered radiation from hand-held dental x-ray unit (이동용 치과 X선 발생장치의 누설 및 산란 선량에 관한 연구)

  • Kim, Eun-Kyung
    • Imaging Science in Dentistry
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    • v.37 no.2
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    • pp.65-68
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    • 2007
  • Purpose: To compare the leakage and scattered radiation from hand-held dental X-ray unit with radiation from fixed dental X-ray unit. Materials and Methods: For evaluation we used one hand-held dental X-ray unit and Oramatic 558 (Trophy Radiologie, France), a fixed dental X-ray unit. Doses were measured with Unfors Multi-O-Meter 512L at the right and left hand levels of X-ray tube head part for the scattered and leakage radiation when human skull DXTTR III was exposed to both dental X-ray units. And for the leakage radiation only, doses were measured at the immediately right, left, superior and posterior side of the tube head part when air was exposed. Exposure parameters of handheld dental X-ray unit were 70 kVp, 3 mA, 0.1 second, and of fixed X-ray unit 70 kVp, 8 mA, 0.45 second. Results: The mean dose at the hand level when human skull DXTTR III was exposed with portable X-ray unit $6.39{\mu}Gy$, and the mean dose with fixed X-ray unit $3.03{\mu}Gy$ (p<0.001). The mean dose at the immediate side of the tube head part when air was exposed with portable X-ray unit was $2.97{\mu}Gy$ and with fixed X-ray unit the mean dose was $0.68{\mu}Gy$ (p<0.01). Conclusions: The leakage and scattered radiation from hand-held dental radiography was greater than from fixed dental radiography.

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Physical Properties of Polycrystalline Zinc-Substituted Lithium Ferrite (ZnO가 Lithium ferrite의 물리적 특성에 미치는 영향에 관한 연구)

  • 고재귀
    • Journal of the Korean Magnetics Society
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    • v.9 no.5
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    • pp.234-238
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    • 1999
  • Lithium ferrites are prominent in the element of microwave frequency communication core and high frequency memory core because of their low coercivity and the high squareness ratio. This paper reports primarily the development of lithium ferrites with the low coercivity and high squareness ratio. The materials with $Li_{0.48-0.5x}Bi_{0.02}Ni_{0.04}Zn_xFe_{2.46-0.5x}O_4$ (x = 0,0.01, 0.02, 0.03) have been prepared to investigate the physical properties. The addition of ZnO gave raised maximum induction $(B_m)$ and decreased coercive force $(H_c)$, but the squareness ratio $(R\;=\;B_m/B_r)$ was decreased. The specimen of squareness ratio R=0.82, coercive force $H_c=\;1.80\;Oe$ was obtained for $Li_{0.48-0.5x}Bi_{0.02}Ni_{0.04}Zn_xFe_{2.46-0.5x}O_4$ (X=0) sintered at 105$0^{\circ}C$. Also the sample of squareness ratio R = 0.75, coercive force $H_c=\;1.70\;Oe$ for $Li_{0.48-0.5x}Bi_{0.02}Ni_{0.04}Zn_xFe_{2.46-0.5x}O_4$ (X = 0) sintered at 110$0^{\circ}C$ was measured. The Tc was obtained 463$^{\circ}C$ and the Br of environmental temperature variation was stable.

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Effect of Fe and BO3 Substitution in Li1+xFexTi2-x(PO4)3-y(BO3)y Glass Electrolytes (Li1+xFexTi2-x(PO4)3-y(BO3)y 계 유리 전해질에서 Fe 및 BO3 치환 효과)

  • Choi, Byung-Hyun;Jun, Hyung Tak;Yi, Eun Jeong;Hwang, Haejin
    • Journal of the Korean Electrochemical Society
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    • v.24 no.3
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    • pp.52-64
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    • 2021
  • The effect of Fe and BO3 doping on structure, thermal, and electrical properties of Li1+xFexTi2-x(PO4)3-y(BO3)y (x = 0.2, 0.5)-based glass and glass ceramics was investigated. In addition, their crystallization behavior during sintering and ionic conductivity were also investigated in terms of sintering temperature. FT-IR and XPS results indicated that Fe2+ and Fe3+ ions in Li1+xFexTi2-x(PO4)3-y(BO3)y glass worked as a network modifier (FeO6 octahedra) and also as a network former (FeO4 tetrahedra). In the case of the glass with low substitution of BO3, boron formed (PB)O4 network structure, while boron preferred BO3 triangles or B3O3 boroxol rings with increasing the BO3 content owing to boic oxide anomaly, which can result in an increased non-bridging oxygen. The glass transition temperature (GTT) and crystallization temperature (CT) was lowered as the BO3 substitution was increased, while Fe2+ lowered the GTT and raised the CT. The ionic conductivity of Li1+xFexTi2-x(PO4)3-y(BO3)y glass ceramics were 8.85×10-4 and 1.38×10-4S/cm for x = 0.2 and 0.5, respectively. The oxidation state of doped Fe and boric oxide anomaly were due to the enhanced lithium ion conductivity of glass ceramics.

Influences of the Composition on Spectroscopic Characteristics of AlxGa1-xN Thin Films (AlxGa1-xN 박막의 조성이 분광학적 특성에 미치는 영향)

  • Kim, Dae Jung;Kim, Bong Jin;Kim, Duk Hyeon;Lee, Jong Won
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1281-1287
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    • 2018
  • In this study, $Al_xGa_{1-x}N$ films were grown on (0001) sapphire substrates by using metal-organic chemical vapor deposition (MOCVD). The crystallinity of the grown films was examined with X-ray diffraction (XRD) patterns. The surfaces and the chemical properties of the $Al_xGa_{1-x}N$ films were investigated using atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), respectively. The optical properties of the $Al_xGa_{1-x}N$ film were studied in a wide photon energy range between 2.0 ~ 8.7 eV by using spectroscopic ellipsometry (SE) at room temperature. The data obtained by using SE were analyzed to find the critical points of the pseudodielectric function spectra, $<{\varepsilon}(E)>=<{\varepsilon}_1(E)>+i<{\varepsilon}_2(E)>$. In addition, the second derivative spectra, $d^2<{\varepsilon}(E)>/dE^2$, of the pseudodielectric function for the $Al_xGa_{1-x}N$ films were numerically calculated to determine the critical points (CPs), such as the $E_0$, $E_1$, and $E_2$ structure. For the four samples (x = 0.18, 0.21, 0.25, 0.29) between a composition of x = 0.18 and x = 0.29, changes in the critical points (blue-shifts) with increasing Al composition at 300 K for the $Al_xGa_{1-x}N$ film were observed via ellipsometric measurements for the first time.