• YAKHAK HOEJI
• /
• v.17 no.2
• /
• pp.111-114
• /
• 1973

Je-chun clay, Hwa-soon bentonite, and Hwa-soon montmorillonite were treated with treated with organic solvents, i.e., ethylene glycol, ethanol, n-hexane, dioxane, ethylene chlorohydrin and obtained X-ray diffractograms were compared with those of the original samples. Organic solvent was adsorbed on the basal plane surfaces of Je-chun clay, Hwa-soon bentonite, Hwa-soon montmorillonite and, as a result, the axis spacing ws increased, However, organic solvent did not affect the non-expanding lattice of Japanese acid clay and the basal plane remained unchanged.

• Korean Journal of Agricultural Science
• /
• v.16 no.1
• /
• pp.102-110
• /
• 1989

Surface structure and X-ray diffractogram of gelatinized potato starch on heating temperature, time and additives were investigated by Scanning Electron Microscopy (SEM) and X-ray diffractometry. The results obtained are as follows; Potato starch had an amylose content of 23.5%, and blue value of 0.41. Raw potato starch granuls showed egg form. Destruction of starch granuls increased as gelatinizing time and temperature increased. The degree of gelatinization of potato starch showed to be 90% by X-ray diffractomertry at $70^{\circ}C$. There were no significant differences in degree of gelatinization of potato starch on gelatinizing time and phosphate concentration at $70^{\circ}C$. The degree of gelatinization of sample prepared was higher in presence of phosphate than in absence of phosphate.

• Journal of the Mineralogical Society of Korea
• /
• v.2 no.1
• /
• pp.18-25
• /
• 1989

The X-ray diffraction and electron microscopy study of the kaolin sample from Sancheong area show that the halloysite occurs as hydrated 10$\AA$ form. It implies that the 7$\AA$ reflection and hk-line splitting in the X-ray diffractogram are ascribed to kaolinite. Kaolinite in Sancheong kaolin is of a disordered type. It tends to be enriched in the colored part of kaolin samples. Quantitative analyses show that kaolin contains 16-57% halloysite and 10-55%kaolinite.

• Korean journal of food and cookery science
• /
• v.10 no.1
• /
• pp.76-79
• /
• 1994

This study was carried out to examine changes in morpholgy and crystallinity of cowpea starch during preparation of chongpo-mook(starch gel food). It was known by photornicroscopy under polarized light and X-ray diffractometry that cowpea starch had lost its crystallinity at the temperature range of 70∼75$^{\circ}C$ It also was obserbed by scanning electron microscopy that overall shape of starch granules was maintained inspite of swelling to considerable extent at the range of 65∼75$^{\circ}C$, however, granules were folded after solubles were extracted out of them above 85$^{\circ}C$. Mechanism of gelation seemed to be formation of junction zones stabilien by groups of weak H-bonds, not by recrystalliztion according to the results of DSC thermogram of reheating of sample pan after cooling and X-ray diffractogram of reheated cowpea starch gel.

• Korean journal of food and cookery science
• /
• v.13 no.4
• /
• pp.396-401
• /
• 1997

Physical Properties of Jeungpyun product were analyzed during fermentation in the ranges of 0 to 10 hours. Penetration value of Jeungpyun sample measured by penetrometer was increased greatly according to the development of fermentation time, recording maximum value, 135 at 7 hours. Specific volume and total pore ratio were also increased greatly in course of fermentation time, recording maximum value, 3.5 ㎤/g-dry matter and 54.9％ at fermentation time, 6 hours and 4 hours respectively while they were decreased since then. Some remaining peaks on X-ray diffractogram were seen in all the Jeungpyun samples. Micropores and macropores were observed on cross-sectional view of all the fermented Jeungpyun samples.

• Journal of the Korean Ceramic Society
• /
• v.29 no.3
• /
• pp.195-201
• /
• 1992

It had been studied the structure and the magnetic properties of singel phase Co2Y(Ba2Co2Fe12O22) powder, one of the hexagonal ferrite. The material was successfully prepared by a commercially applicable coprecipitation method. Adding asqueous solution of BaCl2, CoCl2 and FeCl2(Ba2+:Co2+:Fe2+=1:1:6 in mole ratio) to a mixture of NaOH and hydrogen peroxide solution, coprecipitate was formed with rapid oxidation of ferrous to ferric ion. The coprecipitate transformed to single phase Co2Y powder at heat treatment temperatures as low as 900$^{\circ}C$. The shape of Co2Y particles obtained at 900$^{\circ}C$ was hexagonal plate-like (diameter∼$\mu\textrm{m}$, aspect ratio>10). The structure of the Co2Y was refined by a Rietveld analysis of the measured X-ray diffractogram. The lattice parameters are ao=5.8602${\AA}$ and co=43.512${\AA}$. Co2Y is a soft magnetic material with saturation magnetization 30 emu/g and coecivity 170 . A standard X-ray diffraction pattern for Co2Y is proposed as well.

• Korean journal of food and cookery science
• /
• v.11 no.3
• /
• pp.282-286
• /
• 1995

Physicochemical properties of Jeungpyun dough were analyzed during fermentation in the ranges of 0 to 10 hours. Solube Protein and total content of free amino acid of Jeungpyun dough were decreased at the early stage of fermentation, recording minimum value, 0.292 mg/g-dry matter and 13.31 mg/100g-dry matter at fermentation time, 2 hours and 4 hours respectively while they were increased since then. It was observed that, although few changes occurred at the early stage of fermentation, the height of peak on X-ray diffractogram was decreased somewhat and some disintegration of starch granule on scanning electron micrograph occurred slightly in dough samples of above 6 hours of fermentation time.

• Korean Journal of Soil Science and Fertilizer
• /
• v.31 no.4
• /
• pp.334-341
• /
• 1998

Sodium hydroxide concentrations were adjusted to 2.0, 2.5, 3.0 and 3.5M by dissolution in seawater. The fly ash was hydrothermally reacted with sodium hydroxide solutions (1:8, W:V) at $100^{\circ}C$ under the closed system. X-ray diffractogram proved that Na-P1 type zeolite was produced from bituminous coal fly ash. It is different from the X-ray of artificial zeolite produced by using sodium hydroxide solution dissolving in distilled water. Solid sieve structure was developed well by hydrothermal reaction with the ash and 3.0M sodium hydroxide. However chinks were observed in the structure of the product by 3.5M sodium hydroxide. CEC of the artificial zeolite was $244.5cmol^+\;kg^{-1}$ at 2.0M, 259.8 at 3.0M, 263.4 at 3.0M and 179.8 at 3.5M after 24 hours hydrothermal reaction; Artificial zeolite having high CEC, above $244.5cmol^+\;kg^{-1}$ could produce by using lower concentration of NaOH prepared in seawater than other production methods.

• Advances in concrete construction
• /
• v.11 no.1
• /
• pp.73-80
• /
• 2021

Rice Husk Ash (RHA) geopolymer paste activated by sodium aluminate were characterized by X-ray diffractogram (XRD), scanning electron microscope (SEM), energy dispersion X-Ray analysis (EDAX)and fourier transform infrared spectroscopy (FTIR). Five series of RHA geopolymer specimens were prepared by varying the Si/Al ratio as 1.5, 2.0, 2.5, 3.0 and 3.5. The paper focuses on the correlation of microstructure with hardened state parameters like bulk density, apparent porosity, sorptivity, water absorption and compressive strength. XRD analysis peaks indicates quartz, cristobalite and gibbsite for raw RHA and new peaks corresponding to Zeolite A in geopolymer specimens. In general, SEM micrographs show interconnected pores and loosely packed geopolymer matrix except for specimens made with Si/Al of 2.0 which exhibited comparatively better matrix. Incorporation of Al from sodium aluminate were confirmed with the stretching and bending vibration of Si-O-Si and O-Si-O observations from the FTIR analysis of geopolymer specimen. The dense microstructure of SA2.0 correlate into better performance in terms of 28 days maximum compressive strength of 16.96 MPa and minimum for porosity, absorption and sorptivity among the specimens. However, due to the higher water demand to make the paste workable, the value of porosity, absorption and sorptivity were reportedly higher as compared with other geopolymer systems. Correlation regression equations were proposed to validate the interrelation between physical parameters and mechanical strength. RHA geopolymer shows comparatively lower compressive strength as compared to Fly ash geopolymer.

• Korean Journal of Food Science and Technology
• /
• v.32 no.2
• /
• pp.258-264
• /
• 2000

Starches from the eight varieties of rice were analyzed using scanning electron microscope(SEM), differential scanning calorimetry(DSC) and X-ray diffractometry, and tested on the starch-granule susceptibility to 15% $H_2SO_4$ and glucoamylase. The shape of starch granules from normal rice varieties and low-amylose mutants were polygonal while shrunken and floury mutants were globular. According to DSC, starches from Nampung CB243 showed higher onset temperature$(T_o)$, completion temperature$(T_c)$ and Punchilmi, Nampung EM90 showed higher enthalpy$({\triangle}H)$ of gelatinization than others. shr showed the highest hydrolysis rate to 15% $H_2SO_4$ while Nampung CB243 showed the lowest one. Eight varieties of rice starch granules showed A-type pattern on X-ray diffractograms. The lower amylose content rice varieties showed the higher hydrolysis rate treated with glucoamylase.