• Journal of the Korean Chemical Society
• /
• v.21 no.4
• /
• pp.246-255
• /
• 1977

The adsorption of methylmethacylate on layer silicates containing various interlayer cations has been studied by means of infrared spectroscopy and X-Ray. Several characteristic carbonyl bands of adsorbed methylmethacrylate appeared differently at the region of 1723∼1547$cm^{-1}$depending on the species of cation and the dehydration temperature. The carbonyl stretching band shifted about 190$cm^{-1}$ to lower frequencies has been observed only for polyvalent cations, which has been attributed to $>C=O{\cdot}{\cdot}{\cdot}M^{n+}$ complex formation. The band appeared at 1703∼1640$cm^{-1}$ is responsible for hydrogen bonding between carbonyl oxygen and cationic water or cationic hydroxyl group, and the degree of shift indicates good correlation with the polarizing power of the interlayer cations. However, the band appeared at 1723$cm^{-1}$ has not been correlated with the species of cation but assigned to the carbonyl stretching which reacted with the surface hydroxyl group. On the basis of interlamellar spacing, it is suggested that the molecular plane of MMA molecule is parallel to silicate layers.

• Korean Journal of Materials Research
• /
• v.25 no.9
• /
• pp.480-486
• /
• 2015

$Pb_{1-x}MoO_4:Er^{3+}/Yb^{3+}$ phosphors with various doping concentrations of $Er^{3+}$ and $Yb^{3+}$ ($x=Er^{3+}+Yb^{3+}$, $Er^{3+}=0.05$, 0.1, 0.2, and $Yb^{3+}=0.2$, 0.45) are successfully synthesized using a microwave sol-gel method, and the up-conversion photoluminescence properties are investigated. Well-crystallized particles, which are formed after heat treatment at $900^{\circ}C$ for 16 h, exhibit a fine and homogeneous morphology with particle sizes of $2-5{\mu}m$. Under excitation at 980 nm, the $Pb_{0.7}MoO_4:Er_{0.1}Yb_{0.2}$ and $Pb_{0.5}MoO_4:Er_{0.05}Yb_{0.45}$ particles exhibit a strong 525 nm emission band, a weak 550 nm emission band in the green region, and a very weak 655 nm emission band in the red region. The Raman spectra of the doped particles indicate the presence of strong peaks at higher and lower frequencies induced by the disordered structures of $Pb_{1-x}MoO_4$ through the incorporation of the $Er^{3+}$ and $Yb^{3+}$ ions into the crystal lattice, which results in the unit cell shrinkage accompanying the new phase formation of the $MoO_{4-x}$ group.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2007.06a
• /
• pp.273-278
• /
• 2007

2-D MT surveys at the Century mine in Australia have been performed with very far remote reference in Esashi, Japan as well as Gregory Downs, which are roughly 6400 km and 80 km apart from the field site, respectively. Long period pulsations observed in this survey generally showed dominant $H_x$ polarization than $H_y$; $H_x$ component is more than 3 times stronger than $H_y$ component. Polarity reversal in magnetic field pointing east ($H_y$ component) has also been observed in long period pulsations, while $H_x$ component remain coherent between the hemispheres. Though $H_x$ component shows relatively good coherency than $H_y$ component between the hemispheres at frequencies lower than 0.01 Hz, it seems rather too far to be used as a remote reference for ordinary MT frequency band.

• The Journal of the Acoustical Society of Korea
• /
• v.34 no.5
• /
• pp.335-342
• /
• 2015

Phononic crystals are composite materials consisting of a periodic arrangement of scattering inclusions in a host material. One of the most important properties of phononic crystals is the existence of band gaps, i.e., ranges of frequencies at which acoustic waves cannot propagate through the structure. The present study aims to investigate theoretically and experimentally the acoustic band structures in two-dimensional (2D) phononic crystals consisting of periodic square arrays of stainless steel solid cylinders with a diameter of 1 mm and a lattice constant of 1.5 mm in water. The theoretical dispersion relation that depicts the relationship between the frequency and the wave vector was calculated along the ${\Gamma}X$ direction of the first Brillouin zone using the finite element method to predict the band structures in the 2D phononic crystals. The transmission and the reflection coefficients were measured in the 2D phononic crystals with 1, 3, 5, 7, and 9 layers of stainless steel cylinders stacked in the perpendicular direction to propagation at normal incidence. The theoretical dispersion relation exhibited five band gaps at frequencies below 2 MHz, the first gap appearing around a frequency of 0.5 MHz. The location and the width of the band gaps experimentally observed in the transmission and the reflection coefficients appeared to coincide well with those determined from the theoretical dispersion relation.

• Journal of the Korean Ceramic Society
• /
• v.52 no.1
• /
• pp.66-71
• /
• 2015

$NaY_{1-x}(WO_4)_2:Ho^{3+}/Yb^{3+}$ phosphors with doping concentrations of $Ho^{3+}$ and $Yb^{3+}$ ($x=Ho^{3+}+Yb^{3+}$, $Ho^{3+}=0.05$, 0.1, 0.2, and $Yb^{3+}=0.2$, 0.45) were successfully synthesized via the cyclic microwave-modified sol-gel route; their upconversion properties were investigated. Well-crystallized particles showed a fine and homogeneous morphology with particle sizes of $2-5{\mu}m$. Under excitation at 980 nm, the synthesized particles exhibited yellow emissions based on a strong 550-nm emission band in the green region and a very strong 655-nm emission band in the red region. The Raman spectra of the doped particles indicated the domination of strong peaks at higher and lower frequencies induced by the incorporation of the $Ho^{3+}$ and $Yb^{3+}$ elements into the $Y^{3+}$ sites in the crystal lattice, which resulted in unit cell shrinkage that accompanied a new phase formation of the $WO_{4-x}$ group.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.20 no.9
• /
• pp.967-973
• /
• 2009

In this paper, X-band satellite communication oscillator of double phase locked is implemented by constructing a couple of phased-locked loop, and then we have analyzed the phase noise of designed PLL-DRO. The designed phase-locked oscillator is consist of series feedback DRO, frequency divider, phase detector, loop filter and programmable PLL-IC. By dividing oscillation frequency of 12.6 GHz into two frequencies, it exhibits output power of 15.32 dBm at 6.3 GHz. Phase noises of implemented oscillator are -81 dBc/Hz@100Hz, -100.86 dBc/Hz@1 kHz, -111.12 dBc/Hz@10 kHz, -116 dBc/Hz@100 kHz and -140.49 dBc/Hz@1 MHz respectively. These indicate excellent stable operation of oscillator and very good phase noise characteristics.

• Proceedings of the KIEE Conference
• /
• 1987.07a
• /
• pp.110-114
• /
• 1987

A method for synthesizing low-pass elliptic filters in a microstrip configuration is presented. The realization consists of the cascade connection of proper rectangular elements, each one corresponding to four reactive elements of the lumped-constant prototype. This allows an effictive control of parasitics and unwanted reactances. Which results in the possibility of realizing higher order filters with cutoff frequencies UP to X-band. Fifth and seventh order filters were fabricated on allumina substrates.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.27 no.4
• /
• pp.399-402
• /
• 2016

We propose a thin electromagnetic wave absorber using varactor diodes combined with intentionally introduced multiple slits, which enables continuous sweep of an absorption frequency band throughout relatively wide frequencies. The absorption frequency range of conventional electrically tunable absorbers has been restricted by high capacitance of varactor diodes. In order to overcome the problem, we introduce parasitic capacitance and connect them with varactors in series, which reduces the total capacitance dramatically. As a result, we can raise the operating absorption frequency up to the X-band region. Moreover, we can also control the operating frequencies by modifying the number of slits with little change in an entire frequency sweep range. Good agreement between simulated and measured results show the validity of our proposal.

• Korean Journal of Remote Sensing
• /
• v.20 no.1
• /
• pp.39-46
• /
• 2004

The generalized Rayleigh-Gans (GRG) approximation is usually used to compute the scattering amplitudes of leaves smaller or comparable to a wavelength, while the physical optics (PO) approach with the resistive sheet approximation is commonly used for leaves larger or comparable to the wavelength. In this paper, the scattering amplitudes of an elliptical leaf are computed using those theoretical scattering models (GRG and PO) at different frequencies. The accuracies of the analytical models for microwave scattering from deciduous leaves are investigated by comparison with the precise estimation by the method of moment (MoM). It was found that both the PO approach and the GRG approximation can be used alternatively for computing the scattering matrices of natural deciduous leaves at P-, L-, C- and X-band frequencies.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
• /
• 2000.11a
• /
• pp.268-271
• /
• 2000

본 논문에서는 X-band의 10.5 GHz와 S-band의 2.38 GHz 두가지 주파수를 이용하여 곡물의 함수율 측정을 위한 마이크로파 송수신 장치를 설계 및 제작하였다. 측정 장치들의 핵심부품인 발진기, 송수신 패치안테나와 검파기는 HP EEsof ADS를 이용하여 설계하였으며 하이브리드 MIC형태로 제작하였다. 이 송수신 측정장치를 이용하여 측정된 데이터를 통계분석 프로그램으로 회귀 분석하여 밀도에 민감하지 않은 새로운 보정 모델을 제시하였다. 시료의 출력 전압을 독립변수로 한 함수율 측정 모델을 가지고 함수율의 예측값과 실측값을 비교한 결과 상관계수는 0.9276, 표준오차는 0.975 %로 나타나 산물밀도를 보정하면서 정확도가 높은 벼의 함수율 측정이 가능하였다.