• 제목/요약/키워드: Water-$Al_2O_3$

검색결과 561건 처리시간 0.035초

ADN기반 단일액상추진제 분해용 촉매 제조 및 특성 연구 (A Study of Catalysts for Decomposition of ADN-Based Liquid Monopropellant)

  • 전종기;허수정;조영민;김태규
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.412-415
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    • 2017
  • 본 연구에서는 금속을 담지한 alumina bead 촉매를 이용하여 ammonium dinitramide (ADN)기반 단일액상추진제 분해 성능 분석을 수행하였다. Alumina bead를 $1200^{\circ}C$에서 소성한 후, 회전 증발기를 이용하여 과량 용액 함침법 (Excess water impregnation)으로 alumina bead에 Pt 및 Cu 를 담지하였다. 자체 제작한 batch 반응기에서 ADN기반 단일액상추진제 분해 온도($T_{dec}$)를 측정하였다. Cu/$Al_2O_3$ 촉매가 Pt/$Al_2O_3$ 촉매에 비해 분해 온도가 더 낮게 나타났으며, $T_{dec}$ 는 약 $130^{\circ}C$이었다.

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Al2O3 Coating and Filling of Carbon Nanotubes

  • Lee Jong-Soo;Min Byung-Don;Kim Sang-Sig
    • Transactions on Electrical and Electronic Materials
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    • 제4권4호
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    • pp.1-6
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    • 2003
  • Aluminum oxide ($Al_2O_3$) nanotubes and nanorods were fabricated by coating and filling of multiwalled carbon nanotubes (MWNTs) with atomic-layer deposition (ALD). $Al_2O_3$ material was deposited on the MWNTs at a substrate temperature of $300^{\circ}C$ using trimethylaluminum and distilled water. Transmission electron microscopy, high resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, and selected area electron diffraction of the deposited MWNTs revealed that amorphous $Al_2O_3$ material coats the MWNTs conformally and that this material fills the inside of the MWNTs. These illustrate that ALD has an excellent capability to coat and fill any three-dimensional shapes of MWNTs conformally without producing any crystallites.

Gas Barrier Properties of Nanolaminated Single Inorganic Film Deposited by Neutral Beam Assisted Sputtering Process

  • Jang, Yun-Sung;Lee, You-Jong;Hong, Mun-Pyo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.465-465
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    • 2012
  • In this study, we developed an Al2O3 nanolaminated single gas barrier layer using a Neutral Beam Assisted Sputtering (NBAS) process. The NBAS process can continuously change crystalline structures from an amorphous phase to a nanocrystal phase with various grain sizes and lead to the formation of a nanolaminated structure in the single inorganic thin film. As a result, the water vapor transmission rates (WVTR) of the nanolaminated Al2O3 thin films by NBAS process have improved more than 40% compared with that of conventional Al2O3 layers by the RF magnetron sputtering process under the same sputtering conditions.

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OLED Barrier와 Encapsulation을 위한 원자층 증착 Polymer / Al2O3 다층 필름의 온습도 신뢰도 평가 분석 (Reliability Evaluation of Atomic layer Deposited Polymer / Al2O3 Multilayer Film for Encapsulation and Barrier of OLEDs in High Humidity and Temperature Environments)

  • 이사야;송윤석;김현;류상욱
    • 반도체디스플레이기술학회지
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    • 제16권4호
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    • pp.1-4
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    • 2017
  • Encapsulation of organic based devices is essential issue due to easy deterioration of organic material by water vapor. Atomic layer deposition (ALD) is a promising solution because of its low temperature deposition and quality of the deposited film. Moisture permeation has a mechanism to pass through defects, Thin Film Encapsulation using inorganic / organic / inorganic hybrid film has been used as promising technology. $Al_2O_3$ / Polymer / $Al_2O_3$ multilayer film has shown excellent environmental protection characteristics despite of thin thicknesses of the films.

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Organotemplate-free synthesis of ZSM-5 membrane for pervaporation dehydration of isopropanol

  • Li, Jiajia;Li, Liangqing;Yang, Jianhua;Lu, Jinming;Wang, Jinqu
    • Membrane and Water Treatment
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    • 제10권5호
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    • pp.353-360
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    • 2019
  • ZSM-5 membrane was prepared on tubular macroporous ${\alpha}$-alumina support using a different synthesis route. The effects of organic template agent and Si/Al ratio of the synthesis gel on morphology, structure, and separation performance of the ZSM-5 membrane used for dehydration of isopropanol were investigated. High water perm-selectivity ZSM-5 membrane with a thickness of about $3.0{\mu}m$ and a low Si/Al ratio of 10.1 was successfully prepared from organotemplate-free synthesis gel with a molar composition of $SiO_2$ : $0.050Al_2O_3$ : $0.21Na_2O$ : NaF : $51.6H_2O$ at $175^{\circ}C$ for 24 h. The ZSM-5 membrane exhibited high pervaporation performance with a flux of $3.92kg/(m^2{\cdot}h)$ and corresponding separation factor of higher than 10,000 for dehydration of 90 wt.% isopropanol/water mixture at $75^{\circ}C$.

Protective Layer on Active Layer of Al-Zn-Sn-O Thin Film Transistors for Transparent AMOLED

  • Cho, Doo-Hee;KoPark, Sang-Hee;Yang, Shin-Hyuk;Byun, Chun-Won;Cho, Kyoung-Ik;Ryu, Min-Ki;Chung, Sung-Mook;Cheong, Woo-Seok;Yoon, Sung-Min;Hwang, Chi-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.318-321
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    • 2009
  • We have studied transparent top gate Al-Zn-Sn-O (AZTO) TFTs with an $Al_2O_3$ protective layer (PL) on an active layer. We also fabricated a transparent 2.5 inch QCIF+AMOLED display panel using the AZTO TFT back-plane. The AZTO active layers were deposited by RF magnetron sputtering at room temperature and the PL was deposited by ALD with two different processes. The mobility and subthreshold slope were superior in the cases of the vacuum annealing and the oxygen plasma PL compared to the $O_2$ annealing and the water vapor PL, however, the bias stability was excellent for the TFTs of the $O_2$ annealing and the water vapor PL.

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Al2O3 High Dense Single Layer Gas Barrier by Neutral Beam Assisted Sputtering (NBAS) Process

  • 장윤성;홍문표
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.157-157
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    • 2015
  • Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low water vapor transition rate (WVTR) of $1{\times}10^{-6}g/m^2day$. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2day$) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study NBAS process was introduced to deposit enhanced film density single gas barrier layer with a low WVTR. Fig. 1. shows a schematic illustration of the NBAS apparatus. The NBAS process was used for the $Al_2O_3$ nano-crystal structure films deposition, as shown in Fig. 1. The NBAS system is based on the conventional RF magnetron sputtering and it has the electron cyclotron resonance (ECR) plasma source and metal reflector. $Ar^+$ ion in the ECR plasma can be accelerated into the plasma sheath between the plasma and metal reflector, which are then neutralized mainly by Auger neutralization. The neutral beam energy is controlled by the metal reflector bias. The controllable neutral beam energy can continuously change crystalline structures from an amorphous phase to nanocrystal phase of various grain sizes. The $Al_2O_3$ films can be high film density by controllable Auger neutral beam energy. we developed $Al_2O_3$ high dense barrier layer using NBAS process. We can verified that NBAS process effect can lead to formation of high density nano-crystal structure barrier layer. As a result, Fig. 2. shows that the NBAS processed $Al_2O_3$ high dense barrier layer shows excellent WVTR property as a under $2{\times}10^{-5}g/m^2day$ in the single barrier layer of 100nm thickness. Therefore, the NBAS processed $Al_2O_3$ high dense barrier layer is very suitable in the high efficiency OLED application.

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Photocatalytic Degradation of Methyl tert-Butyl Ether (MTBE): A review

  • Seddigi, Zaki S.;Ahmed, Saleh A.;Ansari, Shahid P.;Yarkandi, Naeema H.;Danish, Ekram;Oteef, Mohammed D.Y.;Cohelan, M.;Ahmed, Shakeel;Abulkibash, Abdallah M.
    • Advances in environmental research
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    • 제3권1호
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    • pp.11-28
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    • 2014
  • Advanced oxidation processes using UV and catalysts like $TiO_2$ and ZnO have been recently applied for the photocatalytic degradation of MTBE in water. Attempts have been made to replace the UV radiation by the solar spectrum. This review intends to shed more light on the work that has been done so far in this area of research. The information provided will help in crystallizing the ideas required to shift the trend from UV photocatalysis to sunlight photocatalysis. The careful optimization of the reaction parameters and the type of the dopant employed are greatly responsible for any enhancement in the degradation process. The advantage of shifting from UV photocatalysts to visible light photocatalysts can be observed when catalysts like $TiO_2$ and ZnO are doped with suitable metals. Therefore, it is expected that in the near future, the visible light photocatalysis will be the main technique applied for the remediation of water contaminated with MTBE.

에멀젼을 이용한 Al2O3-ZrO2 복합분체의 제조 : I. 에멀젼 안정화에 대한 열역학적 모델 (Preparation of Al2O3-ZrO2 Composite Powders by the Use of Emulsions: I. Thermodynamic Model of the Emulsion Stability)

  • 한상훈;백종규;송승룡
    • 한국세라믹학회지
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    • 제24권6호
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    • pp.593-601
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    • 1987
  • A thermodynamic model to predict the stability of the water-in-oil type emulsion and the size of the droplets in stable emulsions was developed. Using this model, the effects of various factors government the droplet size in the metal salt solution-kerosene-span 80 system for the preparation of Al2O3-ZrO2 composite powders were investigated. It was shown that the given emulsion systems were thermodynamically unstable in every case but could be kinetically meta stable. When radius ofthe droplet was below nm, the increase in entropy change due to the configurational contribution of small droplets dominated the total free energy change for emulsification. The optimum conditions under which smaller deoplet was obtained were proposed and the validity of the model was proved with diameters of the droplet and composite powders experimentally determined.

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Al2O3 나노입자가 젤(Gel) 추진제의 곡관 유동특성에 미치는 연구 (Flow Characteristics Investigation of Gel Propellant with Al2O3 Nano Particles in a Curved Duct Channel)

  • 오정수;문희장
    • 한국추진공학회지
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    • 제17권3호
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    • pp.47-55
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    • 2013
  • 본 연구에서는 곡관 채널에서의 비뉴튼 젤 추진제의 유동 특성에 대해 연구하였다. 물을 기본유체로 하는 모사젤을 Carbopol 941 젤화 작용제와 NaOH 농축액을 혼합하여 제작하였으며 입자 유무에 따른 유동 특성을 파악하기 위해 $Al_2O_3$ 나노 입자가 첨가된 젤을 제작하여 두 젤 추진제간의 유변학적 특성을 비교하였다. 두 모사젤에 대해 U-자형의 곡관부 위치별 유동특성과 Dean 와류(vortices)의 경향은 상이하였으나 나노 입자가 첨가된 모사젤 추진제의 경우 높은 컨시스턴시 지수에도 불구하고 두 모사젤 모두 비슷한 범위의 임계 Dean 수를 도출하였다. 나노 입자 첨가 유무와 무관하게 power-law 지수값이 임계 Dean 수를 결정하는데 주요 변수임을 판단할 수 있었으나 나노입자가 첨가된 젤의 경우 Dean 와류 강도의 변동폭이 상대적으로 크다는 결론을 내릴 수 있었다.