• Title/Summary/Keyword: Water residence time

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Study on The Thermochemical Degradation Features of Empty Fruit Bunch on The Function of Pyrolysis Temperature (반응온도에 따른 팜 부산물(empty fruit bunch)의 열화학적 분해 특성에 관한 연구)

  • Lee, Jae Hoon;Moon, Jae Gwan;Choi, In-Gyu;Choi, Joon Weon
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.350-359
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    • 2016
  • We performed fast pyrolysis of empty fruit bunch (EFB) in the range of temperature from $400{\sim}550^{\circ}C$ and 1.3 s of residence time. The effect of temperature on the yields and physicochemical properties of pyrolytic products were also studied. Elemental and component analysis of EFB showed that the large amount of potassium (ca. 8400 ppm) presents in the feedstock. Thermogravimetric analysis suggested that the potassium in the feedstock catalyzed degradation of cellulose. The yield of bio-oil increased with increasing temperature in the range of temperature from $400{\sim}500^{\circ}C$, while that of gas and biochar decreased and showed monotonous change each with increasing temperature. When the EFB was pyrolyzed at $550^{\circ}C$, the yield of bio-oil and char decreased while that of gas increased. Water content of the bio-oils obtained at different temperatures was 20~30% and their total acid number were less than 100 mg KOH/g oil. Viscosity of the bio-oils was 11 cSt (centistoke), and heating value varied from 15 to 17 MJ/kg. Using GC/MS analysis, 27 chemical compounds which were classified into two groups (cellulose-derived and lignin-derived) were identified. Remarkably the concentration of phenol was approximately 25% based on entire chemical compounds.

Removal of Ammonia-N by using the Immobilized Nitrifier Consortium in Aquaculture System (양어장에서 고정화된 질화세균군을 이용한 암모니아 질소 제거)

  • SUH Kuen-Hack;KIM Yong-Ha;AHN Kab-Hwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.868-873
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    • 1997
  • Nitrifier consortium entrapped in Ca and Ba-alginate beads were packed into two reactors and studied for removing ammonia-nitrogen in aquaculture system. The ammonia-nitrogen concentration of the influent was continually kept about 2 ppm. At the hydraulic residence time of 0.6 hours, ammonia-nitrogen removal amount of two reactors was about 52.6 and 51.0 g $NH_3-N/m^3/day$, respectively. The ability of adjusting to an impulsive leading which was happened according to variations of HRT was better at Ba-alginate reactor, but its discrepancy was not so large. At the respect of removing ammonium-nitrogen, two reactors showed the similar ability of treating recirculating water.

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Study on the Desulfurization Characteristic of Limestone Depending on the Operating Parameters of In-Furnace Desulfurization for Oxy-Fuel Combustion Using Drop Tube Furnace (순산소연소 조건에서 Drop tube furnace를 이용한 운전변수에 따른 석회석의 탈황특성 연구)

  • Choi, Wook;Jo, Hang-Dae;Choi, Won-Kil;Park, Yeong-Sung;Keel, Sang-In;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.857-864
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    • 2011
  • Oxy-fuel combustion with many advantages such as high combustion efficiency, low flue gas flow rate and low NOx emission has emerged as a promising CCS technology for coal combustion facilities. In this study, the effects of the direct sulfation reaction on $SO_2$ removal efficiency were evaluated in a drop tube furnace under typical oxy-fuel combustion conditions represented by high concentrations of $CO_2$ and $SO_2$ formed by gas recirculation to control furnace combustion temperature. The effects of the operating parameters including the reaction temperature, $CO_2$ concentration, $SO_2$ concentration, Ca/S ratio and humidity on $SO_2$ removal efficiency were investigated experimentally. $SO_2$ removal efficiency increased with reaction temperature up to 1,200 due to promoted calcination of limestone reagent particles. And $SO_2$ removal efficiency increased with $SO_2$ concentrations and the humidity of the bulk gas. The increase of $SO_2$ removal efficiency with $CO_2$ concentrations showed that $SO_2$ removal by limestone was mainly done by the direct sulfation reaction under oxy-fuel combustion conditions. From the impact assessment of operation parameters, it was shown that these parameters have an effects on the desulfurization reaction by the order of the Ca/S ratio > residence time > $O_2$ concentration > reaction temperature > $SO_2$ concentration > $CO_2$ concentration > water vapor. The semi-empirical model equation for to evaluate the effect of the operating parameters on the performance of in-furnace desulfurization for oxy-fuel combustion was established.

A Comparative Considerations of the Moat at the East and West (동.서양 해자(垓字)의 비교 고찰)

  • Jung, Yong-Jo;Park, Joo-Sung;Sim, Woo-Kyung
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.28 no.3
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    • pp.29-38
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    • 2010
  • A moat is a pond or waterway paved on the outside of a fortress that is one of the facilities to prevent enemy from approaching the fortress wall or classify it as the boundary space, and this study was undertaken to find out the characteristics of the moat that was existed in the East and the West from ancient time to medieval time with the following result. First, the moat in the East was installed of natural moat and artificial moat at the same time while the moat in the West had the fortress built in naturally advantageous site to use natural most substantially more. Second, the moats of Korea were smaller in scale compared to other countries (Japan, China and the Western countries). Third, the fortresses in the East were built to protect towns or royal palace while the West had the fortress to protect the residence of kings, lords, great wealthy persons and the like, and they were used jointly with the natural moat and artificial moat to defend against the infiltration of enemy. Fourth, the Pungsujiri in the Orient is one of the numerous ideologies forming the supplementary ideologic system of Korean people that could not be denied as the perception that influences on Korean people after the Silla Dynasty, and this Pungsujiri was considered when determining the location of the castle. The moat surrounding the castle had the role to keep the good energy in the castle from escaping away. Fifth, the Ha-Ha technique in the west was designed to prevent the external power from infiltration by digging the ditch on the place applicable to the boundary of the garden site, rather than the fence. While walking around along the water-side path without knowing the existence of this ditch, when the road is discovered with the cut off in the ditch, people had the exclamation without actually recognizing such astonishment. It was originally the dike for military purpose during the medieval time that was designed to look into the garden without physical boundary surrounded with the vertical fence in the garden that by having the deep ditch like shape on the boundary line of the garden which was designed to form the farm by preventing various types of cattle from coming inside the garden and bring in the garden element for farms, forestry, agricultural land and the like.

Analysis of Landscape Structure Change for Riparian Buffer Zone KyangAn Watershed (경안천 유역 수변구역 경관구조 변화 분석)

  • Kim, Kyung-Tak;Kim, Joo-Hun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.8 no.3
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    • pp.74-83
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    • 2005
  • The Riparian Buffer Zone has many potential values including the preservation of water quality as well as being ecologically friendly. This study aims to quantitatively analyze the landscape structure index of the Riparian Buffer Zone in the Kyoung-an stream and to produce base information necessary for proper management. The study used aerial images that were applied to geometric corrections for a time series from 1966 to 2000 for land data and also used FRAGSTATS, which is a type of ARCVIEW extension module, as an analysis tool. An analysis of land use change and the Landscape Index revealed that the area of farm land has decreased and that the area of residential property has increased. In addition, there was a slight change for land used for purposes other than farming or for residence. The results of analyzing the Landscape Structure Index, revealed that the NP has increased from 437 in 1966 to 695 in 2000. This data reveals that the change of land use is influenced by various artificial factors. The NPS, which represents the declining degree of patch, decreased from 9.441 to 5.934, revealing that the change of land use has been progressing considerably. In regard to forest areas, land use reduced somewhat but did not indicate a significant change. Therefore, an analysis of the total index reveals that the edge of patch has become more complicated and that the variation index of patch has increased significantly. However, this study reveals that barriers to block pollution have weakened as a result and that there is a need to concentrate on the implementation and the management of the Riparian Buffer Zone. Consequently, this study reveals that substantial research is necessary in order to carry out the proper management of the Riparian Buffer Zone, especially in light of the distribution type of each patch and the change in conditions regarding them.

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Geochemical Characterization of Rock-Water Interaction in Groundwater at the KURT Site (물 암석 반응을 고려한 KURT 지하수의 지구화학적 특성)

  • Ryu, Ji-Hun;Kwon, Jang-Soon;Kim, Geon-Young;Koh, Yong-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.189-197
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    • 2012
  • Geochemical composition of fracture filling minerals and groundwater was investigated to characterize geochemical characteristics of groundwater system at the KURT site. Minerals such as calcite, illite, laumontite, chlorite, epidote, montmorillonite, and kaolinite, as well as I/S mixed layer minerals were detected in the minerals extracted from the fracture surfaces of the core samples. The groundwater from the DB-1, YS-1 and YS-4 boreholes showed alkaline conditions with pH of higher than 8. The electrical conductivity (EC) values of the groundwater samples were around $200{\mu}S/cm$, except for the YS-1 borehole. Dissolved oxygen was almost zero in the DB-1 borehole indicating highly reduced conditions. The Cl- concentration was estimated around 5 mg/L and showed homogeneous distribution along depths at the KURT site. It might indicate the mixing between shallow groundwater and deep groundwater. The shallow groundwater from boreholes showed $Ca-HCO_3$ type, whereas deep groundwater below 300 m from the surface indicated $Na-HCO_3$ type. The isotopic values observed in the groundwater ranged from -10.4 to -8.2‰ for ${\delta}^{18}O$ and from -71.3 to -55.0‰for ${\delta}D$. In addition, the isotope-depleted water contained higher fluoride concentration. The oxygen and hydrogen isotopic values of deep groundwater were more depleted compared to the shallow groundwater. The results from age dating analysis using $^{14}C$ indicated relatively younger (2000~6000yr old) groundwater compared to other european granitic groundwaters such as Stripa (Sweden).

Pharmacokinetics of cefadroxil after oral administration in olive flounder, Paralichthys olivaceus (Cefadroxil의 경구투여에 따른 넙치(Paralichthys olivaceus)에서의 약물동태학 연구)

  • Lee, Ji-Hoon;Park, Kwan Ha
    • Journal of fish pathology
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    • v.31 no.1
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    • pp.23-34
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    • 2018
  • The pharmacokinetic properties of cefadroxil (CDX) were studied after oral administration for 7 days to cultured olive flounders (average 660 g), Paralichthys olivaceus. For examination of pharmaco-kinetic profiles, CDX of 45 to 225 mg/kg body weight was administered at two different water temperatures, $13{\pm}3^{\circ}C$ or $22{\pm}3^{\circ}C$. CDX concentrations were determined in muscle, plasma, gastrointestinal tract, hematopoietic organs and liver by HPLC-MS/MS. Muscle samples were taken at 0.25, 0.5, 1, 3, 7, 14 and 28 days post dose, whereas plasma, gastrointestinal tract, hematopoietic organs and liver concentrations were measured at 1, 3, 7, 14 and 28 days post-dosing. The kinetic profiles of $C_{max}$, $T_{max}$, $T_{1/2}$ of CDX were analyzed by fitting to a non-compartmental model with PKSolver program. The following pharmacokinetic parameters were obtained with oral administration of 45 and 225 mg/kg at 13 and $22^{\circ}C$ in muscle, plasma, gastrointestinal tract, hematopoietic organs and liver, respectively: $C_{max}$ (maximum tissue concentration)=$985.98-5,032.86{\mu}g/kg$, $5,670.99-38,922.23{\mu}g/l$, $2,457.27-10,192.78{\mu}g/kg$, $886.04-3,070.87{\mu}g/kg$ and $1,188.15-3,814.33{\mu}g/kg$; $T_{max}$ (time for maximum concentration)= every 1 day; $MRT_{0-{\infty}}$ (mean residence time)= 1.51-4.74, 2.12-3.06, 4.25-13.18, 1.37-18.66 and 1.78-29.76 days; $T_{1/2}$ (half-life)= 1.08-3.47, 1.14-5.42, 3.56-10.99, 1.17-14.93 and 1.25-28.55 days.

Yeoheon's Recognition of Geography and the Significance of the Compilation of Geographical Records by His Disciples (여헌(旅軒) 장현광(張顯光)의 지리인식(地理認識)과 문인(門人)들의 지지편찬(地誌編纂) 의의)

  • Choi, Wonsuk
    • (The)Study of the Eastern Classic
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    • no.49
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    • pp.73-107
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    • 2012
  • Yeoheon Jang Hyeongwang(1554-1637), one of the greatest Mid-Joseon Confucianists did systematic studies on universe and nature. It can be considered that he inherited the academic tradition of Cho Sik (曺植) and Jeong Gu(鄭逑) and followed their steps of fengshui (風水) and compilation of geographical records. His living and thought and deserve researching with regard to geographical studies. This paper attempts to analyze Yeoheon's recognition of geography in general. In other words, I shall prove that his view of geography is Neo-Confucian. At the same time, I shall discuss how he named people's residence, how he understanded the Joseon territory, what he thought about fengshui, and what significance the complication of geographical records by his disciples had. Yeoheon considered that land is composed of water, fire, earth, and rock, and understanded the land according to the theory of Zhouyi (周易). He analyzed geographic environments by the system of Zhouyi. His study of geography is basically intended for practical use, and as a result is necessary for people to choose where to live and where to cultivate. In his opinion, it is essential to divide the land of the Joseon by means of geographical differences in order to help people to find a better place to live. We can see his Confucian view from the fact that he placed a greater emphasis on human beings over nature. Therefore, the practical use for humans is the first priority in his study of geography. Meanwhile, he considered nature itself as only the object of study. He realized the vitality of life by making a close observation of nature and attained the mind of the Heaven and Earth in a detached way. He, as a follower of Neo-Confucianism, enjoyed the land by feeling comfortable with his present status and by being satisfied with himself. He put his Confucian view of universe and world into practice in his life. As a part of his efforts, he named his residence and surrounding natural environments with the polar star and 28 stars, and accordingly they are reconstructed in a system of universe. The Confucian tradition of dongcheon gugok (洞天九曲) starting with Zhu Xi's administration of wuyi jiugu (武夷九曲) was widely prevalent during the Joseon period, but Yeoheon's system of organizing places is original. His sense of naming places reflects his ideas of following his predecessors, comparing natural objects to human emotions, and desiring to live in retirement. Yeoheon understanded the Joseon territory with comparison of the Chinese land. He expressed his knowledge in the form of changing geographical features of a district, appreciating natural beauty, locating towns, and being familiar with a region, and proposing his own climatology and view of the reality. His recognition of the Joseon territory resolves itself into the following several points. He regarded the Joseon territory as one organism, and considered the territory to be composed of ki (氣) as Neo-Confucianists usually do. In addition, he understanded not only natural environments but also towns from a perspective of the fengshui and adopted a comparative methodology in dividing regions. He also applied climatology to analyze persons and customs. He employed the methodology of fengshui from the comprehensive theory of the Yijing. It is because he was influenced by Cho Sik and Jeng Gu. Yeoheon chose dwelling places for people, or gave advice on several places of his hometown relying on his knowledge of fengshui. When it comes to his theory of fengshui, he agreed with the theory of topography with regards to the fengshui of tombs, but criticized the custom of delaying funerals in order to turn fortune in one's favor. In addition, he accepted that it is necessary to complement a town by creating forests around it. We need to pay attention to the fact that Yeoheon's disciples complied several geographical records. It proves that they inherited the tradition of "valuing practical use and governing on behalf of the people" from Cho Sik and Jeong Gu. Yeoheon put a great emphasis on geographical records and encouraged his disciples to compile them. In other words, he emphasized that they, as administrator or intellectual, need to be erudite in the history and custom of a region where they have lived, and have to establish a standard to encourage or warn people in the region while considering the geographical records. His opinion functioned as a guideline for his successors to compile geographical records later. This paper only analyzed several facts with regard to Yeoheon's knowledge of geography and an academic tradition concerning the study of geography. In the future, I shall discuss how his predecessors and successors understanded geography and how the tradition of compiling geographical records was transferred and developed between them. I believe that this study will contribute to establishing the history of geography, which the Joseon Confucianists researched for a long time but we have not paid an enough attention to until now.

Comparison of Seawater Exchange Rate of Small Scale Inner Bays within Jinhae Bay (수치모델을 이용한 진해만 내 소규모 내만의 해수교환율 비교)

  • Kim, Nam Su;Kang, Hoon;Kwon, Min-Sun;Jang, Hyo-Sang;Kim, Jong Gu
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.1
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    • pp.74-85
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    • 2016
  • For the assessment of seawater exchange rates in Danghangpo bay, Dangdong bay, Wonmun bay, Gohyunsung bay, and Masan bay, which are small-scale inner bays of Jinhae bay, an EFDC model was used to reproduce the seawater flow of the entire Jinhae bay, and Lagrange (particle tracking) and Euler (dye diffusion) model techniques were used to calculate the seawater exchange rates for each of the bays. The seawater exchange rate obtained using the particle tracking method was the highest, at 60.84%, in Danghangpo bay, and the lowest, at 30.50%, in Masan bay. The seawater exchange rate calculated based on the dye diffusion method was the highest, at 45.40%, in Danghangpo bay, and the lowest, at 34.65%, in Masan bay. The sweater exchange rate was found to be the highest in Danghangpo bay likely because of a high flow velocity owing to the narrow entrance of the bay; and in the case of particle tracking method, the morphological characteristics of the particles affected the results, since once the particles get out, it is difficult for them to get back in. Meanwhile, in the case of the Lagrange method, when the particles flow back in by the flood current after escaping the ebb current, they flow back in intact. However, when a dye flows back in after escaping the bay, it becomes diluted by the open sea water. Thus, the seawater exchange rate calculated based on the dye diffusion method turned out to be higher in general, and even if a comparison of the sweater exchange rates calculated through two methods was conducted under the same condition, the results were completely different. Thus, when assessing the seawater exchange rate, more reasonable results could be obtained by either combining the two methods or selecting a modeling technique after giving sufficiently consideration to the purpose of the study and the characteristics of the coastal area. Meanwhile, through a comparison of the degree of closure and seawater exchange rates calculated through Lagrange and Euler methods, it was found that the seawater exchange rate was higher for a higher degree of closure, regardless of the numerical model technique. Thus, it was deemed that the degree of closure would be inappropriate to be used as an index for the closeness of the bay, and some modifications as well as supplementary information would be necessary in this regard.