• Proceedings of the PSK Conference
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• 2003.10b
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• pp.224.1-224.1
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• 2003

A sensitive and selective liquid chromatographic method coupled with tandem mass spectrometry (LC-MS/MS) was developed for the determination of beraprost in human plasma. Plasma samples were transferred into 96-well OASIS HLB extraction plate using an automated sample handling system and the drugs were eluted with methanol. The eluents were then evaporated and reconstituted with water. All sample transfer and solid-phase extraction (SPE) was automated through the application of both the PerkinElmer MultiPROBE II HT and TOMTEC Quadra 96 workstation. (omitted)

• Proceedings of the Korea Society of Environmental Toocicology Conference
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• 2000.12a
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• pp.43-43
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• 2000

• Journal of the Korean Society of Marine Environment & Safety
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• v.1 no.1
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• pp.27-38
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• 1995

In this paper, a program for the calculation of GZ curve for a ship in waves is developed and GZ curves for a ferry in the still water and in waves are calculated. And the added mass, damping, restoring forces and wave exciting forces are calculated by using the strip theory given by Salvesen, Tuck, Faltinsen. Capsizing simulations are perfoned in consideration if the nonlinear restoring forces of the ship in waves by using the Runge-Kutta 4-th method.

• Journal of Applied Biological Chemistry
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• v.43 no.1
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• pp.44-48
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• 2000

Burkholderia cepacia strain G4 (pHG-2) containing toluene 2-monooxygenase and toluene dioxygenase, was able to grow on toluene and accumulate cis-3-methyl-3,5-cyclohexadien-1,2-diol (cis-toluene dihydrodiol) in the liquid culture. The cis-toluene dihydrodiol produced was identical to the authentic compound, as judged through mass spectrometry and nuclear magnetic resonance analysis. Our results indicate that pHG-2 provides an economical means to produce chemically-important chiral synthons while growing on toluene.

• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.883-888
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• 2001

We describe an ion-surface scattering apparatus newly developed to investigate the reactive scattering process of low-energy alkali-metal ions at surfaces. The apparatus consists of an alkali-metal ion gun that is rotatable by 360°, a quadrupole mass spectrometer (QMS) with an ion energy analyzer, a sample manipulator with a heating-and-cooling stage, and an ultrahigh vacuum (UHV) chamber that houses these components. Preliminary experimental results obtained from the apparatus are presented on angular and energy distributions of the ions scattered from clean Pt(111) and water-adsorbed Pt surfaces.

• Journal of Korean Society on Water Environment
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• v.32 no.5
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• pp.410-418
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• 2016

This study was conducted to improve the analysis method used for N-nitrosamines and to investigate the occurrences of N-nitrosamines in tributaries of the Han-river, intake stations, water treatment plants and tap water used within the city of Seoul. The samples were pretreated through a solid phase extraction and analyzed using a gas chromatography tandem mass spectrometer (GC-MS/MS). The GC-MS/MS in CI mode was compared with the GC-MS/MS in EI mode by the method detection limits (MDLs). MDLs by GC-CI/MS/MS and GC-EI/MS/MS were 0.2 ~ 1.1 ng/L and 0.2 ~ 1.4 ng/L, respectively. Samples were collected from ten tributaries of the Han-river (T1 ~ T10), six intake stations (I1 ~ I6), six water treatment plants (P1 ~ P6) and 25 taps in Seoul city. The maximum levels of N-nitrosodimethylamine (NDMA) were 0.013 μg/L, 0.008 μg/L, 0.006 μg/L and 0.002 μg/L in tributary water, raw water, finished water and tap water samples, respectively. Detected levels were much lower than 0.1 μg/L corresponding to the guideline value of WHO.

• Tunnel and Underground Space
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• v.6 no.1
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• pp.30-38
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• 1996

A two dimensional analysis program for groundwater flow in fractured network was developed to analyze the influence of discontinuity characteristics on groundwater flow. This program involves the generation of discontinuities and also connectivity analysis. The discontinuities were generated by the probabilistic density function(P.D.F.) reflecting the characteristics of discontinuities. And the fracture network model was completed through the connectivity analysis. This program also involves the analysis of groundwater flow through the discontinuity network. The result of numerical experiment shows that the equivalent hydraulic conductivity increased and became closer to isotropic as the density and trace length increased. And hydraulic head decreased along the fracture zone because of much water-flow. The grouting increased the groundwater head around cavern. An analysis of groundwater flow through discontinuity network was performed around underground oil storage cavern which is now under construction. The probabilistic density functions(P.D.F) were obtained from the investigation of the discontinuity trace map. When the anisotropic hydraulic conductivity is used, the flow rate into the cavern was below the acceptable value to maintain the hydraulic containment. But when the isotropic hydraulic conductivity is used, the flow rate was above the acceptable value.

• Computational Structural Engineering
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• v.3 no.3
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• pp.141-146
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• 1990

This study is on a seismic analysis of absorber rod in KMRR Reactivity Control Mechanism. The model being studied is two coaxial tubes(control absorber rod and flow tube) immersed in the water and partially coupled(overlap) by water gap. The hydrodynamic mass effects by the water in each surrounding conditions are considered in the model. The natural frequencies, stresses and displacements of the system due to Safe Shutdown Earthquake are computed in the cases of in-phase modes and out-of-phase modes of two coaxial tubes. The results show that maximum stresses are well below the allowable limit but the maximum displacements at the ends of both tubes are so much that the absorber rod contacts with the flow tube(or surrounding wall).

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.11b
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• pp.416-421
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• 2002

This paper dealt with an experimental study on the hydro-elastic vibration of clamped perforated rectangular plates submerged in water. The penetration of holes in the plates had a triangular pattern with P/D (pitch to diameter) 1.750, 2.125, 2.500, 3.000 and 3.750. The natural frequencies of the perforated plates in air were obtained by the analytical method based n the relation between the reference kinetic and maximum potential energy and compared with the experimental results. Good agreement between the results was found for the natural frequencies of the perforated plates in air. It was empirically found that the natural frequencies of the perforated plate in air increase with an increase of P/D, on the other hand, the natural frequencies of the perforated plate in contact with water decrease with an increase of P/D. Additionally, the effect of the submerged depth on the natural frequency was investigated.

• Corrosion Science and Technology
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• v.11 no.4
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• pp.141-150
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• 2012

Stress corrosion cracks in Alloy 600 compact tension specimens tested at $325^{\circ}C$ in a simulated primary water environment of pressurized water reactor were analyzed by analytical transmission electron microscopy and secondary ion mass spectroscopy (SIMS). From a fine-probe chemical analysis, oxygen was found on the grain boundary just ahead of the crack tip, and chromium oxides were precipitated on the crack tip and the grain boundary attacked by the oxygen diffusion, leaving a Cr/Fe depletion (or Ni enrichment) zone. The oxide layer inside the crack was revealed to consist of a double (inner and outer) layer. Chromium oxides existed in the inner layer, with NiO and (Ni,Cr) spinels in the outer layer. From the nano-SIMS analysis, oxygen was detected at the locations of intergranular chromium carbides ahead of the crack tip, which means that oxygen diffused into the grain boundary and oxidized the surfaces of the chromium carbides. The intergranular chromium carbide blunted the crack tip, thereby suppressing the crack propagation.