• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.511-514
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• 2007

This study was performed to construct a geothermal data base about thermal conductivity of ground heat exchanger and thermal properties of grouting material which used to refill the borehole. We have acquired geothermal data sets from 39 sites over wide area of South Korea except to Jeju island. From data analysis, the range of thermal conductivity is $1.5{\sim}4.0$ W/mK. It means that thermal conductivity varies with grouting material as well as regional geology and ground water system.

• Journal of the Korean Ceramic Society
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• v.24 no.2
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• pp.101-110
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• 1987

The relative electrical conductivity of vacuum deposited Al films on a soda-lime(2947) and an alumino boro silicate(7809) glass was investigated with the variation of the relative humidity,temperature and film thickness. The structure and microstructure of Al films before and after exposure to the humidity wereexamined by the X-ray Diffractormenter(XRD) and Scanning Electron Microscope(SEM). As the relative humidity increased, the electrical conductivity of Al films on both glasses was decreased. However, the Al films on 7809 glass showed higher conductivity than that of 2947 glass under the same testing conditions. The decreasing of electrical conductivity was caused by the formation of Aluminum hydroxide which was made by the reaction between the aluminum films and water vapor.

• Proceedings of the SAREK Conference
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• 2007.11a
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• pp.423-428
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• 2007

This study was performed to construct a geothermal data base about thermal conductivity of ground heat exchanger and thermal properties of grouting material which used to refill the borehole. We have acquired geothermal data sets from 39 sites over wide area of South Korea except to Jeju island. From data analysis, the range of thermal conductivity is 1.5$\sim$4.0 W/mK. It means that thermal conductivity varies with grouting material as well as regional geology and ground water system.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.6
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• pp.2369-2379
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• 2013

The Soil-Water Characteristics Curve (SWCC) is affected by the initial density of soil under unsaturated condition. Also, the characteristic of hydraulic conductivity is changed by the initial density of soil. To study the effect of initial density of unsaturated soil, SWCC and the Hydraulic Conductivity Function (HCF) of Jumoonjin sand with various relative densities, 40%, 60% and 75% were measured in both drying and wetting processes. As the results of SWCC estimated by van Genuchten (1980) model, the parameter related to Air Entry Value(AEV), ${\alpha}$ in the wetting process is larger than that in drying process, but the parameters related to the SWCC slope, n and the residual water content, m are larger than those in wetting process. The AEV is increased or Water Entry Value (WEV) is decreased with increasing the relative density of sand. The AEV is larger than the WEV at the same relative density of sand. As the results of HCF estimated by van Genuchten (1980) model which is one of the parameter estimation methods, the unsaturated hydraulic conductivity maintained at a saturated one in the low level of matric suctions and then suddenly decreased just before the AEV or the WEV. The saturated hydraulic conductivity in drying process is larger than that in wetting process. The saturated hydraulic conductivity is decreased with increasing the relative density of sand in both drying and wetting processes. Also, the hysteresis in unsaturated HCFs between drying and wetting process was occurred like the hysteresis in SWCCs. According to the test results, the AEV on SWCC is decreased and the saturated hydraulic conductivity is increased with increasing the initial density. It means that SWCC and HCF are affected by the initial density in the unsaturated soil.

• Journal of Hydrogen and New Energy
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• v.16 no.2
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• pp.103-110
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• 2005

Proton conducting solid polymer electrolyte (SPE) membranes have been used in many energy technological applications such as water electolysis, fuel cells, redox-flow battery, and other electrochemical devices. The availability of stable membranes with good electrochemical characteristics as proton conductivity at high temperatures above 80 $^{\circ}C$ and low cost are very important for its applications. However, the presently available perfluorinated ionomers are not applicable because of high manufacturing cost and high temperature use to the decrease in the proton conductivity and mechanical strength. In order to make up for the weak points, the block copolymer (BPSf) of polysulfone and poly (phenylene sulfide sulfone) were synthesized and sulfonated. The electrolyte membranes were prepared with phosphotungstic acid (HPA)/sulfonated BPSf via solution blending. This study would be desirable to investigate the interaction between the HPA and sulfonated polysulfone. The results showed that the characteristics of SPSf/HPA blend membrane was a better than Nafion at high temperature, 100 $^{\circ}C$. These membranes proved to have a high proton conductivity, $6.29{\times}10-2$ S/cm, a water content, 23.9%, and a ion exchange capacity, 1.97 meq./g dry membrane. Moreover, some of the membranes kept their high thermal and mechanical stability.

• Membrane Journal
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• v.21 no.3
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• pp.270-276
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• 2011

A nascent membrane was prepared by using the solution evaporation method with a solution of sPEEK, EdAn (cross-linking reagent), and PEA (grafting reagent) in DMAc. Then, after the imination and sulfonation process the cross-linked and grafted ion-exchange membrane, CG-sPEEK, was obtained. The sulfonation and imination reactions were confirmed by FTIR analysis. In order to evaluate the possibility of prepared membrane for the use of an ion-exchange membrane in PEMFC, proton conductivity, water uptake and volume change were measured and compared with a commercial membrane, Nafion 115. It was revealed that since the proton conductivity (0.17 S/cm) of prepared membrane were much higher than those of Nafion 115 (0.10 S/cm) the prepared membrane could be used for the ion-exchange membrane in PEMFC. However, the high water uptake (130%) of CG-sPEEK should be reduced for the dimension stability.

• Journal of the Korea Concrete Institute
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• v.13 no.4
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• pp.305-313
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• 2001

Conductivity is an important thermal property which governs heat transfer in a solid medium. Generally, the determination of conductivity in concrete is very difficult, because concrete is a heterogeneous material composed of cement, water, aggregate, et cetera and time dependent material of which properties change with curing age. In this study, influencing factors on thermal conductivity of concrete are quantitatively investigated by QTM-D3, a conductivity tester developed in Japan. Then, a prediction equation of thermal conductivity of concrete is suggested from the regression analysis of test results. To consider the factors influencing thermal conductivity of concrete, mortar, and cement paste, seven testing variables (age, amount of cement, types of admixtures, amount of coarse aggregate, fine aggregate ratio, temperature, and humidity condition) of the specimens are used. According to the experimental results, the amount of coarse aggregate and humidity condition of specimen are the main factors affecting the conductivity of concrete. Meanwhile, the conductivity of mortar and cement paste is strongly affected by the amount of cement and types of admixtures. However, the curing age has minor effect on the conductivity variation. Finally, the prediction formula of concrete conductivity as a function of aggregate amount, fine aggregate ratio, specimen temperature, and humidity condition is developed.

• Journal of Hydrogen and New Energy
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• v.28 no.2
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• pp.144-149
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• 2017

A proton-conducting bisphenylpropaned sulfonated fluorinated blockcopolymer (BPSFBC) was synthesized. Five kinds of polymer electrolyted composite membranes were preparated by incorporating silica ($SiO_2$) with various weight ratio. And their characteristics were investigated by FT-IR (fourier transform infrared), $^1H-NMR$ ($^1H$ nuclear magnetic resonance), TGA (thermogravimetric analysis), water uptake, FE-SEM (field emission scanning electron microscopes), and ion conductivity properties. The water uptake and ion conductivity were increased until 9 wt% $SiO_2$, and then decreased. The maximum proton conductivity equal to $52mScm^{-1}$ was measured for the BPSFBC/$SiO_2$-9 composite membrane at $90^{\circ}C$ and 100% relative humidity. From the measured results, it is distinct that the manufactured composite membrane BPSFBC/$SiO_2$-9 can be considered as a polymer membrane suitable for a fuel cell electrolyte.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.195.2-195.2
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• 2011

The borehole heat exchanger of Geothermal Heat Pump (GHP) system should be sustainable and cost effective for long term operation. To guaranty the performance of the system thermal Response Tests (TRTs) with simple recommended procedures have been applied in many countries. Korea government developed a standard TRT procedure in order to control the quality on GHP projects. In the TRT procedure interpretation method has a rule that data set has to be interpreted by the line source model(LSM). The LSM employes some assumptions that surrounding medium is homogeneous and the line source is infinite and constant heat flux, however real ground condition is unisotropic and heterogeneous, and showing regional or local ground water flows in many cases. We need to develope improved evaluation models to estimate accurate ground thermal conductivity with respect to geological and influence of ground water because current TRT standard test procedure has limitations to be applied for every locations and system. This study surveyed the uncertainty of the thermal parameters from the interpretation method considering different evaluation period. The interpretation of 208 TRT data sets represents limitations of LSM application that some obtained ground thermal conductivities are statistically unstable and convergence time of ground thermal conductivity over test period shows trends responding the length of test period. This evaluation study will be helpful to provide some effective procedure for the thermal parameter estimation and to complement current TRT standard procedure.

• Journal of the Korean Applied Science and Technology
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• v.23 no.2
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• pp.160-168
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• 2006

The conductances of trimethyltetradecylammonium bromide (TTAB) plus triphenyltetradecyl phosphonium bromide (TTPB) and TTAB plus trimethylhexadecylammonium bromide (HTAB) over the entire mole fraction range of TTAB were measured in water and in cyclodextrin plus water mixtures at fixed 4 and 8 mM of cyclodextrin at $30^{\circ}C$. The conductivity plot for both binary mixtures shows a single break from which the mixed critical micelle concentration and degree of micelle ionization were computed. From the slope of the conductivity curve, the equivalent ionic conductivities of the monomeric, associated, and the micelle states were calculated and discussed with respect to the surfactant-cyclodextrin complexation in the whole mole fraction range of both surfactant binary mixtures. The association constant K between the respective monomeric surfactant and cyclodextrin cavity of fixed 4 mM cyclodextrin was computed by considering 1:1 association from the surface tension measurement. A comparison among the K values for HTAB-cyclodetrin, TTAB-cyclodextrin, and TTPB-cyclodextrin shows that the former complexation is significantly stronger in comparison to the other ones due to the longer hydrophobic tail.