• 제목/요약/키워드: Water Vapor Density

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물유리를 이용한 고순도 나노실리카 제조 (Synthesis of High Purity Nano-Silica Using Water Glass)

  • 최진석;이현권;안성진
    • 한국재료학회지
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    • 제24권5호
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    • pp.271-276
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    • 2014
  • Silica nano-powder (SNP) is an inorganic material able to provide high-performance in various fields because of its multiple functions. Methods used to synthesize high purity SNP, include crushing silica minerals, vapor reaction of silica chloride, and a sol-gel process using TEOS and sodium silicate solution. The sol-gel process is the cheapest method for synthesis of SNP, and was used in this study. First, we investigated the shape and the size of the silica-powder particles in relation to the variation of HCl and sodium silicate concentrations. After drying, the shape of nano-silica powder differed in relation to variations in the HCl concentration. As the pH of the solution increased, so did the density of crosslinking. Initially, there was NaCl in the SNP. To increase its purity, we adopted a washing process that included centrifugation and filtration. After washing, the last of the NaCl was removed using DI water, leaving only amorphous silica powder. The purity of nano-silica powder synthesized using sodium silicate was over 99.6%.

PVDC와 Nylon 적층필름으로 포장한 비엔나소시지의 Shelf-life 비교 (Comparison of Shelf-life of Vienna Sausage Packed with Polyvinylidene Chloride and Nylon Laminated Film)

  • 박형우;김병삼;박무현
    • 한국식품과학회지
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    • 제21권2호
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    • pp.252-257
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    • 1989
  • OPP/PVDC 도포/LDPE 복합 필름과 Nylon/LDPE복합 필름을 사용하여 비엔나 소시지를 포장하며 품질수명을 비교한 결과는 다음과 같다. 두 복합 필름의 투습도와 가스투과도는 PVDC 도포 필름이 현저히 적었다. Nylon복합 필름은 가로, 세로 사이의 신장율이 비슷했으나 PVDC 도포 필름은 가로, 세로의 신장율이 4.5배 정도 차이가 있었다. 비엔나 소시지의 Critical Quality Index로서 VBN 이 더 적합했고 이 VBN 변화치로부터 구한 반응 속도상수로부터 $Q_{10}$치를 계산하여 예측한 품질수명은 $15^{\circ}C$ 저장의 경우 Nylon 복합 필름은 25일, PVDC 도포 필름은 31일, $5^{\circ}C$ 저장의 경우 Nylon복합 필름은 32일, PVDC도포 필름은 41일로 나타났다. PVDC도포 필름의 품질수명이 6일에서 9일정도 더 길었다.

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공기 산화와 수증기 산화에 의해 제조된 Ti$O_2$-x박막의 광전기화학적 성질에 관한 연구 (Studies on the Photo-Electrochemical Properties of Ti$O_2$-x Thin Films Prepared by Air Oxidation and Water Vapor Oxidation)

  • 최용국;조기형;최규원;오정근;성정섭
    • 대한화학회지
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    • 제37권6호
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    • pp.549-554
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    • 1993
  • 티타늄 금속판을 공기산화와 수증기 산화하여 만든 Ti$O_{2-x}$ 박막을 시료로 사용하여 1M NaOH 용액에서 광전기화학적 성질을 연구하였다. 높은 온도에서 제조된 Ti$O_{2-x}$ 전극들은 낮은 온도에서 제조된 전극들보다 더 음의 값으로 주어지는 flat band potential($V_{fb}$)과 더 높은 donor density($N_D$)를 가졌다. 전극전위의 변화에 따른 광전류 측정과 Mott-Schottky plot로부터 얻은 $V_{fb}$는 -0.95 ∼ -1.1 V 사이에서 비슷한 값으로 주어졌다. 자외부 영역의 광을 완전히 차단하는 TiO2 단결정을 필터로 하여 가시부 영역의 광전류를 측정할 때 분해능이 좋은 slit를 사용한 경우 좋은 sub band gap 광반응을 볼 수 있었다.

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초다공성 에어로젤 함유 섬유상 복합체를 이용한 신발 안창소재에 관한 연구 (Study on Ultra Porous Aerogel/fiber Composite for Shoe Insole)

  • 오경화;박순자
    • 한국의류학회지
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    • 제33권5호
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    • pp.701-710
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    • 2009
  • This study was conducted to develop excellent insole with good thermal insulation using new materials. We investigated that aerogel/fiber composite can be used as padding materials of shoes by comparing surface shape, moisture regain, water vapor permeability, thermal insulation and compression rate of insole materials tried with nonwoven fabric padding materials and insole sold in market. The results are as follows. Surface shapes were shown that the most appropriate material for sealing aerogel/fiber composite was high density fabric as per size of particle of aerogel. Moisture regain of aerogel/fabric composite was better than nonwoven fabric padding samples. However, when compared to insole sold in market, its moisture regain was worse than those of insole merchandises. Water vapor permeability was higher in material padded with nonwoven fabric than materials padded with aerogel/fiber composite in all three kinds of sealing fabrics. Thermal conductivity of aerogel/fabric composite was lower than nonwoven fabric material regardless of sealing fabrics. Thermal insulation of aerogel/fiber composite was higher than padding material of nonwoven fabric regardless of sealing fabrics. Compression rate of nonwoven (SP1) was higher than that of aerogel/fiber composite (SP2). Compressive elastic recovery rate of SP1 was also higher than that of SP2, which its compression rate and compressive elastic recovery rate were both poor. As the above result, ultra porous aerogel/fiber composite were proved to be material of good thermal insulation with lower thermal conductivity and also compression rate was proved to be low. Therefore, we can say that aerogel/fiber composite have high possibility to be used as insole materials for cold winter shoes requiring good thermal insulation protection.

연신된 LLDPE/CaCO3 composite film의 특성분석 (Characterization of LLDPE/CaCO3 Composite Drawn Film)

  • 이정언;박재민;정재훈;김태영;한명동;서장민;서민정;양성백;염정현
    • 한국염색가공학회지
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    • 제34권1호
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    • pp.68-75
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    • 2022
  • The breathable film refers to a high-functional film that allows gas and water vapor to pass through very fine and sophisticated pores but not liquid. In this research, the breathable film was prepared based on linear low-density polyethylene (LLDPE) and CaCO3 particles by extrude method. The LLDPE composite film containing CaCO3 particles had excellent mechanical properties and functionalties. The drawing is a technologically simple and excellent method for improving the mechanical properties of composite films. In this work, the effects of draw ratio on morphology, crystallinity, pore size distribution, mechanical properties, and water vapor permeability of the films were examined. The results revealed that both surface morphology and breathability were affected by the influence of chain orientation and crystal growth with increasing the draw ratio. The mechanical properties were improved with increasing the draw ratio.

Environmental controls on growing-season sap flow density of Quercus serrata Thunb in a temperate deciduous forest of Korea

  • Laiju, Nahida;Otieno, Dennis;Jung, Eun-Young;Lee, Bo-Ra;Tenhunen, John;Lim, Jong-Hwan;Sung, Joo-Han;Kang, Sin-Kyu
    • Journal of Ecology and Environment
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    • 제35권3호
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    • pp.213-225
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    • 2012
  • Sap flux density (SFD) measurements were used, in combination with morphological characteristics of trees and forest structure, to calculate whole-tree transpiration, stand transpiration (St) and mean canopy stomatal conductance (Gs). Analysis based on the relationships between the morphological characteristics of trees and whole tree water use, and on the responses of SFD and Gs to short wave radiation (RR), vapor pressure deficit (VPD) and soil water content (SWC) during drought and non-drought periods were conducted. The results showed a strong positive correlation between whole tree transpiration and both tree diameter at breast height (DBH) ($r^2$ = 0.95, P < 0.05) and sapwood area (SA) ($r^2$ = 0.98, P < 0.05). Relationships between SFD and DBH ($r^2$ = 0.25), as well as SA ($r^2$ = 0.17) were weak. Daily SFD of Quercus serrata Thunb was closely related to VPD and RR. Although operating at different time scales, RR and VPD were important interacting environmental controls of tree water use. SFD increased with increasing VPD (<1 kPa) and RR. SWC had a considerable effect on stand transpiration during the drought period. The relationships between SFD, VPD and RR were distorted when SWC dropped below 35%.

제올라이트를 이용한 화학축열에 대한 실험적 연구 (Experimental Study on Zeolite 13x for Thermochemical Heat Storage)

  • 하승호;박정훈;이수헌;김광호
    • 설비공학논문집
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    • 제29권8호
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    • pp.429-436
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    • 2017
  • There are three main methods to store heat energy; sensible heat storage, latent heat storage, and thermochemical heat storage. Thermochemical heat storage has the highest storage density among the three methods, so this study focused on the thermochemical heat storage method. Experiments were conducted in this study with Zeolite 13x as thermochemical material in a large-scale reactor with 8 kg of Zeolite 13x. Experiments analyzed storage density of Zeolite 13x with respect to four different heating temperatures ($50^{\circ}C$, $100^{\circ}C$, $150^{\circ}C$, $200^{\circ}C$) in heat storage process. As a result, they showed 40~50 percent of storage efficiency in the experiment. Experiments also revealed that reactions between Zeolite 13x and water vapor were reversible and stable, but efficiency of the system was low, compared with sensible heat storage systems or latent heat storage systems.

고주파 마그네트론 스퍼터링에 의해 성막된 TiO2가 도핑된 ZnO 박막의 전기적 및 광학적 특성 (Electrical and Optical properties of TiO2-doped ZnO Films prepared on PEN by RF-magnetron Sputtering Method)

  • 김화민;손선영
    • 한국전기전자재료학회논문지
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    • 제22권10호
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    • pp.837-843
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    • 2009
  • $TiO_2$(2 wt.%)-doped ZnO(TZO) films with thickness from 100 nm to 500 nm were prepared on polyethylene naphthalate(PEN) substrate under various rf-power range from 40 W to 80 W. Their electrical and optical properties were investigated as a function of rf-power. We think that these properties were closely related with the crystallization and the film density of TZO films. It was also presumed that the vaporization of the water vapor and other adsorbed particles such as an organic solvents can affect the electrical properties of the conventional transparent conductive oxide(TCO) films. On the other hand, since the TZO film deposited on glass substrate at room temperature with rf-power of 80 W shows a very low resistivity of $7.5\times10^{-4}\;\Omega{\cdot}cm$ and a very excellent transmittance over an average 85% in the visible range, that is comparable to that of ITO films. Therefore, we expect that the TZO films can be used as transparent electrode for optoelectronic devices such as touch-panels, flat-panel displays, and thin-film solar cells.

Organic Polymer Light-Emitting Devices on a Flexible Plastic Substrate

  • Kanicki, Jerzy;Lee, Shu-Jen;Hong, Yong-Taek;Su, Chia-Chen
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.91-94
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    • 2004
  • We report on the opto-electronic properties of red, green, and blue poly (fluorene) co-polymer light-emitting devices (PLEDs) fabricated on a flexible plastic substrate. The plastic substrate used has a multi-layer structure with water vapor and oxygen transmission rates of less than $10^{-5}$ g/$cm^2$-day-atm and $10^{-7}$ cc/$cm^2$-day-atm, respectively. We obtained a wide range of color gamut and a maximum emission efficiency of 0.7, 10, and 1.7 cd/A for red, green, and blue PLEDs, respectively. Finally, a simple equivalent circuit model is proposed to simulate PLED current density-voltage characteristics.

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해남 농경지에서의 자유 수면 증발 관측과 해석 (Measurement and Analysis of Free Water Evaporation at HaeNam Paddy Field)

  • 한진수;이부용
    • 한국농림기상학회지
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    • 제7권1호
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    • pp.91-97
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    • 2005
  • BYL-EV250 증발기록계를 이용하여 해남 농경지역의 자유 수면 증발량을 관측하였고, 그 자료를 분석하여, 기상 요소와 증발량과의 관계를 분석하였다. 자연상태에서 증발량을 결정하는 기상요소의 관계를 살펴보고, 그 결과를 바람과 포차의 경험식으로 나타내었다. 이 식을 이용하여 자유 수면으로부터의 시간당 증발량을 구할 수 있었으며 수온, 기온, 습도, 풍속 같은 기상요소만으로 증발량 추정이 가능했다. 증발량 산출에 대한 신뢰성을 높이기 위해 지속적으로 수면에서의 물수지에 대한 연구가 수행되어야 할 것으로 사료된다. 증발량 관측도 다른 기상요소와 같이 매시간 관측 자료 생산 가능성을 시사했다. 부력을 이용한 측정방법은 미소 수위 변화(0.1mm 이하)를 측정 할 수 있어 대형증발계를 활용한 자동관측에 대한 신뢰성을 확보할 수 있었다. 이 결과를 바탕으로 장기간 관측된 자유수면 증발자료와 플럭스 타워에서 동시에 관측된 실제 증발산 자료의 비교분석이 현재진행 중에 있다.