• Title/Summary/Keyword: Waste vinyl

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Development of Source Profiles and Estimation of Source Contribution for VOCs by the Chemical Mass Balance Model in the Yeosu Petrochemical Industrial Complex (여수석유화학산단 내 VOCs에 대한 오염원 분류표의 개발 및 CMB 모델에 의한 기여도 산정)

  • Jeon Jun-Min;Hur Dong;Kim Dong-Sul
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.83-96
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    • 2005
  • The purposes of this study were to characterize the local levels of VOCs (volatile organic compounds), to develop source profiles of VOCs, and to quantify the source contribution of VOCs using the CMB (chemical mass balance) model. The concentration of VOCs had been measured every 6-day duration in the SRO monitoring site in the Yeosu Petrochemical Industrial Complex from September 2000 to August 2002. The total of 35 target VOCs, which were included in the TO-14 designated from the U.S. EPA, was selected to be monitored in the study area. During a 24-h period, the ambient VOCs were sampled by using canisters placing about 10 ~ 15 m above the ground level. The collected canisters were then analyzed by a GC-MS in the laboratory. Aside from ambient sampling at the SRO site, the VOCs had been intensively and massively measured from 8 direct sources and 4 general sources in the study area. The results obtained in the study were as follows; first, the annual mean concentrations of the target VOCs were widely distributed regardless of monitoring sites in the Yeosu Petrochemical Industrial Complex. In particular, the concentrations of BTX (Benzene, Toluene, Xylene), vinyl chloride were higher than other target compounds. Second, based on these source sample data, source profiles for VOCs were developed to apply a receptor model, the CMB model. Third, the results of source apportionment study for the VOCs in the SRO Site were as follows; The source of petrochemical plant was apportioned by 31.3% in terms of VOCs mass. The site was also affected by 16.7% from wastewater treatment plant, 14.0% from iron mills, 8.4% from refineries, 4.4% from oil storage, 3.8% from automobiles, 2.3% from fertilizer, 2.3% from painting, 2.2% from waste incinerator, 0.6% from graphic art, and 0.4% from gasoline vapor sources.

Distribution and Composition of Marine Debris on the Sea Bed around the Busan Port (부산항 부근 해역의 해저폐기물 분포에 관한 연구)

  • Kim, Min-Seok;Lee, Jong-Mun;Kim, Jong-Hwa;Kang, Il-Kwon
    • Journal of Fisheries and Marine Sciences Education
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    • v.18 no.3
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    • pp.236-243
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    • 2006
  • A series of surveys are performed to evaluate the abundance, composition and distribution of marine debris on the sea bed around the Busan port. In order to set up a master plan for the marine environmental pollution the relevant maritime authority must understand how many and w㏊t kinds of marine litters are distributed on the sea bed. At first we planed to survey areas divided regularly according to the coast line but there were many sea going vessels and fishing boats. So we selected and surveyed the around area where there were no sea going vessels or fishing boats.The obtained results are as follows: 1. The mean values of litters in number and weight are 5.8 pieces/㏊. and 3.5㎏/㏊. respectively. 2. The highest density in terms of number are vinyl and plastic item, and in weight are fishing gear and ship articles. 3. The nearer to the shore we surveyed the more we collected in terms of the density of marine litters in number and in weight per hectare. 4. Eel pot, oiled waste, rope, others, other pot and net of fishing gear litters in number were 59.9, 22.7, 7.9, 4.5, 3.1 and 1.9% respectively. 5. There is no relationship between the amount of fish caught and the amount of marine debris.

Purification of Waste Acid and Manufacture of Complex Oxide and Mn-Ferrite Powder by Co-Roasting Process (폐산의 정제 기술 및 분무 배소법에 의한 복합 산화물과 Mn-Ferrite 분말의 제조)

  • 유재근;김정석;민병구;성낙일
    • Resources Recycling
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    • v.7 no.4
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    • pp.64-75
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    • 1998
  • The purpose of this study is to produce high putity composite powder composed of Fe-oxide, Mn-oxide and Mn-ferrite having superior homogencity in composition and particle size distribution by co-roasting process. Binary component metal (Fe, Mn) chloride solutions were produced by dissolving mill scale and ferro-mangancse alloy in hydrochloric acid. These chloride solutions contained the impurities such as SiO$_{2}$, P, Al, Ca and Na, which were originated from the Fe/Mn source materials. The neutralization and polymeric coagulant method were adoped to refine the hydrochloric liquor. When pH is far below the isoelectric point (pH 2-3), the SiO$_{2}$ was the most effectively reduced element, while other impurities remained unchanged. By increasing pH above 3, most of the impurities could be reduced effectively due to the coprecipitation reaction. The polymeric coagulants such as poly vinyl alcohol, resin amine and ammonium molybdate were found to have no effect on the spray roaster designed by the authors. The produced oxide powders were confirmed to be mixtures of Fe-oxide, Mn-oxide and mn-ferrite. the powders were homogeneously mixed and the particle size increased sleeply with increasing co-roasting temperature.

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Recycling of End-of-Life Photovoltaic Silicon Modules (사용 후 태양광 실리콘 모듈의 리싸이클링)

  • Kim, Joon Soo;Cho, Jae Young;Lee, Jae Kyung;Park, Areum;Park, Jin Hyuk;Yun, Hyun Mok;Jun, Yun-Su
    • Resources Recycling
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    • v.28 no.5
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    • pp.19-29
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    • 2019
  • Recently, it is increasing a amount of installized solar-cell rapidly, and waste Solar cell module are generated in according to the reduction of efficiency largely. Therefore, it is concerned at the environmental problems and recycling of valuable materials, greatly. The treatment processes of end-of-life photovoltaic modules are composed the disassembly of Aluminum frames, separation of Tempered glass, removal of Ethylene Vinyl Acetate and recovery of valuable Metals. For the efficient recycling, we are considered to the treatment technology seriously. And we are proposed on the general opinions according to the developing technology, EPR (Extended Producer Responsibility) problems and promotion plans for the activation of recycling industry.

Characteristics of Stabilization of Excavated Solid Wastes by Aerobic and Anaerobic Landfilling (호기 및 혐기매립에 의한 굴착폐기물의 안정화 특성 연구)

  • Park, Jin-Kyu;Oh, Dong Ik;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.3
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    • pp.76-85
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    • 2004
  • Anaerobic decomposition of municipal solid waste (MSW) had potential adverse impacts such as the production of methane and long-term post closure on human health and the environment. It was demonstrated that aerobic degradation of MSW resulted in the reduction of a methane yield and the enhancement of stabilization of MSW. Excavated solid wastes were both aerobically and anaerobically treated in order to evaluate the effects of air injection on the stabilization of landfill site. The municipal solid waste (MSW) samples were excavated from a 10-year old landfill (operation period: 1991. 11~1994. 11), Jeonju, Korea. Excavated municipal solid wastes are primarily composed of soils and vinyl/plastics. For the two aerobic simulated lysimeters, the levels of $O_2$ ranged 1.6~23.1% and the levels of $CO_2$ ranged 1.5~15.1%, which confirmed the aerobic decomposition. Aeration did prevent methane formation. For the anaerobic simulated lysimeter, the $CO_2$ rose as $O_2$ was consumed and low levels of CH4 were produced. The pH levels ranged from 7.7 to 8.9 for anaerobic lysimeter and from 7.3 to 8.5 for aerobic lysimeters. As expected, aerobic treatment proved to enhance the removal of biodegradable materials in the excavated solid wastes when monitoring the concentration of BOD, COD, $NH_4-N$, and $NO_3-N$ in the leachate.

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Survey on Nutrient Removal Potential and Growth State of Water Hyacinth (Eichhornia crassipes) at Seo-Ho. (서호수에서 부레옥잠 생육상태와 영양염류 제거량 조사)

  • Kim, Bok-Young;Lee, Jong-Sik;Kim, Jin-Ho
    • Korean Journal of Environmental Agriculture
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    • v.17 no.2
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    • pp.145-149
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    • 1998
  • To find out the effect of water hyacinth(Eichhornia crassipes Solms-Laub) on the control of eutrofication and plant damage with irrigation water contamination, its ability to remove the nutrients such as nitrogen and phosphrus was studied. The overall results are summarized as follow. 1. It was possible to cultivate water hyacinth for 4 month from June to the middle of October in Suwon. 2. The number of plant was increased from 1,320 to 50,600 for 4 months, and total amounts of N, P, K removed from Seo-Ho by water hyacinth were 78.3, 64.2 and 152.4 kg/10a, respectively. 3. EC and $NH_4-N$ contents were lower at water hyacinth treatment than non-treatment and monthly variation of those contents were decreased until August. 4. With the cultivation of water hyacinth in animal waste water in vinyl plastic house, pH, EC, COD and concentrations of $NH_4-N$ and $PO_4-P$ in the water were drastically decreased. 5. Nitrogen contents absorbed from waste water existed in the order of leaf > stem > root but those of phosphorus root > stem > leaf.

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Investigation on Material Flow Diagram for PVC(poly vinyl Chloride) Profile Based Production, Generation, Recycling and Treatment (PVC재질 프로파일의 생산, 발생 및 재활용, 처리에 기반한 물질흐름도 검토)

  • Phae, Chae-Gun;Jung, Oh-Jin
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.129-140
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    • 2012
  • The objective of this study was to estimate the practical recycling rate of plastic products, so that the study was conducted to build material flow diagram for PVC profile. For this objective, product generation, waste generation and recycling status were investigated. Using collected and analyzed status data, analysis of material flow by product and building material flow diagram were conducted. As result of estimating the recycling rate by product, The sum of domestic demand was 525,448 ton and waste generation was 105,853ton in PVC flooring and profile. The sum of generation of recycling product and raw material was investigated to be 76,004ton(14.46%), which is higher compared to recycling obligation(8.5%) in 2009. To build the material flow diagram in the years(5~20years) ahead, prediction of future demand was based on the assumption that there will be no difference in annual generation of current and future. As the recycling rate of flooring and profile increases, it is estimated to reach 20% in 2013 according to the material flow diagram.

Assessment on Environmental Stabilization of Used Open Dumping Landfill - A Case Study of Kamkok Landfill - (사용종료 비위생 매립지의 환경 안정성 평가 - 감곡 매립지 사례 연구 -)

  • Park, Sangchan;Cho, Byeongreal;Jeong, Jihye;Lee, Minhee;Kim, Taeyoung;Park, Jongho
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.6
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    • pp.13-19
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    • 2008
  • The objectives of this paper are to investigate states of these open dumping landfills for managing, utilizing and stabilization of a municipal solid waste landfill site in environmentally secure conditions. The result of the physical analysis of the landfill showed that it is composed of between 29.72-63.84% organic matter, 32.88% vinyl plastic. The environmental assessment of the landfill site confirmed that the landfill is at a maturation phase due to 0.18 of $BOD_5$/CODcr of leachate. VS and FS of TS Was respectively 30.37%, 32.34% and C/N ratio was 21.8. Surface water around landfill was BOD 10.7 mg/g, SS 37.8 mg/g, E-Coli 31,157(MPN/$100m{\ell}$) and Ground water was $COD_{Mn}$ 1.13-1.38 mg/g, $NO_3-N$ 1.025-4.075 mg/g. Leachat indicated T-P 0.002-0.028 mg/g, $NH_3-N$ 4.0-21.0 mg/g. The soil contamination of around landfill didn't appear as below of the regulation of Soil Environment Conservation Act. The Landfill Gas was $CH_4$ 13.25%, $CO_2$ 6.17%, H2S and CO was not detected. Also Surface Water was not detected $CO_2$, $CH_4$, $H_2S$, CO.

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Priority Decision of Cross-Compliance of Public-Benefit Direct Payment for Agriculture and Rural Area (농업·농촌 공익형 직불제 상호준수의무 우선순위 결정)

  • Chae, Hong-Gi;Kim, Se-Hyuk;Kim, Tae-Kyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.218-225
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    • 2020
  • This study analyzed the priorities of the cross-compliance items of public-benefit direct payment using an Analytic Hierarchy Process and Fuzzy Decision Making Analysis. The valuation criteria are policy efficiency, farm acceptability, and feasibility, and the valuation targets are the basic and additional cross-compliance items. The survey was performed by targeting 50 experts from each class, and conducted for about a month starting from the beginning of July 2019. The results show that the weight of the valuation criteria is higher in the order of farm acceptability, feasibility, and policy efficiency. Compliance with PLS standards, compliance with disposal standards of waste vinyl and pesticides, soil testing, compliance with toxic substance standards, education, etc. are comparatively evaluated to be higher cross-compliance items in basic cross-compliance. Disposing of an abandoned well, jointly collecting and disposing of agricultural by-products, common area care and cleaning, maintenance of empty houses and poor facilities, growing green manure crops during the fallow period, etc. are comparatively evaluated to be higher cross-compliance items for the additional cross-compliance. The results of this study are expected to contribute to the government's policy related to the cross-compliance of public-benefit direct payment.

An Ultrafiltration Study for the Recycling of Synthetic Water-Based Cutting Oil (수용성 합성 절삭유의 재사용을 위한 한외여과 연구)

  • Kim, Jong-Pyo;Kim, Jae-Jin;Ryu, Jong-Hoon
    • Clean Technology
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    • v.8 no.3
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    • pp.119-128
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    • 2002
  • In the present study the membrane filtration characteristics of a commercially available synthetic water-based cutting oil through two kinds of ultrafiltration membranes (HF1-45-CM50 and HF1-43-CM100) with molecular weight cut-offs of 50,000 and 100,000, respectively, have been investigated in detail. Among these membranes, the hydrophilic one (HF1-45-CM50) was found to show a satisfactory result for both the permeate flux and the permeability of oil components, whereas the permeate flux obtained with the hydrophobic membrane (HF1-43-CM100) appears to be significantly low, indicating that synthetic cutting oil was easily wetted on the hydrophobic membrane surface and induced more membrane fouling. The effect of material characteristics of the membrane on the filtration characteristics was found to be much more significant compared with the mean pore size of the membrane. Backflushing by nitrogen gas was applied to reduce the formation of a gel layer and membrane fouling. With the hydrophilic membrane, the backflushing was found to increase the permeate flux, whereas the backflushing resulted in a decrease in flux for the hydrophobic membrane. The flux recovery was observed to be highest when the membranes fouled with waste synthetic cutting oil were immersed into a cleaning solution for more than 72 hours and then backflushed by nitrogen gas.

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