• Title/Summary/Keyword: Waste solution

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A Study on The Comparison of Leaching Methods and Stability of Cement Mortar Solidified Cadmium sludge (시멘트고화에 의한 카드뮴슬러지의 안정성 및 용출실험방법 비교 검토)

  • 주소영;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.17 no.3
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    • pp.21-30
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    • 2002
  • This study was Performed to evaluate the effective solidification of Cd sludge using cement and power plant fly ash as cement admixture, to identify the leaching characteristics of the heavy metal Cd sludge solidified, and to develope proper KLT(Korean Leaching Test) of hazardous waste. KLT was compared with EPT(Extraction Procedure Toxicity) and TCLP(Toxicity Characteristics Leaching Procedure). Fly ash contents ranged from 0% to 30% of cement weight. The experimental results showed that the optimum amount of fly ash replaced was 10% to 15% and KLT was less appropriate than EPA and TCLP. Also the purpose of the study was to suggest the modification factors on the leaching test currently used, based on the above mentioned aspects. The effects of pH, leaching time, leaching for agitating intensity, and leaching solvent were investigated. As the result of test, the leaching potential was relatively high when the pH and agitation intensity of leaching solution were 5 and 150rpm, respectively. Leaching time of six hours was found to be sufficient and the use of acetic acid as a leaching solvent is more useful in landfill site particularly.

Identification of Damping Characteristics of Free-piston Stirling Engines via Nonlinear Dynamic Model Predictions (프리피스톤 스털링 엔진의 동역학 모델 예측을 통한 비선형 부하 감쇠 특성에 관한 고찰)

  • Sim, Kyuho;Kim, Dong-Jun
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.3
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    • pp.248-257
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    • 2016
  • Recently, researches on the free-piston Stirling engines(FPSEs) are actively investigated. FPSEs have merits in its light weight, simple structure, and little need for maintenance, thus becoming a promising solution for the power conversion of renewable energy and waste heat recycle. This paper presents the methodology that estimates damping coefficients using analytical models of linear and nonlinear dynamics for FPSEs, and validates the methodology by comparing with existing experimental results. The analysis model predicts an operable range of linear damping coefficients forming limit cycles by using the root locus, and time responses obtained by numerical integration determines nonlinear damping coefficients. The model predictions are compared with experimental results of the well-known FPSE B-10B. We also investigate the damping characteristics regarding heater temperatures and power piston motions.

A Study on Phosphorus Removal Process Using Steel Industry By-Products(Slag) at Dynamic condition (동적(動的) 상태(狀態)에서 산업(産業) 폐기물(廢棄物)을 이용(利用)한 인(燐) 제거(除去)에 관한 연구(硏究))

  • Lee, Seung-Hwan;Ahn, Kyu-Hong;Yoon, Jong-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.4
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    • pp.103-110
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    • 1996
  • Excessive phosphorus (P as orthophosphate) is one of the major pollutants in natural water that are responsible for algal blooms and eutrophication. P removal by slag is an attractive solution if the P sorption capacity of the slag is significant. To design an efficient land treatment facility, basic information on the behaviour of P in the media-water environment is required. In this study, detailed column experiments were conducted to study the P transport under dynamic condition, and mathematical models were developed to describe this process. The column experiments conducted with dust and cake waste products (slag) from BHP steel industry in Australia as adsorbing media indicated that they had higher sorption capacity of P than that of a sandy loam soil from North Sydney, Australia. P transport in the dust and cake columns exhibited characteristics S-shaped or curvilinear breakthrough curves. The simulated results from a dynamic physical non-equilibrium sorption model (DPNSM) and Freundlich isotherm constants satisfactorily matched the corresponding experimental breakthrough data. The mobility of P is restricted proportionally to the adsorbent's sorption capacity.

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Characteristics of Upcycle Designs in Product and Fashion Design (업사이클 제품 및 패션 디자인의 제작기법과 특성)

  • Lee, Lumi;Yim, Eunhyuk
    • Journal of Fashion Business
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    • v.19 no.4
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    • pp.1-20
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    • 2015
  • Acceleration of the fashion cycle has caused problems of environmental pollution because consumers made a lot of waste of clothes. To solve them, upcycle design has been uprised. This study researched the present condition through recent cases of upcycle design. The standard of collected cases is focused on used products which was already run out once and then has been recreated by being recreated with new design. Through this study, there is a purpose to provide solution of environmental pollutions and a right direction of upcycle fashion design. Collected cases are classified into five production methods. First method is Melting and Compressing, which it melts or compresses materials. Second method is Gathering and Combining, which it gathers or combines each different materials. Third method is Cutting and Dividing, which it cuts or divides products materials. Fourth method is Mixing and Changing, which it mixes materials, adds design elements, and changes of purpose. Final things are classified with multiplicatively used factors which are already divided.

Hydrocarbon Synthesis of Waste Lignocellulosics by Liquefaction Reaction of Thermochemical Deoxyhdrogenolysis Method (II) (목질폐재(木質廢材)의 열(熱)-화학적(化學的) 탈(脫)산소-수소첨가반응(환원반응)에 의한 액화(液化)탄화수소의 합성 (II))

  • Lee, Byung-Guen
    • Journal of the Korean Wood Science and Technology
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    • v.19 no.4
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    • pp.80-84
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    • 1991
  • Lignocellulosic biomass including acetosolv ricestraw and spruce lignin were liquefied and converted into liquid hydrocarbons by catalytic hydroliquefaction reaction. These experimental works were carried out in 1-liter-capacity autoclave using 50% tetralin and m-cresol solution respectively as soluble solvent and Ni. Pd. Fe and red mud as catalyst. $H_2$ gas was supplied into the reactor for escaltion of deoxhydroenolysis reaction. Catalyst concentrations were 1 % of raw material based on weight. The ratio between raw materials and soluble solvent are 1g and 10cc. The reaction conditions are 400-$700^{\circ}C$ of reaction temperature, 10-50 atms of reaction pressure. The highest yield of hydrocarbon, so called "product oil" showed 32% and 5.5% of lowest char formation when red mud was used as catalyst. The product oil yields from those of other catalysts were in the range of 20-29%. The influence of different initial hydrogen pressures was examined in the range d 30-50 atms. A minimum pressure of 35 atms was necessary to obtain a complete recovery of souble solvent for recycling.

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Development of Polymeric Adsorbents for the Treatment of Colored Waste Waters and It's Applications ―Diethylaminoethylated Cellulosic Adsorbents― (유색배수 처리를 위한 고분자흡착제의 개발과 그 응용(III) ―디에틸아미노에틸화 셀룰로오스계 흡착제―)

  • Choe, Ji Eun;Sung, Woo Kyung;Lee, Mee Kyung;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.42-48
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    • 1993
  • In the present work, decoloring of acid dye solution by the diethylaminoethylated cellulosic adsorbents($CA_{DASE}$) was studied with the aim of developing polymeric adsorbents for the treatment of colored wastewaters. To prepare the cellulosic adsorbents, the $CA_{DASE}$ cellulose and polyvinyl alcohol mixture(80 wt% cellulose content) were crosslinked by tryacryloyl hexahydro-s-tryazine(TAHHT), ammonium phosphate and then treated with solutions containing sodium hydroxide and 2-diethylaminoethyl chloride. Batch and flow method were employed to determine decoloring capacity of C $A_{DEAE}$ for C.I.acid yellow 49. $CA_{DASE}$ exhibited much better desorption capacity than activated carbon. Furthermore, the exhausted $$CA{DASE} could be readily regenerated by washing with dilute sodium hydroxide.

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An Experimental Study on Investigation for Application of High Quality Recycled Fine Aggregate Produced by Dry Manufacturing Method (건식제조법에 의해 생산된 고품질 재생산골재의 활용성 검토를 위한 실험적 연구)

  • Moon Hyung-Jae;Koo Gyung-Mo;Roh Kyung-Min;Cho Bong-Suk;Kim Gyu-Yong;Kim Moo-Han
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.11a
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    • pp.29-32
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    • 2005
  • Recently, for the problem solution of demand and supply imbalance of fine aggregate due to the shortage of natural fine aggregate and the environment regulation on sea sand extraction in the construction field, the studies for the application of recycled fine aggregate using waste concrete are being progressed versatilely. The purpose of this study is to investigate quality of recycled fine aggregate manufactured by drying manufacturing system which is the manufacture method of high duality recycled fine aggregate, and to analyze on thehardened and durability properties of recycled concrete using it. Therefore it is to present the fundamental data for application and utilization of recycled concrete. The results of this study are as follows; Quality of recycled fine aggregate by drying manufacturing system is improved, and compressive strength, carbonation depth and chloride ion penetration depth of recycled concrete using high quality recycled fine aggregate are similar to those of normal concrete using natural and crashed sand. But, resistance to $H_{2}SO_{4}$ show decreased somewhat.

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The Separation and Recovery of Nickel and Lithium from the Sulfate Leach Liquor of Spent Lithium Ion Batteries using PC-88A

  • Nguyen, Viet Tu;Lee, Jae-Chun;Jeong, Jinki;Kim, Byung-Su;Pandey, B.D.
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.137-144
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    • 2015
  • The present paper deals with the extractive separation and selective recovery of nickel and lithium from the sulfate leachate of cathode scrap generated during the manufacture of LIBs. The conditions for extraction, scrubbing and stripping of nickel from lithium were optimized with an aqueous feed containing $2.54kg{\cdot}m^{-3}$ Ni and $4.82kg{\cdot}m^{-3}$ Li using PC-88A. Over 99.6% nickel was extracted with $0.15kmol{\cdot}m^{-3}$ PC-88A in two counter-current stages at O/A=1 and pH=6.5. Effective scrubbing Li from loaded organic was systematically studied with a dilute $Na_2CO_3$ solution ($0.10kmol{\cdot}m^{-3}$). The McCabe-Thiele diagram suggests two counter-current scrubbing stages are required at O/A=2/3 to yield lithium-scrubbing efficiency of 99.6%. The proposed process showed advantages of simplicity, and high purity (99.9%) nickel sulfate recovery along with lithium to ensure the complete recycling of the waste from LIBs manufacturing process.

Interaction of NpO+2 with Cl- in Na-Ca-Cl-type solutions at ionic strength of 6M: Effect of presence of Ca ion on interaction

  • Nagasaki, Shinya;Saito, Takumi;Tsushima, Satoru;Goguen, Jared;Yang, Tammy
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1778-1782
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    • 2017
  • The interaction of $NpO^+_2$ with $Cl^-$ was studied using visible-near-infrared spectroscopy in $NaCl-Ca-Cl_2-NaClO_4$, $NaCl-NaClO_4$, and $CaCl_2-NaClO_4$ solutions with ionic strength (I) of 6M. The spectra of $NpO^+_2$ around 980 nm varied with $Cl^-$ concentration in the $NaCl-CaCl_2-NaClO_4$ and $NaCl-NaClO_4$ solutions at [$Cl^-$] ${\geq}3.5M$, but not in the $CaCl_2-NaClO_4$ solution. Assuming the 1:1 interaction between $NpO^+_2$ and $Cl^-$, the apparent equilibrium constants at I = 6M were evaluated. The presence of $Ca^{2+}$ was found to destabilize overall interaction between $NpO^+_2$ and $Cl^-$. The observations were consistent with the density functional theory calculation.

Artıstıc studies on desıgn development wıth fabrıc scraps ın the context of sustaınable fashıon

  • KOCA, Emine
    • The Research Journal of the Costume Culture
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    • v.27 no.6
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    • pp.654-665
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    • 2019
  • The process of clothing production creates waste and scrap, which creates environmental, economic, and ethical issues. With this in mind the concept of ethical and sustainable fashion is discussed on many platforms as an important and timely topic. Many solutions have been presented on this subject. For the solution of this problem which has been increasing in the fashion and textile industry, the usage of sustainable materials and production methods is needed. There in a 'recyclable material cycle' should be adapted, instead of a 'traditional material cycle'. New methods and techniques should be developed with multi-disciplinary design approaches to produce creative and high value-added products in the name of fashion and sustainability. This is seen as one of the more effective solutions. This study aims to show that production scraps can be transformed into timely clothing designs with samples. The fabric scraps from different brands were turned into unique clothing designs with up to date trends by designer. In the practices completed while following the design process, collage and patchwork techniques were applied depending on the characteristics of the scrap fabric, artistic figures were hand-stitched onto the design. With this study, the scraps that get thrown into dumping grounds and damage the ecosystem can turn into ethical and economic benefits for the manufacturer. How to choose new high value-added products and create an awareness of social responsibility is also shown with examples in this study.