• 제목/요약/키워드: Waste material

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전기로 폐 MgO-C계 내화재의 제강원료 활용 가능성 연구 (Basic Study on the Recycling of a Waste MgO-C Refractory Material as a Flux for EAF Steelmaking)

  • 왕제필;김행구;고민석;이동헌
    • 자원리싸이클링
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    • 제30권6호
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    • pp.53-60
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    • 2021
  • 현재 EAF 전기로 제강공정에서는 슬래그 중의 MgO 함량을 증가시켜 탈황능과 내화재 수명을 개선시키고자 돌로마이트(백운석) 용제(Flux)를 첨가하고 있으며, 또한 에너지효율을 증가시키기 위해 용강 중에 가탄재를 취입하고 있다. 이러한 견지에서 폐 MgO-C계 내화재를 재활용하는 연구를 진행하였다. 폐 MgO-C계 내화재는 MgO(>70%)과 탄소(>10%)를 대량 함유하고 있기 때문이다. 이런 목적으로 제강 슬래그를 대상으로 해서 폐 MgO-C계 내화재를 첨가하는 효과를 실험하였고 그 결과를 경소 돌로마이트를 첨가한 결과와 비교하여 폐 MgO-C계 내화재 재활용 효과를 평가하였다. 폐 MgO-C계 내화재를 사용해서 얻은 결과가 슬래그 염기도 측면에서 경소 돌로마이트를 사용한 결과와 유사하게 나타남으로써 기존 경소 돌로마이트 대체 가능성을 확인하였다. 특히 폐 MgO-C계 내화재를 사용한 경우에는, 폐 내화재에 다량 함유된 흑연 성분에 의한 슬래그 중의 철산화물과의 환원반응으로 CO가스가 발생하여 생긴 크고 작은 기포들이 관찰되었으며 이로써 슬래그 Foaming 효과를 기대할 수 있는 것으로 확인하였다.

Estimation of Input Material Accounting Uncertainty With Double-Stage Homogenization in Pyroprocessing

  • Lee, Chaehun;Kim, Bong Young;Won, Byung-Hee;Seo, Hee;Park, Se-Hwan
    • 방사성폐기물학회지
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    • 제20권1호
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    • pp.23-32
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    • 2022
  • Pyroprocessing is a promising technology for managing spent nuclear fuel. The nuclear material accounting of feed material is a challenging issue in safeguarding pyroprocessing facilities. The input material in pyroprocessing is in a solid-state, unlike the solution state in an input accountability tank used in conventional wet-type reprocessing. To reduce the uncertainty of the input material accounting, a double-stage homogenization process is proposed in considering the process throughput, remote controllability, and remote maintenance of an engineering-scale pyroprocessing facility. This study tests two types of mixing equipment in the proposed double-stage homogenization process using surrogate materials. The expected heterogeneity and accounting uncertainty of Pu are calculated based on the surrogate test results. The heterogeneity of Pu was 0.584% obtained from Pressurized Water Reactor (PWR) spent fuel of 59 WGd/tU when the relative standard deviation of the mass ratio, tested from the surrogate powder, is 1%. The uncertainty of the Pu accounting can be lower than 1% when the uncertainty of the spent fuel mass charged into the first mixers is 2%, and the uncertainty of the first sampling mass is 5%.

바이오에탄올 생산을 위한 바이오매스 자원으로서 버섯골목의 이용 가능성 평가 (Evaluation on the utilization possibility of waste mushroom logs as biomass resource for bioethanol production)

  • 이재원;구본욱;최준원;최돈하;최인규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 춘계학술대회
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    • pp.485-488
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    • 2006
  • In order to investigate the possibility of waste mushroom logs as biomass resource chemical and physical characteristics of normal woods and waste mushroom logs such as crystallinity value, energy consumption, total sugar yield after hydrolysis chemical compounds and molecular weight distribution after acid hydrolysis, were examined. In the results, crystallinity of waste mushroom logs which were three year passed after the inoculation was decreased drastically from 49% to 33% during the cultivation. Lignin contents as chemical compounds of normal woods and waste mushroom logs were 21.07% and 18.78%, respectively. By the results of measurement of energy consumption, the size reduction of normal woods required a significantly higher energy than that of waste mushroom logs. In the hydrolysis, total sugar yield by enzyme and acid hydrolysis were high in waste mushroom logs(53% 57.5%) than in normal woods(42.9%, 47.17%). According to the molecular weight distribution using GPC, low molecular weight compounds were distributed in waste mushroom logs. Based on these results, waste mushroom logs have enough potential as material for developing alternative energy because of easily conversion to sugar by various hydrolysis methods and requirement of low energy consumption during size reduction.

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A Study on the Design of Accessories through the Concept of Reincarnation

  • Park, You Shin
    • 패션비즈니스
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    • 제21권6호
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    • pp.77-86
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    • 2017
  • This study aims to explore the unethical issues in leather processing and to develop designs of leather products based on the concept of reincarnation by ecosystem circulation. The method used in this research include the review of previous literature and the design process for development fashion accessories using waste leather. The design process comprises collecting waste leather, classifying waste leather by type, color, and size, and developing leather products according to line carnation method. For this research, the material was limited to waste cowhide leather collected from leather workshops and leather product factories. The leather pieces were divided into typical and atypical types and developed leather accessories based on the leather piece's color and size. A twill brooch, four-string bracelet, a brooch using the four-stringed leather strap and mini handbag designs were developed using regular type waste leather. An armband of abstract patterns and a cellphone case with graffiti pattern using irregular type over-splitting waste leather. The environmental issues in design are observed as part of understanding the significance of this study. Development of waste leather accessory can expand the usability of the waste leather as well as increase the product value by creating limited-line editions. By understanding the role and benefits of sustainable upcycling, this research suggests an efficient way to use waste materials in fashion to coexist with the natural environment.

熱分解에 의한 可燃性 廢棄物의 처리 및 資源回收에 관한 연구 (A Study on the Treatment of Combustible Wastes and the Resource Recovery by Pyrolysis)

  • Kim, Sam-Cwan;Zong, Moon-Shik
    • 한국환경보건학회지
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    • 제13권1호
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    • pp.17-33
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    • 1987
  • As a result of technical advances and industrialization, the characteristics of domestic and industrial wastes are becoming more complex. Accordingly, improved treatment and disposal systems are being continuously sought to take account of complex characteristics and to comply with economic restrictions. In this study, an application of pyrolysis to the treatment of industrial wastes, including waste scrap rubber, waste raw material used in making the slipper bottom and waste PVC pipe, and the effectiveness of pyrolysis in resource recovery from these wastes were investigated. Batches of wastes were pyrolysed by external heating to a temperature of 400-800$\circ$C in a 32 mm diameter x 0.9 m long silica tube to produce combustible gases, oils and chars. Before the start of pyrolysis runs, the entire system was purged with nitrogen gas to exclude the air. The temperature inside the retort was controlled by the thermocouple in the gas stream, and referred to as the pyrolysis temperature. Under these conditions three products were separately collected and further analyzed. The results were summarized as follows. 1. More gases and less chars were produced with higher pyrolyzing temperature and with higher rates of heating, but the yields of oils tended downwards at temperatures above 700$\circ$C. Accordingly, operating conditions of pyrolysis should be varied with desired material. 2. Calorific values and sulfur contents of produced oils were sufficient and suitable for fuel use. Chars from waste rubber had high heating values with low sulfur contents, but calorific values of chars from waste PVC and waste slipper were as low as 3, 065-4, 273 kcal/kg and 942-2, 545 kcal/kg, respectively. Therefore, char from these wastes are inappropriate for fuel. 3. Soluble contents of Pb, Cd, Cu and Zn in chars from waste rubber and waste slipper were below the Specific Hazardous Waste Treatment Standards. However soluble contents of Pb and Cd in chars from waste PVC were one or two times and five or seven times exceedingly the Specific Hazardous Waste Treatment Standards, respectively. 4. Post high heating is desirable for treatment method of waste PVC which generates toxic hydrogen chloride. 5. The proportions of hydrogen, methane and ethane in produced gases were in the range of 3.99-35.61% V/V, 18.22-32.50% V/V and 5.17-5.87% V/V, respectively. 6. Pyrolysis is a useful disposal method in case of waste slipper, which was hardly combustible, and thus investigations of this kind of materials are required for effective management of industrial waste. 7. Based upon the possible market development for products, overall pyroly economics to take account of treatment values of noncombustible or hazardous materials should be evaluated.

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폐유리를 활용한 강섬유보강 콘크리트의 내구성에 관한 실험적 연구 (An experimental study on the durability of steel fiber reinforced concrete containing waste glass)

  • 정명일;조광연;이봉춘;김경훈;박승범
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.841-846
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    • 2002
  • As growing of industrialization and increasing of population. the quantities of waste are rapidly growing in the earth. It cause some problems such as the waste of natural resources and environmental pollution. In this context, recycling waste glass as a material of concrete has a great advantage environmentally and economically. On that score, other contries have start recycling waste glass widely and accoumulatig the technology of manufacturing equipment and construction. However, few studies have been done in this country. Therefore, this study was conducted freeze-thaw resistance test and neutralization reaction test to analyze the durability properties of steel fiber reinforced concrete containing waste glass as fine aggregate and containing industrial by-products(Fly ash).

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매립장의 인공점토차수재 개발에 관한 연구 (Development of Amended Clay Liner for Waste Containment System)

  • 신은철;김성환;오영인
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1997년도 총회 및 춘계 학술발표회 논문집
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    • pp.70-73
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    • 1997
  • 산업폐기물의 재활용은 정부가 적극적으로 권장하고 있다. 폐석회의 비중, 건조단위중량. 일축 압축강도, pH, 투수계수 등의 지반특성을 실내시험결과를 고찰함으로써 폐석회가 매립장에서 인공차수재 및 복토재로 사용 가능성을 평가한다. 폐석회를 몇가지 환경실험을 통해서 그 결과를 EPA기준과 비교하였다. 본 논문에서는 실내실험을 수행한 결과를 전술하였고, 실험결과 분석에 의하면 혼합토(폐석회/화강풍화토)가 위생매립장의 인공차수재로 가능성이 있다고 판단된다.

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폐유리 분말을 이용한 모르터 기초실험과 콘크리트 제품 개발을 위한 연구 (The experimental study on the basic test by mortar and the development of concrete material using Powdered Waste Glasses)

  • 서동훈;김광기;박선길;박병근;정병훈;정민영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2001년도 학술논문발표회
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    • pp.58-63
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    • 2001
  • Recently, it has been often reported that recycling of wasted glasses should be a great topic in related business circles. For the environmental reasons, a public institution are looking fur the ways of recycling these waste glasses. Consequently, the purpose of this research is to recycle crushed and powdered waste glasses by substituting for the cement in mortar and concrete. First of all, the optimum replacement ratio of Powdered Waste Glasses(PWG) can be obtained from the pilot test results. Secondary, we make advances in recycling of waste glasses as recycled to make secondary concrete products. So, we manufactured concrete brick and block contained powdered waste glasses by through mortar pilot test.

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Herbaceous Biomass Waste-Derived Activated Carbons for Supercapacitors

  • Han, Joah;Lee, Jin Hyung;Roh, Kwang Chul
    • Journal of Electrochemical Science and Technology
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    • 제9권2호
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    • pp.157-162
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    • 2018
  • In the study, herbaceous biomass waste including giant miscanthus, corn stalk, and wheat stalk were used to prepare commercially valuable activated carbons by KOH activation. The waste biomass predominantly consists of cellulose/hemicellulose and lignin, in which decomposition after carbonization and activation contributed to commercially valuable specific surface areas (>$2000m^2/g$) and specific capacitances (>120 F/g) that exceeded those of commercial activated carbon. The significant electrochemical performance of the herbaceous biomass-derived activated carbons indicated the feasibility of utilizing waste biomass to fabricate energy storage materials. Furthermore, with respect to both economic and environmental perspectives, it is advantageous to obtain activated carbon from herbaceous biomass waste given the ease of handling biomass and the low production cost of activated carbon.

Oyster Shell waste is alternative sources for Calcium carbonate (CaCO3) instead of Natural limestone

  • Ramakrishna, Chilakala;Thenepalli, Thriveni;Nam, Seong Young;Kim, Chunsik;Ahn, Ji Whan
    • 에너지공학
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    • 제27권1호
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    • pp.59-64
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    • 2018
  • In this paper, we investigated the alternative sources of limestone. Oyster shell waste originated from aquaculture that causes a major disposal landfill problem in coastal sectors in southeast Korea. Their inadequate disposal causes a significant environmental problems araised. Bio mineralization leads to the formation of oyster shells and consists $CaCO_3$ as a major phase with a small amount of organic matter. It is a good alternative material source instead of natural lime stone. The utilization of oyster shell waste for industrial applications instead of natural limestone is major advantage for conservation of natural limestone. The present work describes the limestone and oyster shells hydraulic activity and chemical composition and characteristics are most similar for utilization of oyster shell waste instead of natural limestone.