• 제목/요약/키워드: Waste form

검색결과 490건 처리시간 0.027초

Immobilization of Metal lons Using Low-Temperature Calcination Techniques of Spinel-ferrites

  • Yen, Fu-Su;Kao, Hsiao-Chiun;Chen, Wei-Chien
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.106-110
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    • 2001
  • Formation of stoichiometric lithium-, nickel-, and zinc- ferrites by calcining organo-metallic precursors a temperature below 40$0^{\circ}C$ is examined using DTA/TG, and XRD techniques. It attempts to simulate th immobilization of metal ions in industrial liquid influents (waste) through the synthesis of stoichiometric spinel ferrites (SSF). Two steps of the SSF formation during thermal treatments are noted. The transformation of magnetite to ${\gamma}$ - Fe$_2$O$_3$and subsequent first formation of SSF were observed at temperatures ranging from 200 to 45$0^{\circ}C$. Th formation of cation-containing ${\gamma}$-Fe$_2$O$_3$and subsequent second formation of the ferrite occurred at temperature ranges of < 45$0^{\circ}C$ and 500 to $650^{\circ}C$, depending on the heating rate used. Then the temperature range of 200t 45$0^{\circ}C$ is critical to the performance of the technique, because a calcination at the range would lead to a complete formation of SSF, avoiding the occurrences of ${\gamma}$-Fe$_2$O$_3$and ion-containing ${\gamma}$-Fe$_2$O$_3$. If not, so $\alpha$-Fe$_2$O$_3$would occur. And annealing at temperature above $650^{\circ}C$ must be employed by which solid-state reactio of $\alpha$-Fe$_2$O$_3$with metal ions (possibly metal oxides) to form SSF can be conducted.

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플레어스택의 화염 형상 분석 (Analysis of Flame Shape in Flare Stack)

  • 이헌석;김범수;정상용;유진환;박철환;고재욱
    • 한국가스학회지
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    • 제13권3호
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    • pp.49-53
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    • 2009
  • 릴리프시스템은 공정 내에 과압 방지하여 공정의 안전성을 높여주는 역할을 한다. 릴리프 시스템에서 방출되는 폐가스로 인한 폭발, 복사열, 독성가스 확산을 막기 위하여 플레어스택을 설치한다. 플레어스택에서는 공정의 안전성 향상을 위하여 안전한 연소가 가장 중요한 요소이며, 안전한 연소를 위하여 방출되는 가스량과 속도 제어는 API 521 code의 기술기준을 따르며, 플레어스택에서 발생하는 화염의 형상은 방출되는 가스의 압력과 질량유속에 의하여 jet fire의 형상을 하고 있다. 이는 화염의 형상은 완전 연소와 열 방출에 영향을 미치는 요소로 이 논문에서는 화염의 형상을 분석하였다. 화염의 길이는 API code와 jet fire 모델이 유사한 값을 보였으며, 화염은 지면에 더 많은 영향을 미치는 것으로 분석되었다.

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Duckweed as a Protein Source for Fine-Wool Merino Sheep: Its Edibility and Effects on Wool Yield and Characteristics

  • Damry, J.V. Nolan;Bell, R.E.;Thomson, E.S.
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권4호
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    • pp.507-514
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    • 2001
  • Two experiments were carried out to investigate whether duckweed is useful as a dietary protein source for fine-wool Merino sheep and to evaluate its effects on wool yield and characteristics. In Experiment 1, the sheep were given one of three maintenance diets consisting of oaten chaff (520-700 g/d) supplemented with 16-32 g crude protein/d in the form of fresh (1 kg/d) or sun-dried (50-100 g/d) duckweed. Each ration was estimated to provide 5.4 MJ (1.3 Mcal)/d of metabolisable energy (ME). The sheep readily ingested the fresh or dried duckweed. None of the wool measures (yield, rate of fibre elongation, fibre diameter) differed (p>0.05) between dietary treatments. In Experiment 2, oaten-chaff-based diets (800 g/d) supplying 6.5-7.2 MJ (1.6-1.7 Mcal)/d of ME were supplemented with iso-nitrogenous amounts (4-5 g N) either of urea (8 g), cottonseed meal (60 g) or dried duckweed (100 g). In this experiment, the rate of wool fibre elongation, thought to be related to intestinal amino acid absorption, was lower (p<0.05) for sheep given the oaten chaff/urea diet than for those given either oaten chaff/cottonseed meal or oaten chaff/duckweed for which the rates did not differ (p>0.05). Fibre diameter, which ranged from 16.0-16.7 mm, did not differ (p>0.05) between diets, but tended to be lower on the oaten chaff/urea diet so that volume of wool produced was also significantly lower (p<0.05) on this diet than on the diets containing duckweed or cottonseed meal. Rumen ammonia concentrations at 4.5 and 7.5 h after feeding were higher (p<0.05) for sheep given the oaten chaff/urea diet than for those given the other two diets. A comparison of the rumen ammonia concentrations, wool growth rate and predicted flows of amino acids from the rumen of sheep supplemented with duckweed rather than cottonseed meal suggested that duckweed is a valuable source of 'escape protein' for ruminants.

Effects of Nutritional and Environmental Conditions on Planktonic Growth and Biofilm Formation of Citrobacter werkmanii BF-6

  • Zhou, Gang;Li, Long-Jie;Shi, Qing-Shan;Ouyang, You-Sheng;Chen, Yi-Ben;Hu, Wen-Feng
    • Journal of Microbiology and Biotechnology
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    • 제23권12호
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    • pp.1673-1682
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    • 2013
  • Citrobacter sp. is a cause of significant opportunistic nosocomial infection and is frequently found in human and animal feces, soil, and sewage water, and even in industrial waste or putrefaction. Biofilm formation is an important virulence trait of Citrobacter sp. pathogens but the process and characteristics of this formation are unclear. Therefore, we employed in vitro assays to study the nutritional and environmental parameters that might influence biofilm formation of C. werkmanii BF-6 using 96-well microtiter plates. In addition, we detected the relative transcript levels of biofilm formation genes by RT-PCR. Our results indicated that the capacity of C. werkmanii BF-6 to form biofilms was affected by culture temperature, media, time, pH, and the osmotic agents glucose, sucrose, NaCl, and KCl. Confocal laser scanning microscopy results illustrated that the structure of biofilms and extracellular polysaccharide was influenced by 100 mM NaCl or 100 mM KCl. In addition, nine biofilm formation genes (bsmA, bssR, bssS, csgD, csgE, csgF, mrkA, mrkB, and mrkE) were found to contribute to planktonic and biofilm growth. Our data suggest that biofilm formation by C. werkmanii BF-6 is affected by nutritional and environmental factors, which could pave the way to the prevention and elimination of biofilm formation using proper strategies.

전기방사를 이용한 리그닌 나노섬유의 제조 (Fabrication of Lignin Nanofibers Using Electrospinning)

  • 이은실;이승신
    • 한국의류학회지
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    • 제38권3호
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    • pp.372-385
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    • 2014
  • Lignin is an abundant natural polymer in the biosphere and second only to cellulose; however, it is under-utilized and considered a waste. In this study, lignin was fabricated into nanofibers via electrospinning. The critical parameters that affected the electrospinnability and morphology of the resulting fibers were examined with the aim to utilize lignin as a resource for a new textile material. Poly(vinyl alcohol) (PVA) was added as a carrier polymer to facilitate the fiber formation of lignin, and the electrospun fibers were deposited on polyester (PET) nonwoven substrate. Eleven lignin/PVA hybrid solutions with a different lignin to PVA mass ratio were prepared and then electrospun to find an optimum concentration. Lignin nano-fibers were electrospun under a variety of conditions such as various feed rates, needle gauges, electric voltage, and tip-to-collector distances in order to find an optimum spinning condition. We found that the optimum concentration for electrospinning was a 5wt% PVA precursor solution upon the addition of lignin with the mass ratio of PVA:lignin=1:5.6. The viscosity of the lignin/PVA hybrid solution was determined as an important parameter that affected the electrospinning process; in addition, the interrelation between the viscosity of hybrid solution and the electrospinnability was examined. The solution viscosity increased with lignin loading, but exhibited a shear thinning behavior beyond a certain concentration that resulted in needle clogging. A steep increase in viscosity was also noted when the electrospun system started to form fibers. Consequently, the viscosity range to produce bead-free lignin nanofibers was revealed. The energy dispersive X-ray analysis confirmed that lignin remained after being transformed into nanofibers. The results indicate the possibility of developing a new fiber material that utilizes biomass with resulting fibers that can be applied to various applications such as filtration to wound dressing.

Bacillus sp. Y-124로부터 $\alpha$-Amylase의 생산 및 그 보존성에 관한 연구 (Production and Preservation of $\alpha$-Amylase from Bacillus sp. Y-124)

  • Jun, Hong-Ki;Yeehn Yeeh;Lee, Jong-Kune
    • 한국미생물·생명공학회지
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    • 제9권3호
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    • pp.145-152
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    • 1981
  • 산업폐수로부터 강력한 $\alpha$-amylase 생성능력을 가진 미생물을 분리하여 검토한 곁과 Bacillus속 (Bacillus Y-124)으로 판명되었으며, Bacillus Y-l24로부터 $\alpha$-amylase의 생산성을 최적화하기 위해 배양조건 및 생성된 효소의 안정성을 유지하기 위한 제반 영향들을 검토하였다. 기본 배지내의 casein 및 Ca-pantothenate의 첨가는 본 효소의 생산에 좋은 인자로 작용하였으며 calcium이온 역시 효소합성에 관여하는 것으로 나타났다. 또한 (NH$_4$)$_2$HPO$_4$는 본 미생물의 효소생성 에 중요한 유기 질소원으로 작용하였다. 생성된 본 효소의 보존에 대한 안정성의 유지에는 calcium 및 sodium염의 영향이 컸으며 특히 CaCO$_3$$Na_2$SO$_4$의 첨가는 이 효소의 변성요인을 제거하는데 효과적인 보존제의 하나로 인식되 었다.

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산화칼슘을 이용한 대두 올리고당의 회수 (Recovery of Soy Oligosaccharides using Calcium Oxide)

  • 최연배;김강성;손헌수
    • 한국식품과학회지
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    • 제27권2호
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    • pp.225-229
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    • 1995
  • 저칼로리 감미료로서 장내 미생물 균총을 개선한다고 알려진 대두 올리고당을 전처리 및 Steffen법을 이용하여 대두 침지액으로부터 분리, 회수하였다. 전처리로서 pH를 $3.5{\sim}4.0$으로 조절하거나, 염화칼슘을 당 대비 8%(w/w)를 첨가하여 대두 침지액 중에 함유된 단백질을 약 $25{\sim}30%$가량 제거할 수 있었다. 또한 대두 침지액에 염화칼슘과 산화칼슘 분말을 각각 당 대비 약 20%, $100{\sim}120%$씩 첨가한 후 $5^{\circ}C$에서 20분 동안 반응시키는 Steffen법을 이용하면 대두 침지액 중에 존재하는 대두 올리고당의 약 85%를 saccharate 형태로 분리, 회수할 수가 있었다. 이산화탄소로 당을 탈착시켜 회수한 결과 최종적으로 약 80%의 수율로 당을 회수할 수가 있었으며 단백질은 약 80% 정도 제거할 수가 있었다. 회수된 당액의 당조성은 대두 침지액과 유사하였다.

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합판접착제용(合板接着劑用) 미세목분증량제(微細木粉增量劑)에 관(關)한 연구(硏究) (On the Feasibilty of Milled Sanders as a New Extender for Plywood Glue)

  • 안기우
    • Journal of the Korean Wood Science and Technology
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    • 제1권2호
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    • pp.3-10
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    • 1973
  • This study was carried out to examine the characeristics of waste sanders(S)from. plywood and pre-finishing plywood surface sanding and double saw finishing, as a new extander in urea-formaldehyde resin(UFR) in plywood adhesive, and to focus, adhesive strength using the glue extended with milled sanders(MS) as extender, leveling the optimum amount of MS to be added, and examining the physical properties of glue extended MS & S. Also economical good feasibility of substitution for wheat flour(WF) with MS as a new extender is analyzed and presented in details. Selecting three standard samples of 80, 100 and 180 mesh, sorking them in distilled water at $20^{\circ}C$, 24 hours, redrying at $105^{\circ}C$ and rescreening the sample with standard screen, again, the 3 samples of 80, 100, and 180 mesh are passed 23 percent through 80 mesh sander standard sample 27 percent through on 100 mesh and only 10.9 percent through 180 mesh, respectively. The particle size of retained parts are greater in size of redried form. It seems undoubtly that particles to be extended in glue are got swollen and become greater in size and coarser in shape. The shape of fresh S particles are irregular thin needle with small scale, as shown in Figure 5. PFS are so finer than plywood S that only 9.8 percent of the S retained on 100 mest screen, 24. 30 percent on 100-160 mesh, and 65.9% on 160-180 mesh. But particle size of the fresh S is large enough to make the viscosity of glue direct extended with S too high to apply it glue spreader. The glue extended with milled sanders(MS). 3 hours milled PFS or 6 hours milled plywood S, having particle sizes shown in Tables 7 and 8, as ratio of Reain/MS/WF/water: 100/8/8/10, indicate good viscosity of 16 to 24 ps, as shown in Figure 5, for applying direct to glue spreader, have high tensile-shear strength (adhesive strength), 102.4 kp/$cm^2$, and 94 percent wood failure.

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초미분말 서냉 슬래그를 혼화재로 사용한 콘크리트의 기초적 특성 (Basic Properties of Concrete with Ultrafine-Blaine Air Cooling Slag as Admixture)

  • 허재혁;정성욱;허재원;임남기
    • 한국건축시공학회지
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    • 제9권2호
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    • pp.77-83
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    • 2009
  • In this study, a test has been carried out to solve the problem with ground granulated blast-furnace slag, low early strength & lack of supply and to find out a way to use as concrete admixture of the ultrafine blaine air cooling slag which is all disposed as the by product of air cooling slag and its test was conducted to the replacement rate of ultrafine blaine air cooling slag & mixing condition of every concrete admixtures by type for the purpose of obtaining later a basic data for practical use of the cement that used ultrafine blaine air cooling slag by conducting comparative analysis. If ultrafine-blaine air cooling slag is used to the concrete following the results, a high efficiency water reducing agent won't be needed much for flow acquisition due to a high increase in flow, and the stripping time of concrete form will be shortened thanks to the acquisition of early strength, And though, it has the problems with long term strength which is similar or a little lower than the 3 types of ground granulated blast-furnace slag, it's still applicable as the substitute materials for 3 types of ground granulated blast-furnace slag at 10, 15% replacement rate of ultrafine-blaine air cooling slag, at which it shows higher activation index than 3 types of ground granulated blast-furnace slag.

소셜 네트워크 서비스 어플리케이션의 클라우드 모델링 및 분석을 통한 국방 클라우드 컴퓨탱 시스템 설계 (K-Defense Cloud Computing System Design through Cloud Modeling and Analysis of Social Network Service Application)

  • 이성태;유황빈
    • 융합보안논문지
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    • 제13권1호
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    • pp.37-43
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    • 2013
  • 국방부는 지난 2010년, '2012 정보화사업계획'의 일환으로 2014년까지 클라우드 컴퓨팅 기술이 포함된 국방통합정보관리소(메가센터)를 구축하기로 결정하였고, 현재 추진 중에 있다 클라우드 컴퓨팅 환경은 데이터 센터에 많은 IT 자원이 집약된 형태로 효율적인 인프라구조를 위한 기술과 정책을 적용하여 시스템을 설계해야 한다. 즉, 사용자의 요구를 만족 시키기 위해 클라우드 서비스를 효율적으로 제공하여야 하며, 시스템 구축 시 불필요하게 낭비되는 자원이 없게 설계되어야 한다. 그러나 최적 시스템을 구축하기 위해서는 시스템 설계 최초단계에 서비스 성능과 자원 사용의 가용성을 예측할 수 있어야 한다. 본 논문에서는 국방 클라우드 컴퓨팅 시스템의 서비스 가용성 예측을 위해 CloudAnalyst 시뮬레이터를 이용하여 현재 전 세계에서 가장 많은 사용자를 보유한 소설 네트워크 서비스 중 하나인 Facebook을 클라우드 모델링 및 분석하였다. 시뮬레이션 결과를 통해 최적의 국방 클라우드 컴퓨팅 설계 모델을 제안한다.