• Title/Summary/Keyword: WAsP Engineering

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A Study of Heavy Metal-Contaminated Soil Remediation with a EDTA and Boric acid Composite(II): Cd and Cr (EDTA와 붕산 혼합용출제를 이용한 중금속으로 오염된 토양의 처리에 관한 연구(II): 카드뮴 및 크롬)

  • Lee Jong-Yeol;Kim Yong-Soo;Kwon Young-Ho;Kong Sung-Ho;Park Shin-Young;Lee Chang-Hwan;Sung Hae-Ryun
    • Journal of Soil and Groundwater Environment
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    • v.9 no.4
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    • pp.8-14
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    • 2004
  • To investigate the optimal operation factors in appling Soil Flushing Process, which use EDTA and boric acid composite as a flushing reagent, to the Cd(cadmium) and Cr(chromium) contaminated sites, Cd and Cr emediation rate was investigated at various experimental conditions; as EDTA concentration was increased from 0.001M to 0.1M, Cd remediation rate was increased from $73.2\%\;to\;98.5\%$; as boric acid concentration was increased from 0.001M to 0.1M, Cr remediation rate was increased from $59.2\%\;to\;99.0\%$. In the experiments using 0.005M of EDTA and 0.005M of boric acid composite as a flushing reagent at different pH regimes, Cd remediation rate was decreased from $92.4\%\;to;80.9\%$ as the pH was increased from 3 to 7. But Cr remediation rate was more effective ($70.4\%$) at pH 5 compared to the other pHs. Furthermore, at pH 5, Cd and Cr remediation rate was investigated at different molecular ratio of [EDTA]/[Boric aicd]; the optimized [EDTA]/[Boric acid] ratio was 0.01M/0.1M for Cd contaminated site and, as the concentration of boric acid was increased over 0.1M, Cr remediation rate was also increased. So the similar results were shown in the experiments using real contaminated soils which were sampled from a mining and a industrial area.

Continuous Nanocomposite Coatings on a Phosphor for the Enhancement of the Long-term Stability

  • Kim, Jong-Woung;Song, Jung-Oh;Kim, Chang-Keun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.233-233
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    • 2006
  • [ $Y_{2}O_{2}S:Eu$ ], a red phosphor, coated with silica nanoparticles or nanocomposites composed of silica nanoparticles and polymeric materials such as PMMA and PVP was prepared via sol-gel process. Samples were prepared from four different methods coded P1, P2, P3, and P4. P1 includes a conventional sol-gel process and a dip-coating method while P2 has the same procedure with P1 except that nanocomposites containing both silica nanoparticles and polymer prepared by sol-gel process were used as coating materials. In P3 method, phosphors were dispersed in a solution containing silica precursor, i.e., TEOS and then polymerization was performed to coat onto the phosphors surface while P4 followed the same procedure with P3 except that a solution containing both TEOS and organic monomer were used in preparing coating materials. Among various coating methods examined in this study, uniform coating of phosphor could be achieved by using method P4, i.e., phosphor surface coating in a solution containing hydrophobic monomer and TEOS. Furthermore, $Y_{2}O_{2}S:Eu$ red phosphor coated with nanocomposite composed of PMMA matrix and silica nanoparticles exhibited enhanced PL intensity and long-term stability.

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A Study on Characteristics of pH Control with Amines in the Secondary Side of Nuclear Power Plants (원전 2차 계통에서 아민의 pH 제어 특성 연구)

  • Rhee, In-H.;Ahn, Hyun-Kyoung;Park, Byung-Gi;Jun, Gwon-Hyuk;Ho, Song-Chan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.8
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    • pp.3112-3118
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    • 2010
  • The pH control agent in PWRs, to insure the integrity of steam generator, was changed from ammonia to ethanolamine(ETA) which decreased pH at condensate system and low pressure feedwater heater drain system, so that several amines were investigated for the selection of the optimum amine. There was no single alternative amine to meet the optimum condition. The more volatile ammonia provides the higher pH in condensate, while the less volatile ETA increases the pH in wet steam area. Thus, the combined amine of ammonia and ETA is able to equally raise the pH in both region so that the flow accelerated corrosion be reduced in the every system of the secondary side and the integrity of steam generator be also improved in pressurized water reactors (PWRs).

Construction of CpG Motif-enriched DNA Vaccine Plasmids for Enhanced Early Immune Response

  • Park Young Seoub;Hwang Seung Ha;Choi Cha-Yong
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.10 no.1
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    • pp.29-33
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    • 2005
  • A DNA vaccine methodology using eukaryote expression vectors to produce immunizing proteins in the vaccinated hosts is a novel approach to the development of vaccine and immuno-therapeutics, and it has achieved considerable success over several infectious diseases and various cancers. To further enhance its efficiency, attempts were made to develop novel plasmid vectors containing multiple immunostimulatory CpG motifs, for rapid and strong immune response. First, a 2.9 kb compact plasmid vector (pVAC), containing CMV promoter, polycloning site, BGH poly(A) terminator, ampicillin resistance gene and pBR322 origin was constructed. A pVAC-hEPO was also constructed, which contained a human erythropoietin gene, for evaluating the transfection efficiency of naked plasmid DNA both in vitro and in vivo. To examine the adjuvant effect of multi-CpG motifs on naked plasmid DNA, 22 and 44 enriched and unmethylated CpG motifs were introduced into pVAC to generate pVAC-ISS1 and pVAC-ISS2, respectively. $100{\mu}g$ of pSecTagB, pVAC, pVAC-ISS1 or pVAC-ISS2 were each injected intramuscularly into the tibilias anterior muscle of Balb/c mice. The level of interleukin-6 induced in the mice injected with pVAC-ISS1 and pVAC-ISS2 were significantly elevated after 12 hours, which were almost 2 and 2.5 times higher than that in the mice injected with pSecTagB, respectively. These results suggest that DNA vaccine plasmids with enriched CpG motifs can induce rapid secretion of interleukin-6 by lymphocytes. In conclusion, these vectors can contribute to the development of adjuvant-free DNA vaccinations against infectious diseases and various cancers.

Effect of Ethanol as a Dispersant and pH on the Particle Size and Phase Formation in the Synthesis of K+-β"-Al2O3 by Solution State Reaction (액상반응에 의한 K+-β"-Al2O3 합성시 분산첨가제 에탄올과 pH가 입도 및 상형성에 미치는 영향)

  • Cho, Do-Hyung;Kim, Woo-Sung;Shin, Jae-Ho;Lim, Sung-Ki
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.45-51
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    • 2005
  • $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$ in the $K_2O-Li_2O-Al_2O_3$ ternary system was synthesized using aluminum nitrate solution as a starting material. For the synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$, raw materials with chemical composition of $0.84K_2O{\cdot}0.082Li_2O{\cdot}5.2Al_2O_3$ were mixed in solution state. The effects of dispersant and solution-pH were investigated in minimizing the particle size and on the synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$. Ethanol was used for a dispersant, and $NH_4OH$ solution and nitric acid were added for pH adjustment. The solution pH was increased from 1.0 to 7.5 by 0.5 increments. Each sample was calcined at $1200^{\circ}C$ for 2 h and characterized with X-ray diffraction and particle size analyzer. The pH of solution significantly effected both particle size and phase formation, while the addition of ethanol only effected particle size. The synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$ was favored by addition of nitric acid (for pH control).

Preparation and Properties of ZnSe/Zn3P2 Heterojunction Formed by Surface Selenization of Zn3P2 Film Deposited on ZnTe Layer

  • Park, Kyu Charn;Cha, Eun Seok;Shin, Dong Hyeop;Ahn, Byung Tae;Kwon, HyukSang
    • Current Photovoltaic Research
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    • v.2 no.1
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    • pp.8-13
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    • 2014
  • ZnSe/$Zn_3P_2$ heterojunctions with a substrate configuration were fabricated using a series of cost-effective processes. Thin films of ZnTe and $Zn_3P_2$ were successively grown by close-spaced sublimation onto Mo-coated glass substrates. ZnSe layers thinner than 100nm were formed by annealing the $Zn_3P_2$ films in selenium vapor. Surface selenization generated a high density of micro-cracks which, along with voids, provided shunt paths and severely deteriorated the diode characteristics. Annealing the $Zn_3P_2$ film at $300^{\circ}C$ in a $ZnCl_2$ atmosphere before surface selenization produced a dense microstructure and prevented micro-crack generation. The mechanism of micro-crack generation by the selenization was described and the suppression effect of $ZnCl_2$ treatment on the micro-crack generation was explained. ZnSe/$Zn_3P_2$ heterojunctions with low leakage current ($J_0$ < $1{\mu}A/cm^2$) were obtained using an optimized surface selenization process with $ZnCl_2$ treatment. However, the series resistance was very high due to the presence of an electrical barrier between the ZnTe and $Zn_3P_2$ layers.

Structure and Regulation of a Complex Promoter Region from an Alkali-tolerent Bacillus sp.

  • Kim, Jin-Man;Park, Hee-Kyung;Park, Young-Seo;Yum, Do-Young;Bai, Dong-Hoon
    • Journal of Microbiology and Biotechnology
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    • v.3 no.3
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    • pp.146-155
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    • 1993
  • A DNA fragment from an alkali-tolerent Bacillus sp., conferring strong promoter activity, was subcloned into the promoter probe plasmid pPL703 and the nucleotide sequence of this promoter region was determined. The sequence analysis suggested that this highly efficient promoter region containing the complex clustered promoters comprised three kinds of promoters (P1, P2 and P3), which are transcribed by $\sigma^B (formerly \sigma^{37}), \sigma^E(formerly \sigma^{29}) and \sigma^A (formerly \sigma^{43})$ RNA polymerase holoenzymes which play major rules at the onset of endospore formation, during sporulation and at the vegetative phase of growth, respectively. S1 nuclease mapping experiments showed that all three promoters had staggered transcription initiation points. The results of chloramphenicol acetyltransferase assay after the subcloning experiments also indicated that the expression of these clustered promoters was correlated with the programs of growth and endospore development. Promoter P1, P2 and P3 were preceded by 75% AT, 79% AT and 81% AT regions, respectively, and a partial deletion of AT-rich region prevented transcription from promoter P1 in vivo. Two sets of 5 -AGTGTT-3 sequences and inverted repeat sequences located around the promoter P1 were speculated as the possible cis acting sites for the catabolite repression in B. subtilis. In vivo transcripts from these sequence regions may be able to form a secondary structure, however, the possibility that a regulatory protein induced by the excess amount of glucose could be bound to such a domain for crucial action remains to be determined.

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Improvement of Commercial Silicon Solar Cells with N+-P-N+ Structure using Halogenic Oxide Passivation

  • K. Chakrabarty;D. Mangalaraj;Kim, Kyung-Hae;Park, J.H.;J. Yi
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.6
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    • pp.17-20
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    • 2003
  • This paper describes the effect of halogenic gettering during oxide passivation of commercial solar cell with the $N^{+}$-P-$N^{+}$ structure. In order to study the effect of halogenic gettering on $N^{+}$-P-$N^{+}$ structure mono-crystalline silicon solar cell, we performed conventional POCl$_3$ diffusion for emitter formation and oxide passivation in the presence of HCl vapors. The $N^{+}$-P-$N^{+}$ structure based silicon solar cells were found to have higher short circuit current and minority carrier lifetime. Their performance was also found to be superior than the conventional $N^{+}$-P-$N^{+}$ structure based mono-crystalline silicon solar cell. The cell parameters of the $n^{+}$-p-$p^{+}$ and $n^{+}$-p-$n^{+}$ structure based cells, passivated by HCl assisted oxidation were measured. The improvement in $I_{sc}$ was attributed to the effect of the increased diffusion length of minority carriers, which came from the halogenic gettering effect during the growth of passivating oxide. The presence of chlorine caused gettering of the cells by removing the heavy metals, if any. The other advantage of the presence of chlorine was the removal of the diffusion induced (in oxygen environment) stacking faults and line defects from the surfaces of the silicon wafers. All these effects caused the improvement of the minority carrier lifetime, which in-turn helped to improve the quality of the solar cells.

Changes of Blood pH in Micro-circulation System on the Stimulated Time of Pulsed Magnetic Fields (펄스자기장 자극 시간에 따른 미세순환시스템 내에서 혈액의 pH변화)

  • Lee, Boram;Choi, Yukyung;Lee, Hyunsook
    • Journal of Biomedical Engineering Research
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    • v.43 no.4
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    • pp.214-218
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    • 2022
  • The purpose of this study was to investigate the role of the PMF in the treatment of acidosis and inflammation by monitoring the pH change for the continuity of PMF effect on the blood in the micro-circulation system that mimics the capillaries in the human body. Micro-tubes and micro-channels similar in diameter to those of arteries and arterioles were fabricated using PDMS and connected to a micro-pump for blood circulation. The continuity of PMF effect was verified in a micro-circulation system in-vitro. The pH changes for the circulating blood and for persistence time of PMF stimulus effect were confirmed using the optimized PMF conditions based on the previous studies. Also pH changes were observed by continuously stimulating PMF for a set period of time. The result was observed that the pH of the blood acidified using tBHP continued to rise from immediately after stimulation of PMF to 70 minutes of stimulation, reaching a normal pH range, and then decreasing. Our study showed that PMF has a positive effect on the control of blood pH homeostasis, so it is suggested the possibility of being used as a noninvasive treatment for acidosis treatment and anti- inflammatory treatment.

Quantitative Comparison of the E-book and Paper-book by using Eye-tracker

  • Kim, Jung-Yong;Lee, Min-Ho;Min, Seung-Nam;Cho, Young-Jin;Choi, Jun-Hyeok
    • Journal of the Ergonomics Society of Korea
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    • v.31 no.5
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    • pp.609-616
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    • 2012
  • Objective: The aim of the study is to evaluate the difference of legibility between e-book and paper-book by using eye-tracker. Background: Despite of many researches on the e-book and paper-book, there are few researches on the difference between e-book and paper-book. In addition, the researches on the e-book were only dependent on the e-book reader. This study focused on the comparison of e-book and paper-book controlled with the same environments. Method: This study was conducted with $2{\times}3$ within-subject design. Independent variables include the types of book (e-book, paper-book) and font sizes (8pt, 10pt, 12pt). Dependent variables are four measures of fixation duration, saccade length, blink rate and subjective discomfort. Analysis of Variance (ANOVA) with repeated measured design was used to investigate the main and interaction effects of independent variables on each of the dependent variables. The multiple comparisons were performed by post hoc analysis and Bonferroni correction was applied. Results: Fixation duration at e-book was longer than paper-book (p<0.01). Saccade length at e-book was shorter than paper-book (p<0.05). Blink rate at e-book was higher than paper-book (p<0.1). Subjective discomfort at e-book was higher than paper-book (p<0.1). Legibility at 8pt was better than 10pt, 12pt (p<0.01) in fixation duration, saccade length and subjective discomfort. Conclusion: It was found that the legibility at e-book are worse than paper-book from this study. These results indicated that the legibility of e-book was needed to be validated and improved to replace the paper-book. Application: This study suggests improving something related to fixation duration, saccade length, blink rate and subjective discomfort for betterment of e-book.