• 제목/요약/키워드: WAsP Engineering

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반응조의 물리적 인자와 알칼리도가 암모니아 탈기에 미치는 영향에 관한 연구 (Effect of the Physical Parameters and Alkalinity in the Ammonia Stripping)

  • 안주석;임지혜;백예지;정태영;정형근
    • 대한환경공학회지
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    • 제33권8호
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    • pp.583-590
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    • 2011
  • 공기 폭기법을 통해 암모니아를 제거함에 있어, 반응조의 물리적 인자(폭기 깊이, 공기 방울 크기, 표면적)와 알칼리도가 암모니아의 제거 속도에 미치는 영향을 평가하였다. 30 L/min의 공기를 6~53 cm의 폭기 깊이로 실험한 결과, 폭기 깊이는 암모니아 제거 속도에 영향을 미치지 않았다. pH가 10.0, 온도가 $30^{\circ}C$에서 암모니아의 제거 속도 상수와 표준편차는 각각 $0.175h^{-1}$, 0.004로 나타났다. 공기 방울의 크기 및 공기상과 접촉하는 수표면의 표면적은 제거 속도에 영향을 미치지 않았다. 폐수의 알칼리도는 암모니아 제거 속도에 간접적으로 영향을 미치는 것으로 나타났다. 이는 폭기에 의해 이산화탄소가 수용액에 용존되어 pH를 변화시킬 수 있기 때문인 것으로 예상된다. 매립지와 하수 종말 처리장에서 채취한 실제 폐수를 대상으로 암모니아 제거 속도를 살펴보았다. 하수 원수(pH = 7.1, alkalinity = 75 mg/L)의 경우, pH를 9.3으로 조절하여도 암모니아 제거 속도가 크게 증가하지 않았다. 그러나, 알칼리도가 높은 침출수 원수(pH = 8.0, alkalinity = 6,525 mg/L)는 초기 pH가 낮음에도 불구하고, 공기 폭기에 따른 pH 상승으로 인해 암모니아 제거 속도가 증가하는 경향을 나타냈다. 또한, 침출수 원수의 pH를 9.4로 조절한 경우, 하수 원수와 달리 공기 폭기에 따른 pH 저하가 나타나지 않아 암모니아 제거 속도가 유지 되었다.

복잡지형에서의 WAsP 예측성 평가 (An Assessment of WAsP Prediction in a Complex Terrain)

  • 경남호;윤정은;허종철;장동순
    • 한국태양에너지학회 논문집
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    • 제23권1호
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    • pp.39-47
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    • 2003
  • In order to test the predictability of the wind resource assessment computer code in our country a field experiment and prediction by WAsP has been compared. A field experiment has been performed in Songdang province, Jeju island, composed of sea, inland flat terrain, a high and a low slope craters. For this experiment, four meteorological towers have been installed at seashores, inland flat and on a crater. Wind resource at one site is predicted by WAsF with the meteorological data at the other three sites. The comparisons show that the WAsP preditions give better agreement with experimental data by adjusting the roughness descriptions.

복잡지형에서의 WAsP 예측성 향상 연구 (A Refinement of WAsP Prediction in a Complex Terrain)

  • 경남호;윤정은;장문석;장동순;허종철
    • 한국태양에너지학회 논문집
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    • 제23권4호
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    • pp.21-27
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    • 2003
  • The comparative performance of the WAsP in calculating the wind climate in complex terrain has been examined in order to test the predictability of the wind resource assessment computer code in our country. An analysis was carried out of predicted and experimental 10-min averaged wind data collected over 8 months at four monitoring sites in SongDang province, Jeju island, composed of sea, inland flat terrain, a high and a low slope craters. The comparisons show that the WAsP preditions give better agreement with experimental data by adjusting the roughness descriptions, the obstacle list.

RuO2를 양전극으로 사용한 무격막 전해셀에서의 이산화염소수 제조 (Preparation of Chlorine Dioxide Aqueous Solution by Un-divided Electrochemical Cell using RuO2 anode)

  • 권태옥;박보배;노현철;문일식
    • 공업화학
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    • 제20권3호
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    • pp.296-300
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    • 2009
  • $RuO_2/Ti$를 양전극으로 사용한 무격막 전해셀(un-divided electrochemical cell) 시스템에서의 이산화염소수($ClO_2$) 제조 연구를 수행하였다. 이산화염소의 전구체로는 아염소산나트륨($NaClO_2$)이 사용되었으며, 무격막 전해셀에서 전구체 용액의 전해셀 주입유량, 전구체 용액 초기 pH, 아염소산나트륨과 전해질인 염화나트륨의 주입농도 그리고 전류밀도(current density)가 생성된 이산화염소수의 농도 및 pH에 미치는 영향을 조사하였다. 생성된 이산화염소수의 농도와 pH는 초기 전구체 용액의 pH와 전해셀 주입유량에 큰 영향을 받는 것으로 나타났으며, 전해질로 사용된 염화나트륨은 전해질로서의 역할 뿐만 아니라 이산화염소의 전구체로도 작용함을 알 수 있었다. 이산화염소수 제조를 위한 무격막 전해셀에서의 전구체용액의 최적 주입유량은 90 mL/min, 전구체 용액의 초기 pH는 2.3, 아염소산나트륨 주입농도는 4.7 mM, 염화나트륨 주입농도는 100 mM 그리고 전류밀도는 $5A/dm^2$로 나타났으며, 이때 발생된 이산화염소수의 pH는 약 3, 이산화염소 농도는 약 350 mg/L이었다.

Molecular Structure of PCR Cloned PHA Synthase Genes of Pseudomonas putida KT2440 and Its Utilization for Medium-Chain Length Polyhydroxyalkanoate Production

  • Kim, Tae-Kwon;Shin, Hyun-Dong;Seo, Min-Cheol;Lee, Jin-Nam;Lee, Yong-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제13권2호
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    • pp.182-190
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    • 2003
  • A new phaC gene cluster encoding polyhydroxyalkanoate (PHA) synthase I PHA depolymerase, and PHA synthase II was cloned using the touchdown PCR method, from medium-chain length (mcl-) PHA-producing strain Pseudomonas putida KT2440. The molecular structure of the cloned phaCl gene was analyzed, and the phylogenic relationship was compared with other phaCl genes cloned from Pseudomonas species. The cloned phaCl gene was expressed in a recombinant E. coli to the similar level of PHA synthase in the parent strain P. putida KT2440, but no significant amount of mcl-PHA was accumulated. The isolated phaCl gene was re-introduced into the parent strain P. putida KT2440 to amplify the PHA synthase I activity, and the recombinant P. purida accumulated mcl-PHA more effectively, increasing from 26.6 to $43.5\%$. The monomer compositions of 3-hydroxylalkanoates in mcl-PHA were also modified significantly in the recombinant P. putida enforcing the cloned phaCl gene.

THE REMOVAL OF HEAVY METALS USING HYDROXYAPATITE

  • Lee, Chan-Ki;Kim, Hae-Suk;Kwon, Jae-Hyuk
    • Environmental Engineering Research
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    • 제10권5호
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    • pp.205-212
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    • 2005
  • The study was conducted to investigate the removal of heavy metals by using Hydroxyapatite(HAp) made from waste oyster shells and wastewater with high concentration of phosphorus. The maximum calcium concentration for the production of HAp in this study was released up to 361 mg/L at pH of 3 by elution experiments. When the pH was at adjusted 6, the maximum calcium released concentration was 41 mg/L. During the elution experiment, most of the calcium was released within 60 minutes. This reaction occurred at both pH levels of 3 and 6. The result of the XRD analysis for the HAp product used in this study shows the main constituent was HAp, as well as OCP. The pH was 8.6. As the temperature increased, the main constituent did not vary, however its structure was crystallized. When the pH was maintained at 3, the removal efficiency decreased as the heavy metal concentration increased. The order of removal efficiency was as follows: $Fe^{2+}$(92%), $Pb^{2+}$(92%) > $Cu^{2+}$(20%) > $Cd^{2+}$(0%). Most of these products were dissolved and did not produce sludge in the course of heavy metals removal. As the heavy metal concentration increased at pH of 6, the removal efficiency increased. The removal efficiencies in all heavy metals were over 80%. From the analysis of the sludge after reaction with heavy metals, the HAp was detected and the OCP peak was not observed. Moreover, lead ion was observed at the peaks of lead-Apatite and lead oxidant. In the case of cadmium, copper and iron ions, hydroxide forms of each ion were also detected.

단백질흡착을 막는 소프트콘택트렌즈에 관한 연구 (Study on protein adsorption resistant soft contact lens)

  • 정영일;조종수;나재운;김성호
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1996년도 춘계학술대회
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    • pp.223-225
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    • 1996
  • Poly (ethylene glycol) (PEG)macromers terminated with acrylate groups and interpenetrating polymer networks(IPN) composed of poly(hydroxyethyl methacrylate)(PHEMA) or poly(hydroxyethyl methacrylate-co-hydropropyl methacrylate-co-N-vinyl pyrrolidone) [P(HEMA-co-HPMA-co-NVP)] and PEG macromer were synthesized with the aim of obtaining protein adsorption resisatnt soft contact lens. Polymerization of PEG macromer resulted in the formation of cross-linked gels due to the multifunctionality of macromer. Crosslinked P(HEMA) or P(HEMA-co-HPMA-co-NVP) chains were interpenetrated into the cross-linked three-dimensional networks of PEG. It was found that albumin adsorption onto the contact lens prepared by P(HWMA)/PEG IPN decreases with a decrease of molecular weight of PEG whereas its adsorption onto the contact lens prepared by P(HEMA-co-HPMA-co-NVP)/PEG IPN decreases with an increase of molecular weight of PEG. Also, it was found that albumin adsorption onto the both contact lens decreases with an increase of concentration of PEG macromer in the IPN preparation. There are also more adequate in the bioinertness and bioadhesion for the contact lens by P(HEMA)/PEG IPN or P(HEMA-co-HPMA-co-NVP)/PEG IPN than that by P(HEMA) or P(HEMA-co-HPMA-co-NVP).

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TiO2 함량에 따르는 무전해 Ni-P-TiO2 복합도금층 특성 연구 (Characterization of the Morphology and Corrosion Resistance in Electroless Ni-P-TiO2 Composite Coating Prepared by TiO2 Contents)

  • 변영민;김호영;이재웅;황환일
    • 한국표면공학회지
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    • 제52권4호
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    • pp.187-193
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    • 2019
  • Electroless Ni-P coatings are widely used in the chemical, mechanical, and electronic industries because of their excellent wear and abrasion resistance. In this study, the effect of $TiO_2$ particles of composite coating was investigated. To improve the corrosion resistance, electroless $Ni-P-TiO_2$composite coating was studied by varying the $TiO_2$ content. The morphology and phase structure of $Ni-P-TiO_2$ composite coatings were analyzed by scanning electron microscopy(SEM), X-ray diffractometry(XRD) and X-ray photoelectron spectroscopy(XPS). The result showed that $Ni-P-TiO_2$composite coating is composed of Ni, P, Ti and O. It exhibits an amorphous structure, high hardness and good corrosion resistance to the substrate. $Ni-P-TiO_2$ composite coatings have higher open circuit potential than that of the substrate, which obtained at $TiO_2$ content of 5.0 g/L optimal integrated properties.

Al 함량이 다른 PAC를 이용한 응집 조건 별 인 제거효율 평가 (Evaluation of Phosphorus Removal Efficiency at Various Coagulation Conditions Using Polyaluminum Chloride with Different Al Contents)

  • 최정학;윤건곤;이창한
    • 한국환경과학회지
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    • 제32권10호
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    • pp.731-739
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    • 2023
  • In this study, lab-scale phosphorus coagulation/precipitation experiments were performed using three types of polyaluminum chloride (PAC) with different Al contents (10%, 12%, and 17%). The PO4-P removal efficiencies at various operating conditions, such as initial PO4-P concentration, initial pH, and Al/P molar ratio, were evaluated, and correlations among the operating factors affecting phosphorus coagulation/precipitation with PAC were derived to optimize the process efficiency. When the initial PO4-P concentration was 0.065 and 0.161 mmol P/L under an initial pH of 8-10, the optimal PAC dose was 0.126-0.378 and 0.189-0.667 mmol Al/L, respectively. Under these conditions, the Al/P molar ratio was 2.16-6.18 and 1.28-4.30, respectively, and the PO4-P removal efficiency was in the range of 40.2-92.5%. When the Al/P molar ratio was 2 or less under an initial pH condition of 6-8, the PO4-P removal efficiency was approximately ≤40% owing to insufficient Al3+ ions. However, when the Al/P molar ratio is 3-5, the PO4-P removal efficiency improved to approximately 80-90%. Thus, the optimal Al/P molar ratio to achieve a PO4-P removal efficiency of over 90% was determined to be approximately 4 in the PO4-P coagulation/precipitation process using PAC.

지압과 온열의 조합마사지가 인체의 스트레스 완화에 미치는 영향 평가 (Effects of Combined Stimulus on Stress Relief)

  • 이대원;박지형;엄시내;김도원;조승현;고창용;김한성
    • 대한의용생체공학회:의공학회지
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    • 제33권4호
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    • pp.194-201
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    • 2012
  • This study was designed to investigate the effect of a combined stimulus which was composed of chiropractic massage and thermotherapy on the relief of mental and physical stress. Fifteen healthy male subjects were treated with three type of stimuli; control (without any stimulus), a single stimulus (only chiropractic) and a combined stimulus. To evaluate the effects of stimuli, visual analogue scale (VAS), trunk extension, electromyogram (EMG) on erector spinae muscle and electrocardiogram (ECG) were measured and analyzed before and after stimuli. In the control group, there were no significant changes in EMG root mean square (RMS) value and low Frequency/high Frequency (LF/HF) ratio (p > 0.05, p > 0.05). However, both stimulus groups showed significant increases in trunk extension and EMG RMS values (p < 0.05, p < 0.05), but significant decreases in LF/HF ratios (p < 0.05). Particularly the decrement rate in LF/HF ratio was significantly higher in the combined stimulus group than that in the single stimulus group (p < 0.05). Also, a significantly lower VAS was recorded after combined stimulus. Our findings indicate that the combined stimulus might not only improve flexibility and strength of muscle, but also active parasympathetic nerve activity. The combined stimulus may thus contribute to relieve the stress and to enhance the muscle function.