• Title/Summary/Keyword: W-modification

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Effects of Atmospheric Pressure Microwave Plasma on Surface of SUS304 Stainless Steel

  • Shin, H.K.;Kwon, H.C.;Kang, S.K.;Kim, H.Y.;Lee, J.K.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.268-268
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    • 2012
  • Atmospheric pressure microwave induced plasmas are used to excite and ionize chemical species for elemental analysis, for plasma reforming, and for plasma surface treatment. Microwave plasma differs significantly from other plasmas and has several interesting properties. For example, the electron density is higher in microwave plasma than in radio-frequency (RF) or direct current (DC) plasma. Several types of radical species with high density are generated under high electron density, so the reactivity of microwave plasma is expected to be very high [1]. Therefore, useful applications of atmospheric pressure microwave plasmas are expected. The surface characteristics of SUS304 stainless steel are investigated before and after surface modification by microwave plasma under atmospheric pressure conditions. The plasma device was operated by power sources with microwave frequency. We used a device based on a coaxial transmission line resonator (CTLR). The atmospheric pressure plasma jet (APPJ) in the case of microwave frequency (880 MHz) used Ar as plasma gas [2]. Typical microwave Pw was 3-10 W. To determine the optimal processing conditions, the surface treatment experiments were performed using various values of Pw (3-10 W), treatment time (5-120 s), and ratios of mixture gas (hydrogen peroxide). Torch-to-sample distance was fixed at the plasma edge point. Plasma treatment of a stainless steel plate significantly affected the wettability, contact angle (CA), and free energy (mJ/$m^2$) of the SUS304 surface. CA and ${\gamma}$ were analyzed. The optimal surface modification parameters to modify were a power of 10 W, a treatment time of 45 s, and a hydrogen peroxide content of 0.6 wt% [3]. Under these processing conditions, a CA of just $9.8^{\circ}$ was obtained. As CA decreased, wettability increased; i.e. the surface changed from hydrophobic to hydrophilic. From these results, 10 W power and 45 s treatment time are the best values to minimize CA and maximize ${\gamma}$.

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Underwater Stability of Surface Chemically Modified Superhydrophobic W18O49 Nanowire Arrays

  • Lee, Junghan;Yong, Kijung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.601-601
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    • 2013
  • Superhydrophobic W18O49 nanowire (NW) arrays were synthesizedusing a thermal evaporation and surface chemistry modification methods by self-assembled monolayer (SAM). As-prepared non-wetting W18O49 NWs surface shows water contact angle of $163.2^{\circ}$ and has reliable stability in underwater conditions. Hence the superhydrophobic W18O49 NWs surface exhibits silvery surface by total reflection of water layer and air interlayer. The stability analysus of underwater superhydrophobicity of W18O49 NWs arrays was conducted by changing hydrostatic pressure and surface energy of W18O49 NWs arrays. The stability of superhydrophobicity in underwater conditions decreased exponentially as hydrostatic pressure applied to the substrates increased3. In addition, as surface energy decreased, the underwater stability of superhydrophobic surface increased sharply. Specifically, sueprhydrophobic stability increased exponentially as surface energy of W18O49 NWs arrays was decreased. Based on these results, the models for explaining tendencies of superhydrophobic stability underwater resulting from hydrostatic pressure and surface energy were designed. The combination of fugacity and Laplace pressure explained this exponential decay of stability according to hydrostatic pressure and surface energy. This study on fabrication and modeling of underwater stability of superhydrophobic W18O49 NW arrays will help in designing highly stable superhydrophobic surfaces and broadening fields of superhydrophobic applications even submerged underwater.

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A Modification Technique of Finite Element Model for Dynamic Analysis under Multiple Support Excitations (다지지점 가진에 대한 동적해석을 위한 유한요소모형의 수정기법)

  • 김재민
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.12 no.3
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    • pp.437-445
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    • 1999
  • This paper presents a simple modification technique of finite element model for dynamic analysis of linear/nonlinear structural system subjected to multiple support excitation. For the sake of verification of the proposed method, dynamic responses obtained by the present technique for a couple of linear and nonlinear structural systems were compared with those by a general-purpose structural analysis software which can deal with the multi-support analysis. The method presented in this paper is expected to be used for multiple support excitation analysis by means of a computer code without the capability of modeling the non-synchronous support motion.

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A Modification of the Shapiro-Wilk Test for Exponentiality Based on Censored Data (중도절단자료에 대한 수정된 SHAPIRO-WILK 지수 검정)

  • Kim, Nam-Hyun
    • The Korean Journal of Applied Statistics
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    • v.21 no.2
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    • pp.265-273
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    • 2008
  • Kim (2001a) presented a modification of the Shapiro and Wilk (1972) test for exponentiality based on the ratio of two asymptotically efficient estimates of scale. In this paper we modify this test statistic when the sample is censored. We use the normalized spacings based on the sample data, which was used in Samanta and Schwarz (1988) to modify the Shapiro and Wilk (1972) statistic to the censored data. As a result the modified statistics have the same null distribution as the uncensored case with a corresponding reduction in sample size. Through a simulation study it is found that the proposed statistic has higher power than Samanta and Schwarz (1988) statistic especially for the alternatives with the coefficient of variation greater than or equal to 1.

A Study on the Plasma Enhanced Hot-wire CVD Grown Miorocrystalline Silicon Films for Photovoltaic Device Applications (태양전지 응용을 위한 플라즈마 열선 화학기상증착법으로 성장한 미세결정 실리콘에 관한 연구)

  • 유진수;임동건;고재경;박중현;이준신
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.632-635
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    • 2001
  • Microcrystalline Si films have been deposited by using five W-wire filaments of 0.5 mm diameter for hot-wire chemical vapor deposition (HWCVD). We compared the HWCVD grown films with the film exposed to transformer couple plasma system for the modification of seed layer. W-wire filament temperature was maintained below 1600$^{\circ}C$ to avoid metal contamination by thermal evaporation at the filament. Deposition conditions were varied with H$_2$dilution ratio, with and without plasma treatment. From the Raman spectra analysis, we observed that the film crystallization was strongly influenced by the H$_2$dilution ratio and weakly depended on the distance between the wire and a substrate. We were able to achieve the crystalline volume fraction of about 70% with an SiH$_4$/H$_2$ratio of 1.3%, a wire temperature of 1514$^{\circ}C$, a substrate separation distance of 4cm, and a chamber pressure of 38 mTorr. We investigated the influence of ${\mu}$c-Si film properties by using a plasma treatment. This article also deals with the influence of the H$_2$dilution ratio in crystallization modification.

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Full Bridge Resonant Inverter Using Asymmetrical Control with Resonant-frequency Tracking for Ultrasonic Cleaning Applications

  • Jittakort, Jirapong;Sangswang, Anawach;Naetiladdanon, Sumate;Koompai, Chayant;Chudjuarjeen, Saichol
    • Journal of Power Electronics
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    • v.17 no.5
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    • pp.1150-1159
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    • 2017
  • Flexibility in the power control of ultrasonic transducers has remained a challenge for cleaning applications. This paper introduces a modification of the existing piezoelectric ceramic transducer (PCT) circuit to increase the range of operation through its impedance characteristics. The output power is controlled using the asymmetrical voltage-cancellation (AVC) method. Together with a phase-locked loop control, the switching frequency of the inverter is automatically adjusted to maintain a lagging phase angle under load-parameter variations during the cleaning process. With the proposed modification, the region of the zero-voltage switching (ZVS) operation is extended, which results in a wider range of output power control. A hardware prototype is constructed and the control algorithm is implemented using an STM32F4 microcontroller. Simulation and experimental results are provided to verify the proposed method for a 50-W PCT. The operating frequency and output power ranges under study are 37 - 41 kHz and 15.8 - 50 W, respectively.

Process Design and Finite Element Analysis of Rectangular Cup used for Ni-MH Battery with High Aspect Ratio (니켈-수소 2차 전지용 고세장비의 직사각 컵에 대한 성형공정 설계 및 유한요소해석)

  • Ku, T.W.;Kim, H.Y.;Song, W.J.;Kang, B.S.
    • Transactions of Materials Processing
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    • v.17 no.3
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    • pp.170-181
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    • 2008
  • The shape of rectangular cup used for Ni-MH(Nickel-coated Metal Hydrogen) battery for hybrid car looks quite simple, but the forming process of extruding and setting up process design are highly difficult. Furthermore, there are few concrete reports on the rectangular deep drawn cup as part of hybrid vehicles till now. In this study, process design for rectangular cup in the multi-stage deep drawing process is carried out, and FE analysis is also preformed based on the result of the process design. From the simulation result, some unexpected problems such as earing, wrinkling and excessive thickness changes of the intermediate blank occurred. To overcome these failures, a series of modification for punch shape in the forming process design are completed and applied. Considering the modified punch shape in the multi-stage deep drawing process, additional FE analysis is also carried out and the simulation result is verified in view of the deformed shape, thickness change and effective strain distribution. The result of FE analysis with the improved process design confirmed not only reducing thinning of wall and possibilities of failure but also improving the quality of drawing product through the modification of punch shape.

A Study on Tooth Profile Modification of Planetary Reducer for 120kW Class Monorail (120kW급 모노레일용 유성기어감속기의 치형수정에 관한 연구)

  • Jeong, Yeong-Sik;Kim, Nam-Kyung;Xu, Zhezhu;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.6
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    • pp.195-200
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    • 2012
  • In this study, parameters and requirements of an 120kW class monorail planetary gearbox was analysed and the adaptive planetary gearbox design was selected. The specification of the sun gear, planetary gear and carrier was set and the profile & lead was optimized. The mechanical efficiency of the optimized one and the original one was observed. Dynamo-tester system was used to observe the mechanical efficiency of the planetary gearbox. A dynamo unit was connected with the planetary gearbox which straightened through the motor by a coupling. The standard tooth shape planetary gearbox and modified tooth shape planetary gearbox were used as test pieces and the rotation speed was set from 600 to 6000rpm with 600rpm, 2.5min one step. In order to check the mechanical efficiency of the planetary gearbox, the tests were done as follows. 1) The power loss between driving motor and dynamo tester. 2) Temperature variation by different rotation speeds. 3) Noise variation by different rotation speeds.

Effect of Surface-Modification of Activated Carbon for Adsorption of Uranium in Radioactive Liquid Wastes (방사성 액체 폐기물 내 우라늄 흡착에 대한 활성탄의 표면 처리 영향)

  • Jang, J.D.;Lee, K.W.;Song, K.C.;Kang, H.;Oh, W.Z.
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.827-835
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    • 2000
  • Adsorption characteristics of uranium on activated carbon whose surface is modified with $HNO_3$ and/or NaOH were investigated. Na-OAC, which was the activated carbon treated with both $HNO_3$ and NaOH. showed higher adsorption capacity than OAC, which was treated with $HNO_3$, as well as Na-AC, which was treated with only NaOH. This can be explained based on the surface functional groups increased by surface modification of activated carbon and the change of solution pH as adsorption proceeds. From these experimental results, it is thought that the pH of uranium solution and surface functional groups on the activated carbon surface are the governing factors in the uranium adsorption system.

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