• Title/Summary/Keyword: W-modification

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Preferential face coating of knitted PET fabrics via UV curing for water- and oil-repellent finish (자외선 경화에 의한 PET 니트직물의 편면 발수발유 가공)

  • Jeong, Yong-Kyun;Jeong, Yongjin;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.17 no.6 s.85
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    • pp.27-35
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    • 2005
  • Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

A Study of the Silicon Mold Surface Treatment Using CHF3 Plasma for Nano Imprint Lithography (나노임프린트 리소그래피 적용을 위한 CHF3 플라즈마를 이용한 실리콘 몰드 표면 처리 특성)

  • Kim, Young-Keun;Kim, Jae-Hyun;You, Ban-Seok;Jang, Ji-Su;Kwon, Kwang-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.790-793
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    • 2011
  • In this study, the surface modification for a silicon(Si) mold using $CHF_3$ inductively coupled plasma(ICP). The conditions under that plasma was treated a input ICP power 600 W, an operating gas pressure of 10 mTorr and plasma exposure time of 30 sec. The Si mold surface became hydrophobic after plasma treatment in order to $CF_x$(X= 1,2,3) polymer. However, as the de-molding process repeated, it was investigated that the contact angle of Si surface was decreased. So, we attempted to investigate the degradation mechanism of the accurate pattern transfer with increasing the count of the de-molding process using scanning electron microscope (SEM), contact angle, and x-ray photoelectron spectroscopy (XPS) analysis of Si mold surface.

Enhanced Photocatalytic Disinfection Efficiency through TiO2/WO3 Composite Synthesis and Heat Treatment Optimization

  • Sang-Hee Kim;Seo-Hee Kim;Jun Kang;Myeong-Hoon Lee;Yong-Sup Yun
    • Journal of the Korean institute of surface engineering
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    • v.57 no.3
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    • pp.179-191
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    • 2024
  • This study focuses on improving the photocatalytic degradation efficiency by synthesizing a TiO2/WO3 composite. Given the environmental significance of photocatalysis and the limitations posed by TiO2's large bandgap and high electron recombination rate, we explored doping, surface modification, and synthesis strategies. The composite was created using a ball mill process and heat treatment, analyzed with field emission scanning electron microscope, high resolution X-ray diffraction, Raman microscope, and UV-Vis/NIR spectrometer to examine its morphology, composition and absorbance. We found that incorporating WO3 into the TiO2 lattice forms a Wx-Ti1-x-O2 solution, with optimal WO3 content reducing the band gap and enhancing sterilization efficiency by inhibiting the anatasese to rutile transition. This contributes to the field by offering a way to overcome TiO2's limitations and improve photocatalytic performance.

A study on A-pillar & wiper wind noise estimation using response surface methodology at design stage (반응면 기법을 이용한 A필라/와이퍼 풍절음 예측 연구)

  • Rim, Sungnam;Shin, Seongryong;Shin, Hyunsu
    • The Journal of the Acoustical Society of Korea
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    • v.37 no.5
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    • pp.292-299
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    • 2018
  • The vehicle exterior design is the main parameter of aerodynamic wind noise, but the modification of it is nearly impossible at a proto-type stage. Therefore, it is very important to verify exterior design and estimate the correct wind noise level at the early vehicle design stages. The numerical simulations of aerodynamic wind noises around A-pillar and wiper were developed for specific vehicle exterior designs, but could not be directly used for the discussions with designers because these need complex modeling and simulation process. This study proposes new approach to A-pillar and wiper wind noise estimation at design stage using response surface methodology of modeFRONTIER, of which database is composed of PowerFLOW simulation, PowerCLAY modeling, SEA-Baced (Statistical Energy Analysis-Based) interior noise simulation, and turbulent acoustic power simulation. New design parameters are defined and their contributions are analyzed. A state-of-the-art, easy and reliable CAT (Computer Aided Test) tool for A-pillar and wiper wind noise are acquired from this study, which shows high usefulness in car development.

Preparation of Wall Paper Coated with Modified TiO2 and Their Photocatalytic Effects for Removal of NO in Air (변조된 TiO2 광촉매를 이용한 벽지제조와 대기 중의 NO 제거 효과)

  • Kwon, Tae-Ri;Roo, Wan-Ho;Lee, Chul-Woo;Lee, Won-Mook
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.1-8
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    • 2005
  • In this study, $TiO_2$ powders were prepared by hydro-thermal synthesis with titanium tetra isopropoxide. The prepared $TiO_2$ and the commercial $TiO_2$(P-25, Degussa) were by impregnating $H_2PtCl_6$ solution or the leached solution from the waste catalytic converter of automobile. Modified photocatalysts were analyzed by ICP-AES, UV-DRS, XRD, SEM. And band-gap energy of modified photo-catalyst was found to decreased to 1.76eV and basic structure was changed upon modification by leached solution. Modified photocatalysts were coated on the wallpaper after using mixed solution with adhesive materials(PVC). And then to know the modified photo catalysts tested the reactivity and quantum efficiency in the mixed gas with NO as reactants in the photo catalytic reactor. In the gas phase, photo-catalytic activity of NO was the highest for modified P-25 catalysts(P-25(w)) that P-25(w) was impregnated by leached solution of wasted catalytic converter.

Characterizations of Water-dispersed Biocellulose Nanofibers on the Skin Surface (피부 표면에서의 수분산 바이오셀룰로오스 미세섬유의 특성에 대한 연구)

  • Jun, Seung-Hyun;Kim, Seo Yeon;Park, Sun Gyoo;Lee, Cheon Koo;Lee, Seol-Hoon;Kang, Nae-Gyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.1
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    • pp.89-94
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    • 2018
  • In this study, water-dispersed biocellulose nanofibers (TC) were prepared via an oxidation reaction using 2,2,6,6-tetramethyl-1-piperidine-N-oxy radical (TEMPO) as a catalyst. The TC retained their unique structure in water as well as in emulsion. TC adhered to the skin surface while maintaining nanofibrous structures, providing inherent functions of biocellulose, such as high tensile strength and high water-holding capacity. When gelatin gels as model skin were coated with TC, the hardness representing the elasticity was increased by 20% compared to untreated gelatin gel because TC could tightly hold the gelatin structure. When porcine skin was treated with TC and TC-contained O/W emulsion, the initial water contact angles of TC were lower than other materials, and dramatically decreased over time as water penetrated the fibrous structure of the TC film. Characterization of TC on the skin surface offered insight into the function of nanofibers on the skin, which is important for their applications with respect to fiber-cosmetics.

Cavitation Suppression Effects by the Modification of the Spectral Characteristics of High Intensity Focused Ultrasound (고강도 집속형 초음파의 주파수 성분 특성에 따른 공동 현상 억제 효과)

  • 최민주
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.5
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    • pp.68-77
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    • 1999
  • The paper looked into the effects of the spectral properties (waveform) of the high intensity focused ultrasound on suppression of the ultrasonic cavitation. Three different types of ultrasound were considered in the study, which were sinusoidal (1 MHz, 5 MPa), frequency modulated (from 1 MHz to 6 MHz for 10 ㎲, 5 MPa), asymmetrically shocked (fundamental frequency 1 MHz, peak positive pressure 12 MPa, peak negative pressure -4 MPa). The temporal response of an air bubble in water initially 1 ㎛ in radius to each type of the ultrasound was predicted using Gilmore bubble dynamic model and Church's rectified gas diffusion equation. It was shown that the radially pulsating amplitude of the bubble was greatly reduced for the frequency modulated wave and was little decreased for the shock wave, compared to the case that the bubble was exposed to the sinusoidal wave. It is interesting that the bubble response to the frequency modulated wave remains similar when the frequency component of the modulated ultrasound is beyond the bubble resonant frequency 3 MHz. This implies that, although the ultrasound is modulated up to 3MHz rather than up to the present 6 MHz, it is likely to produce similar cavitation suppression effects. In practice, it means that a typical narrow band ultrasonic transducer can be taken to generate an appropriate frequency modulated ultrasound to reduce cavitation activity. The present study indicates that ultrasonic cavitation may be suppressed to some extent by a proper spectral modification of high intensity ultrasound.

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High temperature oxidation behavior and surface modification of Ni-based superalloys (니켈기 초합금의 고온산화거동과 표면개질에 관한 연구)

  • Seol, Gyeong-Won
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.166-176
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    • 1994
  • Ni base superalloys are composed of solid sohltion hardening elements(Co, Cr. Mo. W and so on) and $\gamma '$ precipitation hardening elements(A1, Ti, Nb, Ta and so on). To Improve the mechanical properties and oxidation resistanre of superalloys, rare earth elements(%r, Hf, Y and so on) are added to the inner substrate, or are used as coating materials. Their pffects on the growth rate and adhes~on of oxide are changed according to the kinds of oxides such as $AI_2O_3$ and $Cr_2O_3$. The effect of yttrium on the oxidation rate, grain size of oxide, internal structure, and crack resistance was investigated for two kinds of Ni-base superalloys. One in AF'115 superalloy containing Hf and the other is MA6000 superalloy containing $Y_2O_3$. They werr owid~zed at high temperature after yttrium surface modification using ion coater. Yttrium coating on the AF115 and MA6000 superalloys results in a marked change in the growth of the inner oxide. For AF115 superalloy, the degree of gram boundary segregation of $Cr_2O_3$, and prefer en^ tial oxidation of Hf are decreased, and the shape of inner oxidation layer was changed from triangle to plate type. For MA6000 superalloy, $Cr_2O_3$ oxide scale was transformed as outer oxidation layer of CrZOI and inner oxidation layer of $Cr_2O_3$.

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A Study on Acceptance and Modification in Yulgok Neo-Confucianism by Myungjae Yoon Jeung (명재 윤증의 율곡성리학의 수용과 변전(變轉))

  • Lee, Young-Ja
    • The Journal of Korean Philosophical History
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    • no.42
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    • pp.39-70
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    • 2014
  • Neo-Confucianism of Myungjae Yoon Jeung either accepted Yulgok Neo-Confucianism as it was or modified it. In this study, his Neo-Confucianism was divided into acceptance and modification in Yulgok Neo-Confucianism and examined. In the acceptance of Yulgok Neo-Confucianism, it was clarified that Neo-Confucianism of Myungjae Yoon Jeung thoroughly inherited characteristics of Yulgok Neo-Confucianism, including 'Yiguijimyo', 'Yitongguiguk' and 'Guibalyiseungildo'. However, Myungjae was not just satisfied with inheriting Yulgok Neo-Confucianism as it was, but modified and inherited the theory of Yulgok by suggesting his own original preaching. There were three original preaching of his in overall; 'emphasis on the control of Li', 'argument method on a theory of gaining knowledge by the study of things', and 'perception on moral mind, human mind and human desire'. Ultimately, it is concluded that Myungjae modified, inherited and developed Yulgok Neo-Confucianism to adjust a theory of Neo-Confucianism in a position of 'Yiguijimyo', based on 'a theory of Guibalyiseungildo' of Yulgok as a Confucian scholar of Giho school. It is consistent with his life philosophy that he avoided speculative arguments on Neo-Confucianism and pursued solid study(實工) with solid mind(實心). It is also consistent with his view of learning that he believed that theories of ancient sages were already rich that we should read them and practice their true knowledge(眞知), and making an effort on writing regardless of them was not a study of Mushil(務實). However, due to his younger students, he was classified as a scholar who emphasized the control of 'Li' the most in Yulgok school, and a new academic tie of Giho Soron was created. It is the most important significance that Neo-Confucianism of Myungjae has in that of Giho.

A Study on the Integrated Computer Program for the Multi Analysis of In-Situ Aquifer and Geothermal Response Test (현장 열응답시험과 현장 대수성시험결과를 동시 분석 가능한 통합전산 Program에 관한 연구)

  • Hahn, Jeong-Sang;Han, Hyuk-Sang;Yonn, Yun-Sang
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.4 no.1
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    • pp.11-19
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    • 2008
  • Groundwater flow in confined aquifer and heat transport in underground geologic media are using same governing equation(line source) like well fuction. Therefore the conventional slope method using only later data obtained from in-situ thermal response test to determine the thermal conductivity of vertical geothermal heat exchanger(GHEX) is basically identical with one of Theis straight line method of aquifer test under artesian condition. In case that the pumping rate(Q, $m^3$/d) and drawdown(s,m) which are used for input data of existing hydrogeologic computer programs for aquifer test are replaced and converted to supplying heat energy per unit length of bore hole(Q/L,w/m or Kcal/h.m) and temperatures (T,$^{\circ}C$)measured at in and out-let of GHEX as in put data respectively, thermal conductivity around geothermal heat exchanger can be easily estimated without any special modification of the existing hydrogeologic computer program. Two numbers of time series temperature variation data obtained from in situ geothermal response test are analized using Theismethods(standard curve and straight line method) by using existing aquifer test program and conventional Slope method proposed by ASHRAE. The results show that thermal conductivity values estimated by two straight methods are identical and the difference of estimated values between standard curve methods and Slope method are also within acceptable ranges. In general,the thermal conductivity estimated from Theis straight linemethod gives more accurate value than the one of Slope method due to that Slope method uses only visual matching otherwise Theis method uses automatic curve matching estimation with reducing RSS.

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