• Title/Summary/Keyword: Volumetric capacity

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Electrochemical Performance of Hybrid (Activated Carbon+LiCoO2) Electrode (하이브리드 (활성탄소+LiCoO2) 전극의 전기화학적 특성)

  • Kim, Ick-Jun;Jeon, Min-Je;Yang, Sun-Hye;Kim, Hyun-Soo;Moon, Sung-In;Oh, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.9
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    • pp.849-854
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    • 2006
  • In this study, the hybrid electrodes, composed of the activated carbon powders and $LiCoO_{2}$ powders, were prepared as a cathode for the high-capacitance type hybrid capacitor, and the electrochemical properties of the hybrid electrodes were examined in terms of the weight composition and the milling time of $LiCoO_{2}$ powders. The specific volumetric capacities were increased with increasing of the composition of $LiCoO_{2}$ powders in the hybrid electrodes. On the other hand the coin cell capacitors, using the hybrid electrodes with $LiCoO_{2}$ poweders milled for 200 h, have exhibited the lower internal resistivities and the better capacity retention after 100 charge-discharge cycle than those of the coin cell capacitors using the hybrid electrodes with raw $LiCoO_{2}$ powders.

Thermodynamic Properties of Alternatives for R12, R22 and Performances of Refrigerator (R12 및 R22대체냉매의 열역학적 물성치 및 냉동기의 성능비교)

  • Chang, S.D.;Shin, J.Y.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.73-83
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    • 1993
  • Thermodynamic properties of alternatives for R12 and R22 were estimated and performances of refrigerating cycle using these refrigerants were compared. In this study, we adopt R134a, R22/R142b, R22/R152a, R22/R152a/R124 as alternatives for R12 and R32/R134a for R22. Thermodynamic properties of these refrigerants were estimated using modified CSD equation of state. Cycle simulations of the refrigerating system considering heat source were carried out in order to compare the performance of the system. R134a shows relatively lower COP than R12 but very similar VCR. R22/R142b(50/50 mass fraction), R22/R152a(10/90), R22/R152a/R124(30/25/45) are good for the substitutes of R12 and R32/R134a(30/70) is appropriate for that of R22 in view of COP and VCR.

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Synthesis of Li2PtO3 Thin Film Electrode by an Electrostatic Spray Deposition Technique

  • Oh, Heung-Min;Kim, Ji-Young;Lee, Kyung-Keun;Chung, Kyung-Yoon;Kim, Kwang-Bum
    • Journal of Electrochemical Science and Technology
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    • v.1 no.1
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    • pp.45-49
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    • 2010
  • $Li_2PtO_3$ thin film electrodes, which might be possible candidate for the cathode materials for implantable batteries, were synthesized using an electrostatic spray deposition (ESD) technique onto a platinum foil substrate. Single phase $Li_2PtO_3$with a structure similar to layered $LiCoO_2$ structure were synthesized by spraying a precursor solution of $CH_3CO_2Li2H_2O$ in ethanol onto a Pt substrate at temperatures ranging from 200 to $400^{\circ}C$ followed by annealing at above $600^{\circ}C$. Lithium carbonate was the only major phase at temperatures up to $500^{\circ}C$. The X-ray diffraction (XRD) peaks of the Pt foil substrate and lithium carbonate disappeared at temperatures >$600^{\circ}C$. The volumetric capacity of the $Li_2PtO_3$ thin film synthesized using the ESD technique was approximately 817 mAh/$cm^3$, which exceeded that of $LiCoO_2$ (711 mAh/$cm^3$).

Alternatives to Enhance Flat Slab Ductility

  • Husain, Mohamed;Eisa, Ahmed S.;Roshdy, Ramy
    • International Journal of Concrete Structures and Materials
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    • v.11 no.1
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    • pp.161-169
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    • 2017
  • Flat slab systems are vastly used in multi-story buildings because of their savings in story height and construction time, as well as for their flexibility in architectural remodeling. However, they frequently suffer brittle punching-shear failure around columns, especially when subjected to lateral loads. Therefore, seismic codes labeled flat slabs as non-ductile systems. This research goal is investigating some construction alternatives to enhance flat slab ductility and deformability. The alternatives are: adding different types of punching-shear reinforcement, using discreet fibers in concrete mixes, and increasing thickness of slab around columns. The experimental study included preparation and testing of seven half-scale interior slab-column connections up to failure. The first specimen is considered a reference, the second two specimens made of concrete mixes with different volumetric ratios of polymer fibers. Another three specimens reinforced with different types of punching-shear reinforcement, and the last specimen constructed with drop panel of inverted pyramidal shape. It is found that using the inverted pyramid-shape drop panel of specimen, increases the punching-shear capacity, and the initial and the post-cracking stiffnesses. The initial elastic stiffnesses are different for all specimens especially for the slab with closed stirrups where it is experienced the highest initial stiffness compared to the reference slab.

Calculation of the Thermodynamic Properties of R-134a and A Preliminary Study of the Refrigeration Performance (R-134a의 열역학적 물성치 계산과 냉동 성능에 관한 연구)

  • Park, Y.M.;Lee, H.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.4
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    • pp.286-296
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    • 1991
  • The thermodynamic properties of R134a, the prospective R12 alternative, have been computerized using Martin-Hou equation of state and the coefficients given by Willson-Basu. Several experimental results in literatures for PVT data, saturated vapor pressure, saturated liquid density are compared with the calculated results to investigate the accuracy. The average deviation (max. deviation) is 0.13% (0.25%) for saturated liquid density, 0.25% (0.8%) for PVT data. Thermodynamic properties, enthalpy, entropy are compared with the NIST's. The maximum percent difference is 3% for saturated liquid enthalpy, 1.5% for saturated vapor enthalpy, 4% saturated liquid entropy, and 0.7% for saturated vapor entropy. Correction of W-B's coefficients and inclusion of the sixth term of M-H EOS for improvement of accuracy are recommended. R134a and R12 are compared with respect to refrigeration performance. COP's are different from each other within 3%. Refrigeration effect of R134a is superior to that of R12 but refrigeration capacity of R134a is inferior to that of R12 because the volumetric efficiency of the system using R134a is lower than that of the system using R12.

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Electrochemical Performances of the Sn-Cu Alloy Negative Electrode Materials through Simple Chemical Reduction Method

  • Oh, Ji Seon;Kim, Duri;Chae, Seung Ho;Oh, Seungjoo;Yoo, Seong Tae;Kim, Haebeen;Ryu, Ji Heon
    • Journal of Electrochemical Science and Technology
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    • v.10 no.3
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    • pp.329-334
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    • 2019
  • Sn-Cu alloy powders were prepared via a simple chemical reduction method for the negative electrode materials in lithiumion batteries. The addition of Cu can suppress the growth of Sn particles during synthetic process. Furthermore, the Cu also acts as a matrix phase against the volume change during cycling. With increasing amount of the Cu, a stable $Cu_6Sn_5$ phase formed in the Sn-Cu alloy and its cycle performance greatly enhanced depending on the Cu content. To promote the generation of the $Cu_6Sn_5$ phase, the synthesis temperature is raised to $60-100^{\circ}C$ from the ambient temperature. The Sn-Cu alloy powders prepared at elevated temperatures showed remarkable cycle performances. The Sn-Cu alloy powder obtained at $60^{\circ}C$ exhibited a significantly high volumetric capacity of over 2,000 mAh/cc at the 50th cycle.

Experimental study on shear damage and lateral stiffness of transfer column in SRC-RC hybrid structure

  • Wu, Kai;Zhai, Jiangpeng;Xue, Jianyang;Xu, Fangyuan;Zhao, Hongtie
    • Computers and Concrete
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    • v.23 no.5
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    • pp.335-349
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    • 2019
  • A low-cycle loading experiment of 16 transfer column specimens was conducted to study the influence of parameters, likes the extension length of shape steel, the ratio of shape steel, the axial compression ratio and the volumetric ratio of stirrups, on the shear distribution between steel and concrete, the concrete damage state and the degradation of lateral stiffness. Shear force of shape steel reacted at the core area of concrete section and led to tension effect which accelerated the damage of concrete. At the same time, the damage of concrete diminished its shear capacity and resulted in the shear enlargement of shape steel. The interplay between concrete damage and shear force of shape steel ultimately made for the failures of transfer columns. With the increase of extension length, the lateral stiffness first increases and then decreases, but the stiffness degradation gets faster; With the increase of steel ratio, the lateral stiffness remains the same, but the degradation gets faster; With the increase of the axial compression ratio, the lateral stiffness increases, and the degradation is more significant. Using more stirrups can effectively restrain the development of cracks and increase the lateral stiffness at the yielding point. Also, a formula for calculating the yielding lateral stiffness is obtained by a regression analysis of the test data.

Effect of Transverse Steel on Shear Performance for RC Bridge Columns (철근콘크리트 원형 교각의 전단성능에 대한 횡방향철근의 영향)

  • Ko, Seong Hyun
    • Journal of the Earthquake Engineering Society of Korea
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    • v.25 no.5
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    • pp.191-199
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    • 2021
  • In seismic design, hollow section concrete columns offer advantages by reducing the weight and seismic mass compared to concrete section RC bridge columns. However, the flexure-shear behavior and spirals strain of hollow section concrete columns are not well-understood. Octagonal RC bridge columns of a small-scale model were tested under cyclic lateral load with constant axial load. The volumetric ratio of the transverse spiral hoop of all specimens is 0.00206. The test results showed that the structural performance of the hollow specimen, such as the initial crack pattern, initial stiffness, and diagonal crack pattern, was comparable to that of the solid specimen. However, the lateral strength and ultimate displacement of the hollow specimen noticeably decreased after the drift ratio of 3%. The columns showed flexure-shear failure at the final stage. Analytical and experimental investigations are presented in this study to understand a correlation confinement steel ratio with neutral axis and a correlation between the strain of spirals and the shear resistance capacity of steel in hollow and solid section concrete columns. Furthermore, shear strength components (Vc, V, Vp) and concrete stress were investigated.

Numerical modeling of concrete conveying capacity of screw conveyor based on DEM

  • Yu, Wenda;Zhang, Ke;Li, Dong;Zou, Defang;Zhang, Shiying
    • Computers and Concrete
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    • v.29 no.6
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    • pp.361-374
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    • 2022
  • On the premise of ensuring that the automatic and quantitative discharging function of concrete conveyors is met, the accuracy of the weight forecast by the mathematical model of the screw conveying volume is improved, and the error of the weight of the concrete parts and the accumulation thickness is reduced. In this paper, the discrete element method (DEM) is used to simulate the macroscopic flow of concrete. Using the concrete discrete element model, the size of the screw conveyor is set, and establish the response model between the influencing factors (process and structure) and the concrete mass flow rate according to the design points of the screw discharging experiment. The nonlinear data fitting method is used to obtain the volumetric efficiency function under the influence of process and structural factors, and the traditional screw conveying volume model is improved. The mass flow rate of concrete predicted by the improved mathematical model of screw conveying volume is consistent with the test results. The model can accurately describe the conveying process of concrete and achieve the purpose of improving the accuracy of forecasting the weight of discharged concrete.

Treatment of Organic Wastewaters by Briquette Ashes Fixed-film Process (연탄재를 이용한 유기성폐수의 처리)

  • Cho, Kwang-Myeung
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.11 no.4
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    • pp.19-33
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    • 1982
  • Briquette ashes, one of important solid wastes in Korea, have relatively high compression strength in spite of their low density, and provide sufficient surface area and some adsorption capacity. Results of this research show that a fixed-film biological process using briquette ashes as media can accomplish BOD removal efficiencies in treating organic wastewaters such as alcoholic waste, diluted nightsoil and sewage , and formula can be derived to determine the effluent BOD concentrations by superficial or volumetric organic loadings. Settling tanks may be required because effluent SS concentration is deteriorated due to the SS in influent or due to the slough-off of slime layer on the media when briquette ashes are utilized for a long period.

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