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Electrochemical Performance of Hybrid (Activated Carbon+LiCoO2) Electrode

하이브리드 (활성탄소+LiCoO2) 전극의 전기화학적 특성

  • 김익준 (한국전기연구원 전지연구그룹) ;
  • 전민제 (부경대학교 공업화학과) ;
  • 양선혜 (한국전기연구원 전지연구그룹) ;
  • 김현수 (한국전기연구원 전지연구그룹) ;
  • 문성인 (한국전기연구원 전지연구그룹) ;
  • 오대희 (부경대학교 공업화학과)
  • Published : 2006.09.01

Abstract

In this study, the hybrid electrodes, composed of the activated carbon powders and $LiCoO_{2}$ powders, were prepared as a cathode for the high-capacitance type hybrid capacitor, and the electrochemical properties of the hybrid electrodes were examined in terms of the weight composition and the milling time of $LiCoO_{2}$ powders. The specific volumetric capacities were increased with increasing of the composition of $LiCoO_{2}$ powders in the hybrid electrodes. On the other hand the coin cell capacitors, using the hybrid electrodes with $LiCoO_{2}$ poweders milled for 200 h, have exhibited the lower internal resistivities and the better capacity retention after 100 charge-discharge cycle than those of the coin cell capacitors using the hybrid electrodes with raw $LiCoO_{2}$ powders.

Keywords

References

  1. B. E. Conway, 'The electrolyte factor in supercapacitor design and performance : conductivity, ion-pairing and solvation', Proceedings of The 4th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, 1994
  2. B. E. Conway, 'Transition from super-capacitor to battery behavior in electrochemical energy storage', J. Electrochem. Soc., Vol. 138, p. 1539, 1991 https://doi.org/10.1149/1.2085829
  3. S. Sarangapani, B. V. Tilak, and C. P. Chen, 'Materials for electrochemical capacitprs', J. Electrochem. Soc., Vol. 143, p. 3791, 1996 https://doi.org/10.1149/1.1836938
  4. 김익준, 이선영, 도칠훈, 문성인, '전기이중층커패시터의 특성에 미치는 혼성 도전재의 영향', 전기전자재료학회논문지, 17권, 1호, 107, 2004
  5. 김익준, 이선영, 문성인, 'EDLC용 CMC+PTFE 혼합바인더 전극의 전기적, 기계적 특성', 전기전자재료학회논문지, 17권, 10호, p. 1079, 2004
  6. M. Takeuchi, T. Maruyama, K. Koike, A. Mogami, T. Oyama, and H. Kobayashi, 'Non-porous carbon for a high energy density electric double layer capacitor', Electrochemistry, Vol. 69, p. 487, 2001
  7. S. Mitani, S. I. Lee, S. H. Yoon, Y. Korai, and I. Mochida, 'Activation of raw pitch coke with alkali hydroxide to prepare high performance carbon for electric double layer capacitor', J. of Power Sources, Vol. 133, p. 298, 2004 https://doi.org/10.1016/j.jpowsour.2004.01.047
  8. A. I. Beliakov and A. M. Brintsev, 'Development and application of combined capacitor: double electric layer - pseudocapacity', Proceedings of The 7th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, 1997
  9. G. G. Amatucci, F. Badway, A. Du Pasquier, and T. Zheng, 'An asymmetric hybrid nonaqueous energy storage cell', J. of the Electrochemical Society, Vol. 148, p. A930, 2001
  10. 이선영, 김익준, 문성인, 김현수, 'Hybrid capacitor의 전기화학적 특성 및 hybrid capacitor/Li-ion battery의 펄스 방전 특성', 전기전자재료학회논문지, 18권, 12호, p. 1133, 2005