• 제목/요약/키워드: Volume Electrical conductivity

검색결과 169건 처리시간 0.022초

Synthesis of Solid Electrolyte Nasicon by Solid State Reaction

  • Kim, Cheol-Jin;Chung, Jun-Ki;Lim, Sung-Ki;Rhee, Meung-Ho
    • The Korean Journal of Ceramics
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    • 제2권1호
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    • pp.25-32
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    • 1996
  • Solid electroyte nasion was synthesized by the optimized solid state reaction minimizing the volume fraction of secondary $ZrO_2$ and glassy phases. To compensate for the evaporation of Na and P during heat-treatment, excess Na and P were added to the starting composition $Na_{1+x} Zr_2 Si_x P_{d-x} O_{12}$ (x=2.1). Phases pure nasicon comparable in volume fraction to the one obtaied from sol-gel process were synthesized after the reaction at $1100~1150^{\circ}C$,$ P_{O2}>=0.1-0.15 $$ZrO_2$ increased with the heat-treatment time due to the decomposition of nasicon phase and that of glassy phase increased as partial oxygen pressure decreased. The synthesized nasion showed a good electrical conductivity of $-1{\times}10^{-2}({\omega}{\cdot}cm)^{-1}$ at $350^{\circ}C$.

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Behavior of Water Droplet on the Polymer Surface and Influence of the Charge

  • Zhu, Yong;Yamashita, Seiji;Anami, Naoya;Otsubo, Masahisa;Honda, Chikahisa;Takenouchi, Osamu;Hashimoto, Yousuke
    • KIEE International Transactions on Electrophysics and Applications
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    • 제3C권3호
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    • pp.81-85
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    • 2003
  • This paper describes the results of experiments made to examine the behavior of water droplet on the polymer surface and influence of the charge. In this experiment, water droplet was put on the polymer surface in an applied AC electric field and the investigations of its behavior were done with a high-speed video camera. It can be observed that the droplet elongates and vibrates with being pulled towards the positive electrode in a wave synchronism with the frequency of the power source. The volume and conductivity of water droplet are shown to have a marked effect on the mode of discharge development. These behaviors may be caused by the change of electric field of applied AC voltage and induced charges in/on the water droplet.

Electrical and Rheological Behavior of the Anhydrous ER Fluids Based on Chitosan Derivatives as the Dispersion Phases

  • Choi Ung-su;Sung Bo-hyun
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2004년도 학술대회지
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    • pp.323-329
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

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Electrical and Rheological Behavior of the Angydrous ER Fluids Based on Chitosan Derviatives as the Dispersion Phases

  • 최웅수
    • KSTLE International Journal
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    • 제5권2호
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    • pp.49-51
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.

박막트랜지스터 응용을 위한 ${\mu}c-Si/CaF_2$/glass 구조특성연구 (The study of ${\mu}c-Si/CaF_2$/glass properties for thin film transistor application)

  • 김도영;안병재;임동건;이준신
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1514-1516
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    • 1999
  • This paper covers our efforts to improve the low carrier mobility and light instability of hydrogenated amorphous silicon (a-Si:H) films with microcrystalline silicon $({\mu}c-Si)$ films. We successfully prepared ${\mu}c-Si$ films on $CaF_2$/glass substrate by decomposition of $SiH_4$ in RPCVD system. The $CaF_2$ films on glass served as a seed layer for ${\mu}c-Si$ film growth. The XRD analysis on $CaF_2$/glass illustrated a (111) preferred $CaF_2$ grains with the lattice mismatch less than 5 % of Si. We achieved ${\mu}c-Si$ films with a crystalline volume fraction of 61 %, (111) and (220) crystal orientations. grain size of $706\AA$, activation energy of 0.49 eV, and Photo/dark conductivity ratio of 124. By using a $CaF_2$/glass structure. we were able to achieve an improved ${\mu}c-Si$ films at a low substrate temperature of $300^{\circ}C$.

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억셉터(Sr, Mg)가 첨가된 LaAlO3의 고온 전도 특성 (High temperature electrical properties of Sr-and Mg-Doped LaAlO3)

  • 박지영;박희정
    • 한국결정성장학회지
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    • 제29권5호
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    • pp.187-191
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    • 2019
  • 고체전지, 산화물연료전지, 센서, 산화물 분리막 등 에너지 재료로 활용이 무궁한 산소 이온 전도체 중 acceptor가 첨가된 $LaAlO_3$의 전기적 특성과 고온에서의 혼합전도체로 사용 가능성을 연구하였다. Sr과 Mg을 $LaAlO_3$에 동시에 첨가하여 만든 LSAM의 전기적 특성을 교류(a.c.)와 직류(d.c.) 방법을 이용하여 다양한 산소 분압에서 측정하였다. 교류 임피던스 방법을 이용하여 LSAM의 전체 저항에서 입자(grain) 저항과 입계(grain boundary) 저항을 분리한 결과, $550^{\circ}C$ 이하의 온도에서는 입계 저항이 지배적이나 $800^{\circ}C$ 이상의 온도에서는 입자 저항이 대부분임을 알 수 있었다. 또 산소분압에 따른 전도도 측정을 물질의 결함모델(defect model)을 이용하여 분석해 전체 전도도를 이온 전도도와 전자 전도도로 분리하였다. 그 결과, $800^{\circ}C$ 이상의 고온에서 LSAM은 낮은 산소분압($Po_2$ < $10^{-10}atm$)에서는 산소이온 전도체이고 높은 산소분압($Po_2$ > $10^{-5}atm$)에서는 혼합전도체의 거동을 보였다. 또 온도가 증가하여도 산소이온 전도가 주도적인 산소분압의 영역은 줄어들지 않았고 낮은 산소분압에서도 안정적인 전기적 특성을 보이는 등으로 보아, LSAM은 고온의 낮은 산소분압(T > $1500^{\circ}C$, $Po_2$ < $10^{-10}atm$) 조건에서 용강에서의 산소이온센서와 같은 산소이온체로의 사용 가능성이 높다.

Influence of Modeling Errors in the Boundary Element Analysis of EEG Forward Problems upon the Solution Accuracy

  • Kim, Do-Won;Jung, Young-Jin;Im, Chang-Hwan
    • 대한의용생체공학회:의공학회지
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    • 제30권1호
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    • pp.10-17
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    • 2009
  • Accurate electroencephalography (EEG) forward calculation is of importance for the accurate estimation of neuronal electrical sources. Conventional studies concerning the EEG forward problems have investigated various factors influencing the forward solution accuracy, e.g. tissue conductivity values in head compartments, anisotropic conductivity distribution of a head model, tessellation patterns of boundary element models, the number of elements used for boundary/finite element method (BEM/FEM), and so on. In the present paper, we investigated the influence of modeling errors in the boundary element volume conductor models upon the accuracy of the EEG forward solutions. From our simulation results, we could confirm that accurate construction of boundary element models is one of the key factors in obtaining accurate EEG forward solutions from BEM. Among three boundaries (scalp, outer skull, and inner skull boundary), the solution errors originated from the modeling error in the scalp boundary were most significant. We found that the nonuniform error distribution on the scalp surface is closely related to the electrode configuration and the error distributions on the outer and inner skull boundaries have statistically meaningful similarity to the curvature distributions of the boundary surfaces. Our simulation results also demonstrated that the accumulation of small modeling errors could lead to considerable errors in the EEG source localization. It is expected that our finding can be a useful reference in generating boundary element head models.

전기방사법에 의해 제조된 폴리에틸렌옥사이드/폴리아닐린 섬유의 열적 및 전기적 거동 (Thermal and Electrical Behaviors of Polyethylene Oxide/Polyaniline Fibers Prepared by Electrospinning Method)

  • 김석;조미화;박수진
    • 공업화학
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    • 제17권1호
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    • pp.16-21
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    • 2006
  • 본 연구에서는 폴리아닐린(PANI)을 제조하여 큰 분자량의 유기산인 10-camphor sulfonic acid (CSA) 또는 dodecylbenzene sulfonic acid (DBSA)로 도핑시키고, polyethylene oxide (PEO)와 함께 블렌딩하여 전기방사 용액을 제조하였다. 제조된 용액을 전기방사하여 섬유형태로 만든 후, TGA와 전기화학 장치(cyclic voltammetry; CV)로 열적, 전기적 성질을 CSA 또는 DBSA로 도핑된 PANI의 함량에 따라 비교, 분석하였다. 본 실험 결과, PANI-CSA와 PANI-DBSA의 함량이 증가함에 따라 열분해 개시온도는 감소하지만 열안정성 지수와 적분 열분해 진행온도가 증가하는 것으로 보아 열안정성은 증가하는 것으로 판단된다. 또한, 전기전도도는 PANI-CSA와 PANI-DBSA의 함량이 증가함에 따라 증가하였으나 30% 이상이 되면 전도도가 일정해지는 것으로 나타났다. 순환전류젼압 곡선 결과, PANI/CSA는 PANI-DBSA 보다 피크가 좀 더 명확해지며, 전류밀도가 크게 나타났다. 이는 PANI/CSA가 약간 더 높은 전기전도도와 전하가 이동하기 쉬운 모폴로지를 가지고 있기 때문인 것으로 판단된다.

Broad and stage-based sensing function of HCFRP sensors

  • Wu, Z.S.;Yang, C.Q.
    • Smart Structures and Systems
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    • 제3권2호
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    • pp.133-146
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    • 2007
  • This paper addresses a new type of broad and stage-based hybrid carbon fiber reinforced polymer (HCFRP) sensor that is suitable for the sensing of infrastructures. The HCFRP sensors, a type of composite sensor, are fabricated with three types of carbon tows of different strength and moduli. For all of the specimens, the active materials are carbon tows by virtue of their electrical conductivity and piezoresistivity. The measurement principles are based on the micro- and macro-fractures of different types of carbon tows. A series of experiments are carried out to investigate the sensing performances of the HCFRP sensors. The main variables include the stack order and volume fractions of different types of carbon tows. It is shown that the change in electrical resistance is in direct proportion to the strain/load in low strain ranges. However, the fractional change in electrical resistance (${\Delta}R/R_0$) is smaller than 2% prior to the macrofractures of carbon tows. In order to improve the resistance changes, measures are taken that can enhance the values of ${\Delta}R/R_0$ by more than 2 times during low strain ranges. In high strain ranges, the electrical resistance changes markedly with strain/load in a step-wise manner due to the gradual ruptures of different types of carbon tows at different strain amplitudes. The values of ${\Delta}R/R_0$ due to the fracture of high modulus carbon tows are larger than 36%. Thus, it is demonstrated that the HCFRP sensors have a broad and stage-based sensing capability.

Cu-TiB2 복합재료의 마모거동에 관한 연구 (A Study on the Wear Behavior of the Cu-TiB2 Composites)

  • 김정남;최종운;강계명
    • 한국재료학회지
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    • 제15권1호
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    • pp.61-65
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    • 2005
  • The titanium $diboride(TiB_2)$ has high strength(750MPa), high melting point $(3225^{\circ}C)\;and\;10\%$ IACS electrical conductivity. On this account, the dispersion hardening $Cu-TiB_2$ composites(MMCs) are a promising candidate for applications as electrical contact materials. MMCs for electrical contact materials can reduce material cost and resource consumption caused by wear, due to its good mechanical and electrical property. In this study, we attempt to prepare MMCs with various volume fraction and particle size of $TiB_2$ by means of hot extruded and cold drawn process. Dry sliding wear tests were performed on a pin-on-disk type wear tester, sliding against SM45C under the different applied loads. After wear testing, the microstructures of the worn surfaces were observed by SEM and the microhardnesses of the subsurface zone were measured.