• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.3
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• pp.414-421
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• 1999

Falling film rectification involves simultaneous heat and mass transfer between vapor and liquid interface. In the present work, the adiabatic rectification process of ammonia-water vapor on the vertical plate was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer in each phases were investigated. The stripping of water in vapor mixture occurred new the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer in falling film.

• International Journal of Air-Conditioning and Refrigeration
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• v.8 no.2
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• pp.69-79
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• 2000

Falling film rectification involves simultaneous heat and mass transfer between vapor and solution film. In the present work, the adiabatic rectification process of ammonia-water vapor by the falling solution film on the vertical plate was investigated. The continuity momentum, energy and diffusion equations for the solution film and the vapor mixture were formulated in integral forms and solved numerically, The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer coefficient in each phases were investigated. The stripping of water in vapor mixture occurred near the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer coefficient in falling film.

• Journal of the Korean Ceramic Society
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• v.35 no.1
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• pp.41-47
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• 1998

Cutting and planarization of diamond films have been performed using copper vapor laser under air at-mosphere. Diamond films of about 350${\mu}{\textrm}{m}$ and 800 ${\mu}{\textrm}{m}$ thick have been synthesized with DC plasma assisted chemical vapor deposition. The position of a specimen has been controlled by computer-driven stage. With copper vapor laser beam of 7W cutting depth increases rapidly and saturates with increasing scan number and decreasing scan speed. 8 repetitive scans at scan speed 0.5 mm/sec produce the maximum cutting depth without focus shifting Rod-shape copper vapor laser beam can be made and used effectively in planar-ization of rough diamond surface.

• Fashion & Textile Research Journal
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• v.3 no.4
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• pp.362-366
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• 2001

We studied on the softness properties of polyester fabric by vapor type ozone processing using ozone's strong oxidation instead of 25% NaOH chemical treatment. When vapor type ozone processing was directly treated to fabrics retaining water to 40% pick up ratio, high concentration ozone was generated oxidation of 3~4% approximately in polyester fabrics and finally its softness improved. The fabric's softness effect was improved because vapor type ozone generated the highest decomposition to oxidation of surface and inter molecules. The experiment revealed that fabric's softness was improved by change of the time of vapor type ozone processing. However, tensile strength and elongation were reduced by increase in time, 60 minute was assumed as the most optimized time to minimize the reduction of fabric's tensile strength and elongation as well as maximizing the fabric's softness.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.4
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• pp.187-198
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• 2003

Zinc selenide (ZnSe) single crystals hold promise for many electro-optics, acousto-optic and green laser generation applications. This material is prepared in closed ampoules by the physical vapor transport (PVT) growth method based on the dissociative sublimation. We investigate the effects of diffusive-convection on the crystal growth rate of ZnSe with a low vapor pressure system in a horizontal configuration. Our results show that for the ratios of partial pressures, s=0.2 and 2.9, the growth rate increases with the Peclet number and the temperature differences between the source and crystal. As the ratio of partial pressures approaches the stoichiometric value of 2, the rate increases. The mass fluk based on one dimensional (1D model) flow for low vapor pressure system fall within the range of the predictions (2D model) obtained by solving the coupled set of conservation equations, which indicates the flow fields would be advective-diffusive. Therefore, the rate and the flow fields are independent of gravity acceleration levels.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.418-425
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• 2004

Characteristics of a liquid-vapor interface where a nonequilibrium condensation flow exists are considered based on molecular dynamics simulations, The condensation coefficient, the velocity distributions of the reflected and evaporated molecules and the number flux of the evaporated molecules are compared with those under the liquid-vapor equilibrium. The comparison shows that the condensation coefficient under the nonequilibrium condensation is slightly larger and the number flux of the evaporated molecules is considerably smaller than those under the liquid-vapor equilibrium. The net condensation flux under the nonequilibrium condensation is underestimated if it is evaluated from the condensation coefficient and the number flux of the evaporated molecules under the liquid-vapor equilibrium. However the underestimation is relatively small.

• Journal of Integrative Natural Science
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• v.6 no.4
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• pp.211-214
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• 2013

In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that HF treatment is not desirable for the synthesis of a high quality PEDOT thin film via vapor phase polymerization method. Rather, sole treatment with plasma noticeably improved the quality of APS-SAM on glass surface. As a result, a highly dense and smooth PEDOT thin film was grown on uniform oxidant film-coated APS monolayer surface.

• Proceedings of the Materials Research Society of Korea Conference
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• 2000.11a
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• pp.50-50
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• 2000

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.652-656
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• 2014

Mercury amount in vapor phase from 3 types of CFL(compact fluorescent lamp) are estimated by measuring mercury concentration in vapor phase. The mercury concentration in vapor phase from CFL is sharply decreased during initial time and then the change in the mercury concentration is slightly decreased up to 24 hours. The mercury concentration in vapor phase is almost constant after 42 hours, which can be called by stabilized concentration. It can be estimated that the stabilized concentration is caused by the evaporation of mercury in the residues of broken CFL and can be affected by temperature and pressure in crushing apparatus. The mercury concentration for CFL manufactures are in the order of A < B < C as the same results of the initial mercury concentration and the stabilized concentration in vapor phase. As increased air flow rate, the partial pressure of mercury is decreased and the amount of mercury is reduced. Initially, the mercury concentration in vapor phase emitted from CFLs is higher than the regulatory level of $0.1mg/m^3$ in the specific facilities regardless of air flow rate. Hence, it is absolutely necessary that mercury in vapor phase should be controlled at the point of crushing campact fluorescent lamp.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.25 no.2
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• pp.156-165
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• 2015

Objectives: The purpose of this study was to investigate the possible effects of a gasoline vapor recovery system on personal exposure levels of gasoline vapor constituents including benzene, toluene, ethyl benzene, xylene(BTEX), and methyl tert-butyl ether(MTBE) among gas station workers in a metropolitan area. Methods: Thirty-one gas station workers at ten gas stations in a metropolitan area were selected as subjects for this study. Test method PV2028 as recommended in the OSHA process was used for sampling and analysis. Results: The personal exposure levels of benzene, toluene, ethyl benzene, xylene, MTBE and gasoline vapor in the gas station workers were $0.0018{\pm}0.0069ppm$, $0.0077{\pm}0.0137ppm$, $0.0002{\pm}0.0008ppm$, $0.0016{\pm}0.0084ppm$, $0.2619{\pm}0.3340ppm$, and $1.4940{\pm}1.7984ppm$, respectively. After adjustment for refueling frequency and volume, personal exposure levelswere higher in the gas stations where gasoline vapor recovery systems(Stage II) were not installed, but the results were not statistically significant. Gasoline vapor concentrations showed a positive correlation to the level of MTBE, a gasoline additive. Conclusions: Vapor recovery systems(Stage II) were effective not only in reducing emissions of air pollutants, but also in reducing exposure to hazardous substances among gas station workers. In addition, acorrelation between gasoline vapors and MTBE concentration was confirmed.