• Journal of Soil and Groundwater Environment
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• v.17 no.3
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• pp.76-85
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• 2012

Geochemical and ecological properties of remediated soil and gas exhausted from a low-temperature thermal desorption (LTTD) process were analyzed to assess the environmental impact of LTTD treatment. Soil characteristics were examined with regard to the chemical (EC, CEC, and organic matter) and the ecological (dehydrogenase activity, germination rate of Brassica juncea, and growth of Eisenia andrei) properties. The exhaust gases were analyzed based on the Air Quality Act in Korea as well as volatile organic compounds (VOCs) and mixed odor. Level of organic Organic matter of the soil treated by LTTD process was slightly decreased compared to that of the original soil because the heating temperature ($200^{\circ}C$) and retention time (less than 15 minutes) were neither high nor long enough for the oxidation of organic matter. The LTTD process results in reducing TPH of the contaminated soil from $5,133{\pm}508$ mg/kg to $272{\pm}107$ mg/kg while preserving soil properties. Analysis results of the exhaust gases from the LTTD process satisfied discharge standard of Air Quality Law in Korea. Concentration of VOCs including acetaldehyde, propionaldehyde, butyraldehyde and valeraldehyde in circulation gas volatilized from contaminated soil were effectively reduced in the regenerative thermal oxidizer and all satisfied the legal standards. Showing ecologically improved properties of contaminated soil after LTTD process and environmentally tolerable impact of the exhaust gas, LTTD treatment of TPH-contaminated soil is an environmentally acceptable technology.

• Journal of Environmental Health Sciences
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• v.36 no.5
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• pp.351-359
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• 2010

The objectives of this study were to understand the characteristics of residents in industrial areas and factors affecting exposure to the Volatile Organic Compounds(VOCs : Benzene, Toluene, Xylene) as well as to assess exposure levels according to house-type, and whether residents were indoors or outdoors. This research was designed to assess the differences in exposure levels to indoor, outdoor and personal VOCs in a case group and a control group across all areas, as well as in each different area, from May to October 2007, in. 110 residents of the G, Y and H industrial areas of the Jun-nam province. The geometric mea-levels of airborne benzene for the case group 1.31part per billion(ppb) indoor, 1.29 ppb outdoor, and 1.32 ppb for personal exposure were significantly higher than for the control group 0.99, 0.87 and 0.57 ppb, respectively. The geometric mean level for toluene personal exposure across the G, Y and H areas was 5.70 ppb for the case group and 6.31 ppb for the control group. While the outdoor level was 4.27 ppb for the case group and 5.06 ppb for the control group, The indoor level for the case group was 4.78 ppb, similar to that of the control group 4.69 ppb. The geometric mean levels for airborne xylene across the G, Y and H areas were 0.16 ppb(outdoor), 0.12 ppb(personal exposure) and 0.10 ppb(indoor) for the case group, and for the control group were 0.17(personal exposure) and 0.09 ppb(indoor and outdoor). The indoor/outdoor(I/O) ratio for case group is 1.19, while that of the control group is 1.15, indicating that the indoor level was higher than the outdoor level. The interrelationship differences among the three different types of levels in the air in the G, Y and H areas are statistically significant, except for the difference between the indoor and outdoor figures for xylene. In terms of the different types of houses and energy type uesd, the geometric mean level for airborne benzene, toluene and xylene for houses were 1.61, 5.39 and 0.12 ppb, respectively. while the figures for flats were 0.67, 3.32 and 0.05 ppb, respectively. Outdoors, the levels of benzene and toluene in flats were 0.71 and 2.62 ppb, respectively. and 1.58 and 5.35 ppb in houses. For personal exposure, the house levels of benzene, toluene and xylene were all higher than for flats. Houses using oil for heating have significantly higher levels than flats, which use gas for heating.

• Analytical Science and Technology
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• v.35 no.3
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• pp.116-123
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• 2022

Polymer bags, metallic canisters, and glass bottles have been used as containers for analyzing the volatile organic compounds (VOCs) in air. In this study, various sampling containers were compared to investigate the short-term stability of VOCs, that is, from the time they are sampled to the time they are analyzed. Polyvinyl fluoride (PVF), polypropylene (PP), polyester aluminum (PE-Al) bags, canisters, and glass bottles were used as sample containers. A 100 nmol/mol standard gas mixture of benzene, toluene, ethylbenzene, m-xylene, styrene, and o-xylene was used for the VOC comparison. Changes in the concentrations of samples stored for 10~20 day in each container were measured using a thermal desorption-gas chromatograph-flame ionization detector (TD-GC-FID). As a result, VOCs stored in a canister and two kinds of amber glass bottles have shown immaterial decreases in concentration in one week, and more than 80 % of the initial concentration was maintained for two weeks. In the case of polymer bags, the concentration of all VOCs, except benzene and toluene, were remarkably decreased below 70% of the initial concentration in one day. Particularly, ethylbenzene, xylene, and styrene have shown dramatic decreases in concentration below 30 % of the initial concentration in all polymer bags in one day.

• Journal of ILASS-Korea
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• v.23 no.4
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• pp.175-184
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• 2018

Emission characteristics of regulated (NOx, PM, CO, NMHC) and unregulated (VOCs, aldehydes, PAHs) air pollutants were investigated for diesel heavy duty buses equipped with different after-treatment systems (DPF+EGR and SCR) under urban driving cycle. The combustion temperature and the working temperature of SCR catalysts were important to make impact on NOx emissions, whereas PM emissions were low. The alkane groups dominated NMVOCs emissions, making 42.6~59.4% of sum of the NMVOCs emissions. Especially, alkane emissions of DPF+EGR-equipped vehicle included DOC had 14.9~15.5% higher than those of SCR-equipped vehicle due to low efficiency of oxidation catalyst. In the case of individual NMVOCs, n-nonane and propylene emissions highly occupied for DPF+EGR and SCR, respectively. Formaldehyde emissions among aldehydes were the highest and PAHs emissions were hardly detected except naphthalene and phenanthrene. The NMHC speciation has been shown to be the highest of the formaldehyde ranged 20.8~21.5%. The results of this study will be contributed to establish Korean HAPs emission inventory for automobile source.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.04a
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• pp.265-266
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• 2000

휘발성 유기화합물(VOCs)은 새로운 유형의 스모그의 광화학반응 촉진제로서의 작용 및 환경학적 문제점들을 제기하고 있으며 공단 주변의 악취발생 및 환경 오염사건등을 유발시키고 있다. 이러한 휘발성 유기화합물을 적절하게 제어할 수 있는 방지대책의 여러 가지 방법들이 국내외적으로 활발히 연구되어지고 있다. 산업현장에서 이들 휘발성유기화합물의 배출을 제어하기 위한 기술 보유 및 개발에 있어서는 아직까지 미비한 단계에 있으며 보유기술의 현장적용의 측면에서 휘발성유기화합물이 지니고 있는 특이한 물리적 성질 등에 의해 많은 어려움을 가진다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.243-244
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• 2000

중금속류, VOCs 및 다이옥신류를 포함한 특정대기유해물질 처리기술은 상당히 미량의 오염물질을 처리하는 것이고 높은 처리효율을 필요로 한다. 따라서 공정 또한 일반적인 대기오염물질 처리공정의 조합을 최적화 하거나 첨가제나 반응제를 추가 투입하는 등 필요에 따라 추가적인 공정을 설치하는 것이 대부분이다. 기존 공정의 변형을 통하여 일반대기오염물질의 처리효율을 높이고 목표로 하는 특정대기오염물질을 일부 제거할 수는 있으나 다양한 특정대기오염물질을 고효율로 처리하기 위해서는 개별물질에 대한 단위장치의 개발보다는 복합적인 장치의 개발이 필요하고 또한 경제성이 있다. (중략)

• Journal of ILASS-Korea
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• v.18 no.2
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• pp.106-111
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• 2013

Adulterations fuel have been using in the vehicle in these days. Because gasoline, diesel prices are rising every day. so people find more cheap price fuel. Adulterations fuel caused a serious air pollution problems. Adulteration fuel were made from waste engine oil, waste paint. According to Government regulations permit to be used recycle fuel(adulteration fuel) only in industrial boiler. Unburned fuel pollutants are effected to human health. In this paper, the hazardous air pollutants characteristics in the diesel vehicles according to adulterations of vehicle fuels were carried out in the NEDC test mode in chassis dynamometer. It is revealed that the all of the regulation pollutants (THC, NOx, CO and PM) emission in the adulterations of vehicle fuels was increased also the green house gas, $CO_2$ was increased. In the hazardous air pollutants characteristics, the VOCs(Volitile Organic Compounds) BTEX(Benzene, Toluene, Ethylbenzene, Xylene) emissions in the adulterations of vehicle fuels showed higher level than these in the diesel fuels.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.1
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• pp.77-84
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• 2003

HS, Ammonia, CH$_4$, VOCs, Microorganism, Bacteria etc produced from swineries or henhouses are known to prevent the growth of livestock. Moreover, they give an unpleasant feeling to the workers. In this study, a methodology to remove odors and toxic gases by oxidation of ozone was thus accomplished. However, most ozone generators which use the atmospheric surrounding air have problems of contamination of electrode for discharge. Therefore in this work, a wire-cylinder type plasma reactor with DC voltage has been used both in a laboratory scale test and in the real swinery to solve the existing problems. About 6 cm of electrode gap could decrease the attachment of dusts, humid aerosols and other polymers, which are contained in the air. This compact designed device could produce ozone to oxidize and remove the air pollutants. But the amount of ozone was not large enough to be harmful to human Health. Also, the concentration of ozone was able to be varied by the input voltage. which makes it available for the proposed system to be installed in various kinds of pig houses. With this device, at maximum 43 mg/㎥ (20 ppm) of ozone could be produced at 40 ㎸ input voltage (consumed energy was 0.1 Wh/㎥). A program was also made in this work to calculate the optimum parameters for design of a plasma reactor in wide range of conditions.

• Journal of Environmental Science International
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• v.28 no.10
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• pp.831-840
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• 2019

Recently, summer high temperature events caused by climate change and urban heat island phenomenon have become a serious social problem around the world. Urban areas have low albedo and huge heat storage, resulting in higher temperatures and longer lasting characteristics. To effectively consider the urban heat island measures, it is important to quantitatively grasp the impact of urban high temperatures on the society. Until now, the study of urban heat island phenomenon had been carried out focusing only on the effects of urban high temperature on human health (such as heat stroke and sleep disturbance). In this study, we focus on the effect of urban heat island phenomenon on air pollution. In particular, the relationship between high temperature phenomena in urban areas during summer and the concentration of photochemical oxidant is investigated. High concentrations of ozone during summer are confirmed to coincide with a day when the causative substances (NO2,VOCs) are high in urban areas during the early morning hours. Further, it is noted that the night urban heat island intensity is large.. Finally, although the concentration of other air pollutants has been decreasing in the long term, the concentration of photochemical oxidant gradually increases in Daegu.

• Proceedings of the KSR Conference
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• 2011.05a
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• pp.613-618
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• 2011

More than 7 million persons use Seoul Metropolitan Subways (SMS) everyday and the number has been in increasing trend. With the increasing trend of concerns on indoor air quality(IAQ), the management of IAQ has become an important issue, especially in case of subway operators, because most of subway lines are placed underground with poor ventilation condition. The ultimate object of study develop independent cleaning device that reduce efficient fine particle and $CO_2$. Urban subway has characteristics about proper clean air flow, must be installed in narrow space and maintenance cycle has enough time. Two layered electrically pre-charged filters were used for removing particulate matters and gas absorbers are packed between two layer filters for removing gases pollutants such $CO_2$, VOCs and HCHO. Urban subway has characteristics about proper clean air flow, must be installed in narrow space and maintenance cycle has enough time. SCAP prototype is producted as all in one method which decrease fine dust, $CO_2$ and noxious gas. and basic test carry out with quantity of wind, a gap of pressure, sampling efficiency.