• Title/Summary/Keyword: VOCs in air

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Health Risk Assessment of Occupants in the Small-Scale Public Facilites for Aldehydes and VOCs (일부 미적용 다중이용시설의 실내 공기 중 알데히드류 및 휘발성유기화합물 노출로 인한 건강위해성 평가)

  • Yang, Ji-Yeon; Kim, Ho-Hyun;Shin, Dong-Chun;Kim, Yoon-Shin;Sohn, Jong-Ryeul;Lim, Jun-Hwan;Lim, Young-Wook
    • Journal of Environmental Science International
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    • v.17 no.1
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    • pp.45-56
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    • 2008
  • This study was to assess the lifetime cancer and non-cancer risk of exposure of worker and user at public facilities in Korea to volatile organic compounds (VOCs). We measured the concentrations of two aldehydes and five VOCs in indoor air at 424 public buildings that 8 kinds of public facilities (70 movie theaters, 86 offices, 86 restaurants, 70 academies, 22 auditoriums, 30 PC-rooms, 30 singing-rooms and 30 bars) all over the country. There were estimated the human exposure dose and risks with averages of the using-time and frequency for facility users and office workers, respectively. Carcinogens (formaldehyde, acetaldehyde, and benzene) were estimated the lifetime excess cancer risks (ECRs). non-carcinogens (toluene, ethylbenzene, xylene, and styrene) were estimated the hazard quotients (HQs). The average ECRs of formaldehyde and benzene for facility worker and user were $1{\times}10^{-3}{\sim}1{\times}10^{-4}\;and\;1{\times}10^{-4}{\sim}1{\times}10^{-5}$ level, respectively, in all facilities. HQs of four non-carcinogens did not exceed 1.0 for all subjects in all facilities. The estimated ECRs for restaurant and auditorium were the highest, and the PC-room and bar were the next higher facilities. Furthermore, people in a smoking facility had the highest cancer risk. Higher ECRs of formaldehyde and benzene were observed in indoor smoking facilities such as restaurant and auditorium. Higher HQs of toluene and xylene were observed at the restaurant and office building.

Interlaboratory Study of Sampling and Analysis Techniques for Ambient VOCs under Field Conditions (현장중심의 동시측정을 통한 환경대기 중 휘발성유기화합물의 측정방식 비교 연구)

  • 김기현;김조천;이강웅;허귀석;이병규
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.685-691
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    • 2000
  • In order to provide basis for an accurate concentration determination of volatile organic compounds(VOCs) in air, four different institutions participated in simultaneous measurements of several VOC species under the experimental scheme of the Measurement and Analysis Division(MAD) of the Korea Society for Atmospheric Environment(KOSAE). Two types of experiments were undertaken by collecting and analyzing ambient air samples from the 7th floor of Natural Science Building, Han Tang University during two day periods of the late May 1998. The first typer of experiment was conducted as five consecutive experiments at 2-hour intervals by two institutions. On the other hand. the second type of experiment was performed as two -10hr sampling by three different institutions. The data obtained from different type of experiments were examined using various statistical approaches. In general, the results of these experiments indicated that the VOC data produced by a number of Korean institutions be fairly agreeable.

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Excellent toluene removal via adsorption by honeycomb adsorbents under high temperature and humidity conditions

  • Cho, Min-Whee;Kim, Jongjin;Jeong, Jeong Min;Yim, Bongbeen;Lee, Hyun-Jae;Yoo, Yoonjong
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.171-177
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    • 2020
  • Removal through adsorption is the most widely used and effective treatment method for volatile organic compounds (VOCs) in exhaust gases. However, at high temperatures and humidity, adsorption is competitive due to the presence of moisture and unsmooth physical adsorption thereby deteriorating adsorption performance. Therefore, water adsorption honeycomb (WAH) and VOCs adsorption honeycomb (VAH) were prepared to improve VOCs adsorption at high temperatures and humidity. Adsorbed toluene amounts on single honeycomb (SH), containing only VAH, and combined honeycomb (CH), containing WAH and VAH, were determined. Further, the toluene adsorption rates of honeycomb adsorbents mounted on rotary systems, VAH-single rotor (SR) and WAH/VAH-dual rotor (DR) were determined. Toluene adsorption by WAH/VAH-CH (inlet temperature: 40-50℃; absolute humidity: 28-83 gH2O/kg-dry air) was 1.6 times that by VAH-SH, and the water adsorption efficiency of WAH/VAH-CH was 1.7 times that of VAH-SH. The adsorption/removal efficiency of the WAH/VAH-DR (inlet temperature: 45℃; absolute humidity: 37.5 gH2O/kg-dry air) was 3% higher than that of VAH-SR. This indicates that the WAH at the rotor inlet selectively removed water, thereby improving the adsorption efficiency of the VAH at the outlet.

Development of the Inorganic Paint Using Clay-Titania Carrier and the Removal Property of Air Pollutant (점토와 광촉매를 이용한 무기도료의 개발과 대기정화성능에 관한 특성 연구)

  • Kim, Wha-Jung;Lee, Jun-Cheol;Chai, Han-Sik
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.655-658
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    • 2005
  • In the domestic atmosphere environment, the VOCs and the NOx have a large proportion of the pollutant, and the HCHO is the main environmental pollutant factor within the house. In this study, the inorganic paint which can absorb and remove VOCs, NOx and HCHO is developed by using clay-titania carrier. The basic data to develope eco-friendly inorganic paint is collected with the performance test to remove the VOCs, NOx and HCHO in the condition of the addition of several inorganic materials to the paint, and also the plan to practical use of eco-friendly inorganic paint is studied.

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VOCs Concentrations of Indoor and Outdoor in Solvent Thinner-Using Occupation, and Application of TiO$_2$ Photocatalytic Air Cleaner

  • Wonho Yang;Joon Cho;Busoon Son;Park, Jongan
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.1.1-2
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    • 2002
  • Ultimate objective of industrial hygiene is the prevention of health impairment that may result from exposure to chemicals at workplaces. This implies the definition of permissible levels of exposure, that is, levels that according to the present status of knowledge are estimated to cause no adverse health effects during the lifetime of the workers, and the regular assessment of the possible health risk associated with exposure by comparing the current or the integrated exposure with the permissible exposure limits. Workers in solvent thinner-using occupation environment might be highly exposed to VOCs(volatile organic compounds) because solvent thinner has been used extensively such as painting, spraying, degreasing, coating and so on in Korea. The purpose of this study was to recognize, evaluate and propose the alternative control the VOCs from solvent thinner-using workplace.

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Comparative Analysis between Direct-reading Meter of PID and GC-FID using the Active Type Air Sampler for VOCs Measurement (직독식 측정기 PID와 능동식 시료채취기에 의한 GC-FID 정량분석법의 VOCs 농도 비교 연구)

  • Yeo, Jin-Hee;Choi, Kwang-Min
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.3
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    • pp.301-306
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    • 2016
  • Objectives: Direct-reading instrument(Photoionization detectors, PID) and quantitative analysis using active type air sampling (Gas chromatography-flame ionization detector, GC-FID) were tested to evaluate their ability to detect volatile organic compounds(VOCs) in a semiconductor manufacturing plant. Methods: The organic compounds used were acetone and ethanol which are normally used as cleaning solutions in the semiconductor manufacturing. The evaluation was based on the preparation of test solutions of known acetone and ethanol concentration in a chamber($600{\times}600{\times}1150mm$). Samples were prepared that would be equivalent to 5~100 ppm for acetone and 10~ 200 ppm ethanol. GC-FID and PID were evaluated simultaneously. Quantitative analysis was performed after sampling and the direct-reading instrument was checked using real-time data logging. Results: Positive correlations between PID and GC-FID were found for acetone and ethanol at 0.04~2.4% for acetone(TLV: 500 ppm) and 0.1~8.3% for ethanol(TLV: 1000 ppm). When the sampling time was 15 min, concentration of test solution was the most similar between measurement methods. However, the longer the sampling time, the less similar the results. PID and GC-FID had similar exposure patterns. Conclusions: The results indicate that PID and GC-FID have similar exposure pattern and positive correlation for detection of acetone and ethanol. Therefore, PID can be used for exposure monitoring for VOCs in the semiconductor manufacturing industry. This study has significance in that it validates measuring occupational exposure using a portable device.

A studies on the Air pollutant Emission Rate calculation from vessels in the Ulsan Port (울산항 선박으로부터의 대기오염 배출량 산정에 관한 연구)

  • Cheong Kwng-Hyun;Kim Sung-Joo;Park Hung-Suck
    • Proceedings of KOSOMES biannual meeting
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    • 2005.05a
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    • pp.111-118
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    • 2005
  • The Protocol adopted in Sep. 1997 included the new Annex VI of MARPOL 73/78, which will enter into force on 19 May 2005. MARPOL Annex VI sets limits on sulphur oxide and nitrogen oxide emissions from ship exhausts and prohibits deliberate emissions of volatile organic compound (VOCs) from oil tanker in port and oil terminal. This study was conducted to find out countermeasures for the new Annex VI of MARPOL 73/78 and draw up a feasible management plan. The emission quantity of NOx and SOX from ships in Ulsan Port was calculated by U.S. EPA and Japan Marine Engineering emission factors of air pollutant from ship exhausts. In addition, volatile organic compound (VOCs) from oil tanker during the loading and discharging period, also calculated.

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Identification of Immune Responsive Genes on Benzene, Toluene and o-Xylene in Jurkat Cells Using 35 k Human Oligomicroarray

  • Sarma, Sailendra Nath;Kim, Youn-Jung;Jeon, Hee-Kyung;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.2 no.4
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    • pp.229-235
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    • 2006
  • Volatile organic compounds (VOCs) are a major component of urban air pollution. It is documented that low exposure levels of VOCs induce alterations in immune reactivity resulting in a subsequent higher risk for the development of allergic reactivity and asthma. Despite these facts, there are few reports on the affected primary target and the underlying effective causal mechanisms. So in this study, to better understand the risk of BTX (benzene, toluene and o-xylene) which are the major VOCs and to identify novel biomarkers on immune response to these VOCs exposure in human T lymphocytes, we performed the toxicogenomic study by analyzing of gene expression profiles using 35 k human oligo-microarray. BTX generated specific gene expression patterns in Jurkat cell line. By clustering analysis, we identified some genes as potential markers on immuno-modulating effects of BTX. Four genes of these, HLA-DOA, ITGB2, HMGA2 and 5TAT4 were the most significantly affected by BTX exposure. Thus, this study suggests that these differentially expressed immune genes may play an important role in the pathogenesis on BTX exposure and have significant potential as novel biomarkers of exposure, susceptibility and response to BTC.

Catalytic Characteristics of Mn-PC for VOCs Combustion (VOCs 연소용 Mn-PC 촉매 특성)

  • Seo, Seong-Gyu;Ma, Zhong-Kun;Liu, Yi;Yoon, Hyung-Sun;Kim, Sang-Chai
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.4
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    • pp.237-242
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    • 2011
  • In this study, the catalytic activity of Mn-Phthalocyanine (Mn-PC) for VOCs (acetadehyde, propionaldehyde and toluene) combustion was determined. The reaction was carried out in a fixed bed reactor at the temperature range of $200{\sim}380^{\circ}C$. We investigated the physicochemical properties of Mn-PC before and after the pretreatment (air, $450^{\circ}C$, 1 hr, 60 cc/min) by TGA (Thermogravimetric Analyzer), BET (Brunauer Emmett Teller), EA (Elemental Analyzer), XRD (X-ray Diffractometer) and SEM (Scanning Electronic Microscope). By TGA analysis, 88 wt.% mass loss of Mn-PC was found at $419^{\circ}C$. The BET surface area of Mn-PC increased after the pretreatment. The decomposition and combustion of organic components in Mn-PC were observed by EA analysis. We also confirmed that Mn-PC had transformed into a new manganese oxide phase ($Mn_3O_4$) after the pretreatment by XRD analysis. By SEM analysis, many of the micropores generated during the pretreatment were found. The catalytic activity of Mn-PC with the pretreatment for propionaldehyde combustion was higher than that of $Mn_3O_4$ and fresh Mn-PC. It showed the catalytic activity of Mn-PC with the pretreatment for VOCs combustion by the order of toluene < acetadehyde < propionaldehyde.