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Thick Film Gas Sensor Based on PCB by Using Nano Particles (나노 입자를 이용한 PCB 기반 후막 가스 센서)

  • Park, Sung-Ho;Lee, Chung-Il;Song, Soon-Ho;Kim, Yong-Jun
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.2 s.43
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    • pp.59-63
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    • 2007
  • This paper presented a low-cost thick film gas sensor module, which was based on simple PCB (Printed Circuit Board) process. The proposed sensor module included a $NO_2/H_2$ gas sensor, a relative humidity sensor, and a heating element. The $NO_2/H_2$ gas and relative humidity sensors were realized by screen-printing $SnO_2,\;BaTiO_3$ nano-powders on IDTS (Interdigital Transducer) of a PCB substrate, respectively. At first 1% $H_2$ gas flowed into the sensor chamber. After 4 min, air filled the chamber while $H_2$ gas flow stopped. This experiment was performed repeatedly. The Identical procedure was used for the $NO_2$ detection. The result for sensing $H_2$ gas showed the increase of voltage from 0.8V to 3.5V due to the conductance increase and its reaction response time by hydrogen flow was 65 sec. $NO_2$ sensing results showed 2.7 V voltage drop due to the conductance decrease and its response time was 3 sec through a voltage monitoring.

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Separation Behavior of Vanadium and Tungsten from the Spent SCR DeNOX Catalyst by Strong Basic Anion Exchange Resin (SCR 탈질 폐촉매로부터 강염기성 음이온교환수지를 이용한 바나듐/텅스텐 분리거동 고찰)

  • Heo, Seo-Jin;Jeon, Jong-Hyuk;Kim, Chul-Joo;Chung, Kueong-Woo;Jeon, Ho-Seok;Yoon, Do-Young;Yoon, Ho-Sung
    • Resources Recycling
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    • v.29 no.5
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    • pp.38-47
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    • 2020
  • In this study, factors affecting the adsorption reaction for the separation/recovery of V and W using Lewatit monoplus MP 600, a strong basic anion exchange resin, from the leachate obtained through the soda roasting-water leaching process from the spent SCR DeNOX catalyst investigated and the adsorption mechanism was discussed based on the results. In the case of the mixed solution of V and W, both ions showed a high adsorption ratio at pH 2-6, but the adsorption of W was greatly reduced at pH 8. In the adsorption isothermal experiment, both V and W were fitted well at the Langmuir adsorption isotherm, and the reaction kinetics were fitted well at pseudo-second-order. As a result of conducting an adsorption experiment by adjusting the pH with H2SO4 to remove Si, which inhibits the adsorption of V and W from the leachate, the lowest W adsorption ratio was shown at pH 8.5. Desorption of W was hardly achieved in strongly acidic solutions, and desorption of V was well performed in both strongly acidic and strongly basic solutions.

Antibacterial Activity of Medicinal Plant Extracts to S. aureus KCCM12256 and V. parahaemolyticus KCCM11965 (한약재 추출액의 S. aureus KCCM12256과 V. parahaemolyticus KCCM11965에 대한 항균 활성)

  • Doh, Eun-Soo
    • Journal of the East Asian Society of Dietary Life
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    • v.20 no.6
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    • pp.881-887
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    • 2010
  • This study was conducted to investigate the antibacterial activities of medicinal plant extracts. The results were as follows. Crude water and methanolic extracts of Sanguisorba officinalis Linne, Coptis chinensis Makino, and Portulaca oleracea Linne, among 31 kinds of medicinal plants, had strong antibacterial activities against S. aureus and V. parahaemolyticus, with the methanolic extract more effective than the water extract. The methnolic and water extracts of S. officinalis Linne had strong antibacterial activities against S. aureus and V. parahaemolyticus. Antibacterial activity against S. aureus and V. parahaemolyticus was observed with extracts of S. officinalis Linne at dilutions of 5 and 10%, respectively. The EtOAc, BuOH, and $H_2O$ fractions of the extract of S. officinalis Linne had antibacterial activities against S. aureus and V. parahaemolyticus. Specifically, the fractions had antibacterial activity against S. aureus at dilutions of 5, 2, and 1%, respectively. Regarding V. parahaemolyticus, the EtOAc, $H_2O$, and BuOH fractions had antibacterial activities at dilutions of 5, 2, and 1%, respectively.

ON THE EXISTENCE OF POSITIVE SOLUTION FOR A CLASS OF NONLINEAR ELLIPTIC SYSTEM WITH MULTIPLE PARAMETERS AND SINGULAR WEIGHTS

  • Rasouli, S.H.
    • Communications of the Korean Mathematical Society
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    • v.27 no.3
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    • pp.557-564
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    • 2012
  • This study concerns the existence of positive solution for the following nonlinear system $$\{-div(|x|^{-ap}|{\nabla}u|^{p-2}{\nabla}u)=|x|^{-(a+1)p+c_1}({\alpha}_1f(v)+{\beta}_1h(u)),x{\in}{\Omega},\\-div(|x|^{-bq}|{\nabla}v|q^{-2}{\nabla}v)=|x|^{-(b+1)q+c_2}({\alpha}_2g(u)+{\beta}_2k(v)),x{\in}{\Omega},\\u=v=0,x{\in}{\partial}{\Omega}$$, where ${\Omega}$ is a bounded smooth domain of $\mathbb{R}^N$ with $0{\in}{\Omega}$, 1 < $p,q$ < N, $0{{\leq}}a<\frac{N-p}{p}$, $0{{\leq}}b<\frac{N-q}{q}$ and $c_1$, $c_2$, ${\alpha}_1$, ${\alpha}_2$, ${\beta}_1$, ${\beta}_2$ are positive parameters. Here $f,g,h,k$ : $[0,{\infty}){\rightarrow}[0,{\infty})$ are nondecresing continuous functions and $$\lim_{s{\rightarrow}{\infty}}\frac{f(Ag(s)^{\frac{1}{q-1}})}{s^{p-1}}=0$$ for every A > 0. We discuss the existence of positive solution when $f,g,h$ and $k$ satisfy certain additional conditions. We use the method of sub-super solutions to establish our results.

pH Sensitive Graphene Field-Effect Transistor(FET) (pH에 민감한 그래핀 전계효과 트랜지스터(FET))

  • Park, Woo Hwan;Song, Kwang Soup
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.2
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    • pp.117-122
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    • 2016
  • Recently, the detection of pH with real-time and in vivo has been focal pointed in the environmental or medical fields. In this work, we developed the pH sensor using graphene sheet. Graphene has high biocompatibility. We fabricated flexible solution-gated field-effect transistors (SGFETs) on graphene sheet transferred on the polyethylene terephthalate (PET) substrate to detect pH in electrolyte solution. The gate length was $500{\mu}m$ and the gate width was 8 mm. We evaluated the current-voltage (I-V) transfer characteristics of graphene SGFETs in pH solution. The drain-source current ($I_{DS}$) and the gate-source voltage ($V_{GS}$) curves of graphene SGFETs were depended on pH value. The Dirac point of graphene SGFETs linearly shifted to the positive direction about 19.32 mV/pH depending on the pH value in electrolyte solution.

Effects of Vinegar and Lactic Acid on the Survival of Pathogens Causing Food Poisoning of Sliced Raw Fish Meat (식초와 젖산이 생선회 식중독 유래 병원성 세균의 생존에 미치는 영향)

  • 김영만;김경희
    • Journal of Life Science
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    • v.12 no.6
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    • pp.669-675
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    • 2002
  • Introduction of sliced raw fish meat(SRFM) to fast food business has been considered seriously. However bacteria causing food poisoning should be controlled. Organic acids such as vinegar and lactic acid used in the sauce for SRFM were evaluated for their antibacterial activities. At low concentration levels of vinegar and lactic acid exerted strong antibacterial activities toward Vibriu sp.. In contrast, in case of Salmonella typhimurium and Escherichia coli O157:H7 low anitbacterial activities were observed even at relatively high concentrations. Minimum inhibitory concentrations(MIC) of vinegar for V. vulnificus, V. cholerae non-O1, V. parahaemolyticus, V. mimicus, S. typhimurium and E. coli O157:H7 were 16, 18, 16, 12, 26, and $20{\mu}\ell /m\ell, respertively. MIC of lactic acid for V. vilnificus, V. cholerae non-O1, V. parahaemolyticus, V. mimicus, S. typhimurium and E. coli O157:H7 were 20, 25, 25, 25, 40, and $35{\mu}\ell /m\ell, respectively. In case of vinegar bactericidal concentration upon 10 second contact for V. vulnificus, V. cholerae non-O1, V. parahaenolyticus, V. mimicus and E. coli O157:H7 were 8, 14, 10, 4, and 48%, respectively; however, even at 50% colony of S. typhimurium was observed. In case of lactic acid any colony was observed for V. vulnificus, V. cholerae non-O1, V. parahaemolyticus, V. mimicus, S. typhimurium and E. coli O157:H7 at the concentration of 2, 3, 4, 3, 14, and 17%, respectively. Vinegar and lactic acid of low concentration inhibited the growth of Vibrio sp., food poisoning pathogen in SRFM; in contrast, at high concentration these organic acids inhibited Salmonella sp. and Escherichia sp., food poisoning pathogen in other than SRFM.

Characteristics of Flame Hardening Process for 12Cr Steels (12Cr 강의 이동 화염경화 공정 특성)

  • Kim Gwang-Ho;Lee Min-Ku;Kim Kyeong-Ho;Kim Whung-Whoe;Rhee Chang-Kyu;Kim Gil-Mu
    • Journal of the Korean institute of surface engineering
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    • v.39 no.2
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    • pp.49-56
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    • 2006
  • In this study, the movable flame hardening process of 12Cr steel for a uniform hardness and desirable residual stress have been investigated. For this, the temperature cycles have been controlled accurately as a function of the three processing variables, the flame intensity $I_f$, the scanning velocity $V_s$, and the initial flame holding time $t_h$, where the standard surface temperature $T_{s,\;max}$, was maintained at $960^{\circ}C$. The optimized conditions were $V_s=0.68mn/s\;and\;t_h=67sec$ for the $C_3H_8:O_2\;=\;5:20l/min,\;V_s=0.80mm/s$ and $t_h=56sec$ for the $C_3H_8:O_2=6:24l/min,\;V_s=1.01mm/s\;and\;t_h=48sec$ for the $C_3H_8:O_2=7:28l/min,\;and\;V_s=1.15mm/s$ and $t_h=39sec$ for the $C_3H_8:O_2$=8:32 l/min. The optimally flame-hardened surface exhibited uniform distributions of the hardness and residual compressive stress over the treated area with moderate levels of $470{\sim}490HV_{0.2}$in hardness and $-300{\sim}-450MPa$ in residual stress, which were acceptable on the basis of the acceptance criteria of Siemens AG-KWU and GE Power Generation Engineering.

ON THE MINIMAL ENERGY SOLUTION IN A QUASILINEAR ELLIPTIC EQUATION

  • Park, Sang-Don;Kang, Chul
    • Communications of the Korean Mathematical Society
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    • v.18 no.1
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    • pp.65-73
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    • 2003
  • In this paper we seek a positive, radially symmetric and energy minimizing solution of an m-Laplacian equation, -div$($\mid${\nabla}u$\mid$^{m-2}$\mid${\nabla}u)\;=\;h(u)$. In the variational sense, the solutions are the critical points of the associated functional called the energy, $J(v)\;=\;\frac{1}{m}\;\int_{R^N}\;$\mid${\nabla}v$\mid$^m\;-\;\int_{R^N}\;H(v)dx,\;where\;H(v)\;=\;{\int_0}^v\;h(t)dt$. A positive, radially symmetric critical point of J can be obtained by solving the constrained minimization problem; minimize{$\int_{R^N}$\mid${\nabla}u$\mid$^mdx$\mid$\;\int_{R^N}\;H(u)d;=\;1$}. Moreover, the solution minimizes J(v).

Kinetics and hydrolysis mechanism of insecticide O,O-diethyl-O-(1-phenyl-3-trifluoromethylpyrazol-5-yl)phosphorothioate (Flupyrazofos) (살충제 O,O-diethyl-O-(1-phenyl-3-trifluoromethylpyrazol-5-yl)-phosphorothioate(Flupyrazofos)의 가수분해 반응 메커니즘)

  • Sung, Nack-Do
    • The Korean Journal of Pesticide Science
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    • v.6 no.3
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    • pp.218-223
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    • 2002
  • The rate of hydrolysis of insecticide, O,O-diethyl-O-(1-phenyl-3-trifluoromethylpyrazol-5-yl)phosphorothioate (Flupyrazofos) have been investigated in 25% (v/v) aqueous dioxane (${\mu}=0.1M$) at $45^{\circ}C$. The hydrolysis mechanism of flupyrazofos proceeds through the specific acid ($A_{AC}2$) catalysis below pH 4.0, specific base ($B_{AC}2$) catalysis above pH 11.0 and general acid & base ($B_{AC}2$) catalysis between pH 5.0 and pH 10.0 via trigonal-bipyramidal ($d^2sp^3$) intermediate as evidence by solvent effect ($|m|{\ll}|{\ell}|$), rate equation ($kt=ko+k_H+ [H_3O^+]+k_{OH}[OH^-]$) and product analysis. The half-life ($T\frac{1}{2}$) of hydrolytic degradation in neutral media at $45^{\circ}C$ was ca. 3 months.

Kinetics and Mechanism of Hydrolysis of Insecticidal $O,O-diethyl-{\alpha}-cyanobenzylideneamino-oxyphosphorothiate\;(Volaton^{\circledR})$ (살충성 $O,O-Diethyl-{\alpha}-cyanobenzylideneamino-oxyphosphorothioate\;(Volaton^{\circledR})$의 가수분해 반응메카니즘)

  • Sung, Nack-Do;Kim, Hyune-Yi;Park, Cheon-Kyu
    • Applied Biological Chemistry
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    • v.37 no.2
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    • pp.124-129
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    • 1994
  • The rate of hydrolysis of insecticidal $O,O-diethyl-{\alpha}-cyanobenzylideneamino-oxyphosphorothioate\;(Volaton^{\circledR})$ has been studied in 25% (v/v) aqueous dioxane. On the basis of solvent effect (pH 6.0; m=0.21, n=1.55, pH 12.0; m=0.42, n=3.14 & $|m|{\ll}|l|$), general base catalysis, hydrolysis product analysis, calculation of molecular orbital (MO) and rate equation, it may be concluded that the hydrolysis of Volaton proceeds through the $A_{AC}2$ mechanism via trigonal bipyramidal $(sp^3d^2)$ intermediate below pH 7.0, while above pH 9.0 the hydrolysis proceeds through the $B_{AC}2$ mechanism. Hydrolysis reactivity of Volaton depends on positive charge strength $(p{\gg}{\alpha}C_2)$ rather than steric hindrance. In the range between pH 7.0 and pH 9.0, these two reactions occur competitively.

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