• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1669-1678
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• 2011

Six new binuclear copper(II) complexes have been prepared by template condensation of the dialdehydes 1,8-[bis(3-formyl-2-hydroxy-5-methyl)benzyl]-l,4,8,11-tetraazacyclotetradecane (PC-a) and 1,8-[bis(3-formyl-2-hydroxy-5-bromo)benzyl]-l,4,8,11-tetraazacyclotetradecane (PC-b) with appropriate aliphatic diamines, and copper(II) perchlorate. The structural features of the complexes have been confirmed by elemental analysis, IR, UV-vis and mass spectra etc. The electrochemical behavior of all the copper(II) complexes show two irreversible one electron reduction process. The room temperature magnetic moment studies depict the presence of an antiferromagnetic interaction in the binuclear complexes. The catechol oxidation and hydrolysis of 4-nitrophenylphosphate were carried out by using the complexes as catalyst. The antimicrobial screening data show good results. The binding of the complexes to calf thymus DNA (CT DNA) has been investigated with absorption and emission spectroscopy. The complex [$Cu_2L^{1a}$] displays significant cleavage property of circular plasmid pBR322 DNA in to linear form. Spectral, electrochemical, magnetic and catalytic studies support the distortion of the copper ion geometry that arises as the macrocyclic ring size increases.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.4
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• pp.403-407
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• 2010

Gecko adhesion system consists of beam-shaped seta and spatula which has the role of adhesive pad. In this paper, adhesion mechanism of gecko adhesion system is performed by using adhesive beam contact model. this model has a feature of non-uniform stress profile on the contact surface and adhesion/detachment mechanism is determined by the tensile stress of the contact region. a spatula tip pad has the role of reduction of maximum tensile stress and adhesive force is increased due to this effect. As for a reverse loading case, maximum compressive stress drops by the spatula effect and this cause unsymmetric loading conditions between adhesion and detachment forces. In this study, finite element method is used for the analysis of adhesive beam contact model and the results for spatula effect are presented.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.1
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• pp.13-24
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• 1993

The tangent stiffness matrices of the plane frame and the thin-walled space frame are derived by using the principle of virtual displacement. In case of the plane frame, the shape function and stiffness matrices are presented for the rigid-hinged condition. For the unsymmetric thin-walled space frame, the elastic and geometric stiffness matrices in three cases of the unrestrained torsion, the restrained torsion, and the restrained anti unrestrained torsion are evaluated by using the various Hermitian polynomials as the shape function. Numerical examples for the lateral buckling analysis of the space frames and the circular arch illustrate the accuracy and convergence characteristics of the derived formulations.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.5
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• pp.34-40
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• 2005

Most analyses and researches on Micro Aerial Vehicle(MAV) have focused upon propulsion, automatic control, aerodynamic configuration in low Reynolds number region, and miniaturization of telemetric parts. In the present study, a structural concept for MAV is designed by using the composite material suitable for light flight structures. In order to study the load path and stress state of the MAV, the load and structural analyses are simultaneously performed by the aeroelasticity module of MSC/NASTRAN. The stability derivatives of the MAV are obtained for three symmetric, two antisymmetric, and four unsymmetric maneuvering conditions. Although the aerodynamic theory in MSC/NASTRAN could not be proper for MAV analysis, it provides an traditional and effective tool for trim and load analyses and may be corrected with the results by more accurate theory or test. The results show that the inertial load due to payloads has a more effect on stress rather than the aerodynamic load.

• Structural Monitoring and Maintenance
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• v.1 no.4
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• pp.371-392
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• 2014

Long-span cable-supported bridges are flexible structures vulnerable to unsymmetric loadings such as railway traffic and strong wind. The torsional dynamic response of long-span cable-supported bridges under running trains and/or strong winds may deform the railway track laid on the bridge deck and affect the running safety of trains and the comfort of passengers, and even lead the bridge to collapse. Therefore, it is eager to figure out the torsional dynamic response of long-span cable-supported bridges under running trains and/or strong winds. The Tsing Ma Bridge (TMB) in Hong Kong is a suspension bridge with a main span of 1,377 m, and is currently the world's longest suspension bridge carrying both road and rail traffic. Moreover, this bridge is located in one of the most active typhoon-prone regions in the world. A wind and structural health monitoring system (WASHMS) was installed on the TMB in 1997, and after 17 years of successful operation it is still working well as desired. Making use of one-year monitoring data acquired by the WASHMS, the torsional dynamic responses of the bridge deck under rail traffic and strong winds are analyzed. The monitoring results demonstrate that the differences of vertical displacement at the opposite edges and the corresponding rotations of the bridge deck are less than 60 mm and $0.1^{\circ}$ respectively under weak winds, and less than 300 mm and $0.6^{\circ}$ respectively under typhoons, implying that the torsional dynamic response of the bridge deck under rail traffic and wind loading is not significant due to the rational design.

• Journal of the Korean Wood Science and Technology
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• v.41 no.3
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• pp.211-220
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• 2013

The nailed joints in wood construction are commonly designed to resist and carry the lateral load but also subject to withdrawal force like uplift load due to the wind. This research was conducted to evaluate the performance of nailed joint composed of dimension lumber and sheathing materials through the nail withdrawal and unsymmetric double shear joint test, and then compared to current design values. The withdrawal strength was greatly dependant on wood specific gravity, and the withdrawal strength of I-joist with OSB showed higher value in spite of low specific gravity. The maximum withdrawal loads were greater than that of derived current design values about 5 times. The lateral resistance of Japanese larch/OSB nailed joints was higher than that of SPF/OSB nailed joint, and derived allowable lateral strength of nailed joints in this study exceeded the current design values. The failure mode of nailed joints was primarily due to the nail bending and this tendency was notable in SPF/OSB nailed joint.

• Journal of the Earthquake Engineering Society of Korea
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• v.3 no.1
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• pp.41-54
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• 1999

For free vibration of non-symmetric thin-walled circular arches including restrained warping effect, the elastic strain and kinetic energy is derived by introducing displacement fields of circular arches in which all displacement parameters are defined at the centroid axis. The cubic Hermitian polynomials are utilized as shape functions for development of the curved thin-walled beam element having eight degrees of freedom. Analytical solution for in-plane free vibration behaviors of simply supported thin-walled curved beams with monosymmetric cross-sections is newly derived. Also, a finite element formulation using two noded curved beams element is presented by evaluating elastic stiffness and mass matrices. In order to illustrate the accuracy and practical usefulness of this study, analytical and numerical solutions for free vibration of circular arches are presented and compared with solutions analyzed by the straight beam element and the ABAQUS's shell element.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.10 no.1
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• pp.17-26
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• 1990

A solution strategy for geometric non-linear analysis for the plane frame structures subjected to conservative and non-conservative forces is presented. By making efficient combination of the load incremental method and the displacement incremental method, this strategy can find postbuckling configuration such as snap-through and turning-back phenomena which cannot be easily found by the conventional load and displacement incrementation scheme. In the case of the analysis of the framed structure subjected to circulatory non-conservative forces, the total tangent stiffness matrix becomes unsymmetric and when calculating the incremental load and unbalanced load vector components, the direction change of the non-conservative forces is considered. Several example problems to demonstrate the feasibility of the present strategy, over ranges of deformation that are well beyond those likly to occur in practical framed structures, are given and discussed.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.26 no.6
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• pp.475-481
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• 2013

The residual stresses occur in the Frequency Selective Surface(FSS) embedded hybrid composite structures after co-curing due to mismatch among the coefficient of thermal expansions and stiffness values between the FSS and composite materials. The spring backs occur due to these residual stresses. Therefore, in this paper, the spring-backs caused by residual stresses in FSS embedded composite structures were studied with considering effect of symmetric and unsymmetric stacking sequence of composite laminates.

• Journal of Sasang Constitutional Medicine
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• v.24 no.2
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• pp.8-18
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• 2012

1. Objectives : This study aimed to assessing the reliability of questionnaire for Japanese as one of method to diagnose Sasang Constitution and evaluating the possibility of applying domestic questionnaire to foreign site. 2. Methods : A cross-sectional survey approved by IRB (Independent Review Board) at Tohoku University was performed for 119 participants with informed consent at a particular city in Japan using self-reported questionnaires developed by KIOM (Korea Institute of Oriental Medicine). Among the entire samples, 112 were retested. The test-retest reliability was assessed by Kappa for normal variables and internal consistency was evaluated by Cronbach's alpha. 3. Results : Four of 77 questions are impossible to calculate consistency owing to unsymmetric matrix between primary reply and secondary one. Seventeen of them (22%) showed 0.4 or below in Kappa, 56 were ranged from 0.4 to 0.8 and no question marked 0.8 or over. Internal consistency was possibly checked for several questions about character, digestion, sweat, excrement, urine, cold-heat pattern. Cronbach's alpha for questions except urine and cold-heat pattern was over 0.6 4. Conclusions : On the basis of Kappa value by two self reported questionnaire, 72.7% of questions showed 0.4 or over so that reliability were highly secured. And other questions except for urine and heat-cold pattern marked 0.6 or over in order that internal consistency was also successfully maintained. Accordingly, when subsequently applying KIOM questionnaire to foreign site, domestic questionnaire should be properly adjusted in social and cultural background, lifestyle, etc.