• 분석과학
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• 제17권6호
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• pp.476-480
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• 2004

A simple, rapid, reproducible and selective UV-Visible spectrophotometric method has been developed for determination of germanium in a week acid medium (pH = 3.0) in the presence of mandelic acid (MA) and malachite green (MG). A single extraction in chlorobenzene was used for the analysis. The germanium-MA ion association complex exhibits an absorption maximum at ${\lambda}_{max}=618nm$ with MG as counter ion and has an apparent molar absorptivtity of $1.313{\times}10^5L\;mol^{-1}\;cm^{-1}$. The values obtained by this UV-Visible spectrophotometric method are in good agreement with the values from inductively coupled plasma-mass spectrometer analysis.

• 대한화학회지
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• 제52권6호
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• pp.622-629
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• 2008

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1851-1853
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• 1996

In this paper the criteria for insulating oil condition of pole transformer were suggested by applying the UV-Visible spectrophotometric method. Ageing of insulating oil caused the change in absorbances of oil os well os the deterioration of electrical properties of oil. By comparing the electrical properties such as $tan{\delta}$ and breakdown voltage with the UV-Visible absorbances of oil, criteria for absorbance values determining oil condition were established. This UV-Visible spectrophotometric method might be applied in ageing analysis of oil and be expected to replace the current method.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2001년도 학술발표회 발표논문집
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• pp.421-425
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• 2001

Among the many parameters describing water quality, total nitrogen content(TN) is regarded as important one in relation to water quality management of the waterbodies for its role in eutrophication process. This study evaluated for accuracy, convenience and promptness of nitrogen analysis methods : (1)UV spectrophotometric method, (2)summation method, (3)cadmium reduction method. And, the detection limit of each method was calculated using EPA method. The UV spectrophotometric method after oxidation appears to be more convenient and accurate in determination of the TN contents than the summation method and cadmium reduction method. The summation method is necessary to separate determinations of the organic nitrogen, ammonia, nitrite, and nitrate. And, because summation method has many other methods for each contents, it can be detected for wide range of concentration.

• 약학회지
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• 제53권5호
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• pp.235-240
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• 2009

The interaction of cadmium (II) ion with quercetin was investigated in aqueous solution at different pH. The quercetin/cadmium stochiometries for cadmium (II) binding have been determined by UV-vis spectrophotometric method. The complexation of Cd(II) ion with 54.72 ${\mu}M$ quercetin (A=1.00793) was formed in 0.2 M $NH_3-0.2$ M $NH_4Cl$ (pH 8.0) buffer solution. 1:1 Cd(II)-complex had a maximum absorbance and showed the bathochromic shift of the long-wavelength band of the UV-vis spectra in the alkaline pH when interacted with quercetin in buffer solution. These results suggest that Cd(II)-quercetin complex has the optimal condition of chelation in basic buffer solution.

• 한국조명전기설비학회지:조명전기설비
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• 제10권5호
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• pp.94-100
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• 1996

자외- 가시선 흡수분광광도법을 적용하여 주상변압기 절연유의 판정기준을 제시하였다. 절연유가 열화하면 절연유의 전기적 특성치가 저하할 뿐만 아니라 흡광도값도 변하게 된다. tan$\delta$와 절연파괴전압과 같은 전기적 특성치를 흡광도값과 비교하여 흡광도값에 의한 절연유의 판정기분을 설정하였다. 흡광도값이 0.580 이하는 양호, 요주의는 0.580~0.900, 불량은 0.900이상이다. 자외-가시건 흡수분광광도법은 절연유의 열화분석에 적용할 수 있으며, 기존의 육안에 의한 절연유 검사 방법을 대체할 수 있을 것으로 기대된다. 그러나 분광광도법을 현장에 적용하려면 저렴하고 경량화된 휴대용 분광광도계의 개발이 필요하다.

• Archives of Pharmacal Research
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• 제14권4호
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• pp.285-289
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• 1991

A convenient spectrophotometric method was examined for the determination of amantadine sulfate (AMTS) which has no UV-VIS chromopohores. AMTS was ion-paired quantitatively with methyl orange (MO) at $70^{\circ}C$ for 30 min. The ion-paired complex was extracted with dichloromethane and the absorbance was measured at 421.5 nm. A linear relationship was observed in the range of $2.5{\times}10^{-7}\;M$ to $3.75{\times}10^{-6}\;M$ and the correlation coefficient was 0.999 (n=3). This assay method was applied to the quantification of AMTS in commercial tablet form with good recovery and high precision.

• 약학회지
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• 제31권5호
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• pp.330-337
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• 1987

The weak UV absorbing ephedrine alkaloids such as ephedrine, pseudoephedrine, methylephedrine and norephedrine could be analyzed by charge-transfer spectrophotometric method. The results obtained are summarized as follows: (1) It was possible to determine a weak UV absorbing ephedrine alkaloids using the intense charge-transfer UV bands in chloroform. (2) This method was suitable for the spectrophotometric determination of ephedrine alkaloids in mixed pharmaceutical preparation. (3) Linear relationship was found between absorbance and concentration in the range of 1.0$\times$$10^{-5}M$~5$\times$$10^{-5}M$ of ephedrine ($\varepsilon$= 2.72$\times$$10^{4}LM^{-1}cm^{-1}$ and pseudoephedrine ($\varepsilon$=2.84$\times$$10^{4]LM^{-1}cm^{-1}$), 1.0$\times$$10^{-5}M$~5$\times$$10^{-5}$M of methylephdrine ($\varepsilon$=1.68$\times$$10^{4}LM^{-1}cm^{-1}$) and 1/3$\times$$10^{-4}M$~4/3$\times$$10^{-4}M$ of norephedrine ($\varepsilon$=0.74$\times$$10^{4}LM^{-1}cm^{-1}$. (4) CT- complex of ephedrine, pseudoephedrine and methylephedrine has absorption maxima at 293nm and norephedrine have absorption maximum at 253nm. (5) CT-complexes were formed in a 1:1 ratio between ephedrine alkaloids and iodine in chloroform. (6) By UV, IR, and $^1H$-NMR spectra, it could be inferred that CT-complexes were formed by interaction between the basic nitrogen of ephedrine alkaloids as electron (n) donor and iodine as electron ($\sigma$) acceptor.

• 약학회지
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• 제33권3호
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• pp.141-148
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• 1989

The weak UV absorbing antihistaminics such as chlorpheniramine, triprolidine, tripelennamine and diphenhydramine were analyzed by charge-transfer spectrophotometric method. The results obtained are summarized as folows. It was possible to determine a weak UV absorbing antihistaminics using the intense charge-transfer UV bands in chloroform. Charge transfer complexes were formed in a 1:1 ratio between antihistaminics and iodine in chloroform. Linear relationship was found between absorbance and concentration in the range of $1.0\;{\times}\;10^{-5}M-5.0\;{\times}\;10^{-5}M$ for chlorpheniramine( ${\varepsilon}\;=\;2.082\;{\times}\;10^4$) and tripelennamine ( ${\varepsilon}\;=\;1.578\;{\times}\;10^4$), $1.0\;{\times}\;10^{-5}M-8.0\;{\times}\;10^{-5}M$ for triprolidine ( ${\varepsilon}\;=\;1.120\;{\times}\;10^4$) and $1.0\;{\times}\;10^{-5}M-1.0\;{\times}\;10^{-4}M$ for diphenhydramine ( ${\varepsilon}\;=\;9.900\;{\times}\;10^3$). Charge transfer complexes of chlorpheniramine, triprolidine and tripelennamine have absorption maxima at 293 nm and complex form of diphenhydramine has absorption maximum at 270 nm. By UV, IR spectra, it could be inferred that CT-complexes were formed by interaction between the basic nitrogen of antihistaminics as electron donor (non bonding electron) and iodine as electron acceptor (${\sigma}$ bonding electron).

• 약학회지
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• 제52권6호
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• pp.426-433
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• 2008

The interaction of cadmium (II) ion with protocatechuic acid ($H_3PA$) and ethylenediaminetetraacetic acid (EDTA) were investigated in aqueous solution at different pH. The protocatechuic acid and EDTA/cadmium stochiometries for cadmium (II) binding have been determined by UV-vis spectrophotometric method. The complexation of Cd (II) ion with protocatechuic acid was formed in solution. Among the two potential sites of chelation present in the protocatechuic acid structure, the carboxylic function presents higher complexation power toward Cd (II). 1 : 1 Cd (II)-complex had a maximum absorbance and showed the bathochromic shift of the long-wavelength band of the UV-vis spectra in the alkaline pH when interacted with protocatechuic acid in 0.2 M $NH_3$ - 0.2 M ${NH_4}Cl$ (pH 8.0) buffer. These results suggest that Cd $({H_2}PA)^+$ complex has the optimal condition of chelation in buffer solution at 64.22 ${\mu}M$ protocatechuic acid (A=1.01455).