• Title/Summary/Keyword: UV reactor

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Preparation and Characterization of PP-g-Poloxamer Membranes by UV Irradiation Methods and their Solutes Permeation Behaviors

  • Lee, S. H.;Shim, J. K.;Lee, Y. M.;Ahn, S. H.;Yoo, I. K.;Baek, K. H.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.97-98
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    • 1998
  • 1. Introduction : Polypropylene(PP) membrane is widely used in the field of microfiltration and ultrafiltration. However, the hydrophobicity of PP causes the adsorption of hydrophobic and amphoteric solutes in the feed. Surface modification techniques of membrane through the treatment of hydrophilizing agents, coating of hydrophilic compounds, UV, plasma and high energy irradiation, etc. can have a great effect on propensities to prevent the protein from staining membranes. Among them, the modification to hydophilize membrane surface using UV is very simple and effective. Recently many studies for more effective surface modification have been conducted. Iwata et al. prepared membranes by grafting polyethylene glycol diacrylate macromer(PEGDA) onto polysulfone with plasma using a glow discharge reactor which prevent the oil from staining the membrane. The primary mechanism contributing to the membranes is preventing the oil from directly contacting the surface of the membrane as the PEGDA chains dissolved into emulsion. To evaluate their feasibility for use as a anti-fouling separation membrane, we prepared hydrophilic membranes by UV irradiation method and investigated their characteristics.

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Effect of surface roughness on the quality of silicon epitaxial film grown after UV-irradiated gas phase cleaning

  • Kwon, Sung-Ku;Kim, Du-Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.504-509
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    • 1999
  • In-situ cleaning and subsequent silicon epitaxial film growth were performed in a load-locked reactor equipped with Hg-grid UV lamp and PBN heater to obtain the smooth and contaminant-free underlying surface and develop low-temperature epitaxial film growth process. The removals of organic and native oxide were investigated using UV-excited $O_2$ and $NF_{3}/H_{2}$, and the effect of the surface condition was examined on the quality of silicon epitaxial film grown at temperature as low as $750^{\circ}C$. UV-excited gas phase cleaning was found to be effective in removing the organic and native oxide successfully providing a smooth surface with RMS roughness of 0.5$\AA$ at optimal condition. Crystalline quality of epitaxial film was determined by smoothness of cleaned surface and the presence of native oxide and impurity. Crystalline defects such as dislocation loops or voids due to the surface roughness were observed by XTEM.

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Application of UV Photocatalytic Degradation of Benzene

  • Gan, Yi;Liu, Ruiqi;Yu, Zhimin
    • Journal of Urban Science
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    • v.8 no.2
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    • pp.29-34
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    • 2019
  • Benzene pollution is becoming increasingly serious, and the treatment technology of benzene has attracted much attention. In this paper, a self-made photocatalytic reactor was used to explore the removal rate of benzene under the ultraviolet light with the wavelength of 253.7nm. The results showed that the degradation rate of benzene decreased from 64.29% to 16.26% when the concentration increased from 43mg/㎥ to 256mg/㎥ under the condition of 28W UV light intensity and 50s residence time. Under the condition of 28W UV light intensity and 103mg/㎥ concentration, the residence time increased from 16.5s to 50s, and the benzene removal rate increased from 13.23% to 42.72%.Under the condition of benzene concentration 103mg/㎥ and residence time of 50s, the removal rate of benzene increased from 29.34% to 52.58% in the process of UV light intensity rising from 28W to 48W.It is concluded that decreasing the concentration and increasing the residence time of gas were beneficial to the removal of benzene and increasing the light intensity can improve the removal rate of benzene.

Degradation of Phenol in Water Using Circulation Dielectric Barrier Plasma Reactors (순환식 유전체 장벽 플라즈마 반응기를 이용한 수중 페놀 처리)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.38 no.3
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    • pp.251-260
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    • 2012
  • Objectives: The purpose of this study was evaluating the applicability of the circulation dielectric barrier plasma process (DBD) for efficiently treating non-biodegradable wastewater, such as phenol. Methods: The DBD plasma reactor system in this study consisted of a plasma reactor (discharge, ground electrode and quartz dielectric tube, external tube), high voltage source, air supply and reservoir. Effects of the operating parameters on the degradation of phenol and $UV_{254}$ absorbance such as first voltage (60-180 V), oxygen supply rate (0.5-3 l/min), liquid circulation rate (1.5-7 l/min), pH (3.02-11.06) and initial phenol concentration (12.5-100 mg/l) were investigated. Results: Experimental results showed that optimum first voltage, oxygen supply rate, and liquid circulation rate on phenol degradation were 160 V, 1 l/min, and 4.5 l/min, respectively. The removal efficiency of phenol increased with the increase in the initial pH of the phenol solution. To obtain a removal efficiency of phenol and COD of phenol of over 97% (initial phenol concentration, 50.0 mg/l), 15 min and 180 minutes was needed, respectively. Conclusions: It was considered that the absorbance of $UV_{254}$ for phenol degradation can be used as an indirect indicator of change in non-biodegradable organic compounds. Mineralization of the phenol solution may take a relatively longer time than that required for phenol degradation.

Removal Characteristics of Single and Binary Vapors of Acetone, Toluene, and Methyl Mercaptan by Cylindrical UV Reactor Installed with TiO2-Coated Perforated Plane (TiO2를 코팅한 다공판을 설치한 원통형 UV 반응기에 의한 아세톤, 톨루엔, 메틸메르캅탄 단일 증기 및 2성분 혼합증기의 제거특성)

  • Jeon, Jin-Woo;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.24 no.3
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    • pp.317-322
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    • 2015
  • The photocatalytic decomposition characteristics of toluene, acetone, and methyl mercaptan (MM) by UV reactor installed with $TiO_2$-coated perforated plane were studied. The removal efficiency of single toluene, acetone, and MM vapor was increased with increasing oxygen concentration, but decreased with increasing inlet concentration. Elimination capacity of single toluene, acetone, and MM vapor was obtained to be $628g/m^3{\cdot}day$, $1,041g/m^3{\cdot}day$, and $2,158g/m^3{\cdot}day$, respectively. Also, the photocatalytic decomposition of binary vapor consisted of toluene and acetone, toluene and MM, acetone and MM were observed. Elimination capacity of toluene mixed with acetone, toluene mixed with MM, acetone mixed with toluene, acetone mixed with MM, MM mixed with toluene, and MM mixed with acetone was $327g/m^3{\cdot}day$, $512g/m^3{\cdot}day$, $128g/m^3{\cdot}day$, $266g/m^3{\cdot}day$, $785g/m^3{\cdot}day$ and $883g/m^3{\cdot}day$, respectively. The inhibitory effect of acetone was higher than MM in photocatalytic decomposition of toluene, the inhibitory effect of toluene was higher than MM photocatalytic decomposition of acetone, and the inhibitory effect of toluene was higher than acetone in photocatalytic decomposition of MM.

Protective Effect of Cheonjeongkibo-Dan UV-Induced Cellular Damage in Human Dermal Fibroblast (천정기보단(天精氣保丹)의 자외선에 의한 세포 손상 억제 효과)

  • Lee, Ghang-Tai;Park, Si-Jun;Lee, Jung-No;Lee, Kwang-Sik;Kim, Dae-Sung;Mun, Yeun-Ja;Lee, Kun-Kuk;Woo, Won-Hong
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.24 no.6
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    • pp.950-955
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    • 2010
  • In this study, we prepared CheonJeongKiBo-Dan(7 oriental medicinal plants, 7OMP: Astragalus Membranaceus root, Panax Ginseng root, Glycyrrhiza Glabra (licorice) root, Schizandra Chinensis fruit, Polygonatum Odoratum, Rehmannia Glutinosa root, Paeonia Albiflora root) by extracting them in one reactor and studied its efficacies on skin. UV irradiation has been suggested as a major cause of photoaging in skin. In order to investigate protective effects against UV-B induced cellular damage, 7OMP was extracted with 70% ethanol and dissolved in DMSO. The protective effect was detected by MTT assay, reactive oxygen species (ROS) generation, phosphorylation of ATR and p53 in human dermal fibroblast cell system after UV-B irradiation. 7OMP reduced UV-B-induced cellular damage in HDFs cells, and inhibited ROS generation. UV-B-induced toxicity accompanying ROS production and the resultant DNA damage are responsible for activation of ATR, p53 and Bad. In this study, 7OMP hampered phosphorylations of ATR and p53 in human dermal fibroblasts. Therefore, 7OMP may be protective against UV-induced skin photoaging.

Enhancing Raw Bovine Milk Quality using Ultraviolet-C (UV-C) Irradiation: A Microbial and Lipid Peroxidation Study

  • Davids Makararpong;Supawan Tantayanon;Chupun Gowanit;Jiranij Jareonsawat;Sukuma Samgnamnim;Sirirat Wataradee;Henk Hogeveen;Chaidate Inchaisri
    • Food Science of Animal Resources
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    • v.44 no.2
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    • pp.372-389
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    • 2024
  • This study investigated the efficacy of ultraviolet-C (UV-C) irradiation in enhancing the quality of raw bovine milk by targeting microbial populations and lipid peroxidation, both of which are key factors in milk spoilage. We categorized the raw milk samples into three groups based on initial bacterial load: low (<3 Log 10 CFU/mL), medium (3-4 Log 10 CFU/mL), and high (>4 Log 10 CFU/mL). Using a 144 W thin-film UV-C reactor, we treated the milk with a flow rate of 3 L/min. We measured the bacterial count including standard plate count, coliform count, coagulase-negative staphylococci count, and lactic acid bacteria count and lipid peroxidation (via thiobarbituric acid reactive substances assay) pre- and post-treatment. Our results show that UV-C treatment significantly reduced bacterial counts, with the most notable reductions observed in high and medium initial load samples (>4 and 3-4 Log 10 CFU/mL, respectively). The treatment was particularly effective against coliforms, showing higher reduction efficiency compared to coagulase-negative staphylococci and lactic acid bacteria. Notably, lipid peroxidation in UV-C treated milk was significantly lower than in pasteurized or untreated milk, even after 72 hours. These findings demonstrate the potential of UV-C irradiation as a pre-treatment method for raw milk, offering substantial reduction in microbial content and prevention of lipid peroxidation, thereby enhancing milk quality.

Development of Practical Advanced Oxidation Treatment System for Decontamination of Soil and Groundwater Contaminated with Chlorinated Solvents (TCE, PCE): Phase II (염소계 화합물(TCE, PCE)로 오염된 토양 및 지하수 처리를 위한 실용적 고도산화처리시스템 개발 (II))

  • Kim, Sang-Yeek;Sohn, Seok-Gyu;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.15 no.2
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    • pp.10-17
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    • 2010
  • Advanced oxidation processes (AOPs) have advantages to reduce the processing time and mineralize contaminants dissolved in groundwater. Recently, remediation techniques for organic contamination in groundwater have been studied, and technology using $UV/H_2O_2$ is generally accepted as one of the most powerful and reliable alternative for the remediation of groundwater contamination. In this study, $UV/H_2O_2$ technology, which generates hydroxyl radical ($\cdot$ OH) as known for strong non-selective oxidant, was used to degrade chlorinated solvents (TCE and PCE), and it was expanded to apply continuous stirred tank reactor (CSTR) system (i.e. combinations of three CSTR). The tested parameters for CSTR system were retention time and groundwater/$H_2O_2$ injection volume ratio. To find optimum parameters for CSTR system, various retention time (6 min ~ 90 min) and groundwater/$H_2O_2$ injection volume ratio (5/1 ~ 119/1) were tested. Other conditions for CSTR were adapted from the batch test results, which concentration of $H_2O_2$ and UV dose were 29.4 mM (0.1%) and 4.3 kWh/L, respectively. Based on the experimental results, the optimum parameters for CSTR system were 20 min for retention time and 119/1 for groundwater/$H_2O_2$ injection volume ratio. Applying these optimum conditions, chlorinated solvents (TCE and PCE) were removed at 99.9% and 99.6%. Moreover, the effluent concentrations of TCE and PCE are 0.036 mg/L and 0.087 mg/L, respectively, which are satisfied the regulatory level (TCE 0.3 mg/L, PCE 0.1 mg/L). Consequently, the CSTR system using $UV/H_2O_2$ technology can achieve high removal efficiency in the event of treatment of groundwater contaminated by chlorinated solvents (TCE and PCE).

A Kinetic Study on the Photocatalytic Degradation of Gas-Phase VOCs Using TiO$_2$ photocatalyst

  • Kim, Sang-Bum;Jo, Young-Min;Hong, Sung-Chang
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E3
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    • pp.117-124
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    • 2001
  • The present paper examined the kinetics of photocatalytic degradation of volatile organic compounds (VOCs) including gaseous trichloroethylene (TCE) and acetone. In this study, we examined the effects of the initial concentration of VOCs and the light intensity of ultra-violet (UV). A batch photo-reactor was specifically designed for this work. The photocatalytic degradation rate increased with the initial concentration of VOCs but remained almost constant beyond a certain concentration. It matched well with the Langmuir-Hinshelwood (L-H) kinetic model. When the effect of light intensity was concerned, it was found that photocatalytic degradation occurs in two regimes with respect to light intensity.

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Characteristics of CO Removal Process Using TiO2 Photocatalyst (TiO2 광촉매를 이용한 CO제거 공정특성)

  • Kim, Jin-Kil;Lee, Sang-Moon;Hong, Sung-Chang;Lee, Eui-Dong;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.116-120
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    • 2013
  • Characteristics of photocatalytic CO removal process conducting CO conversion by using Pt loaded $TiO_2$ photocatalyst were investigated in a photocatalytic tubular reactor. Effects of Pt loading method onto $TiO_2$, linear velocity of gas stream containing CO gas, CO concentration and moisture content in the gas stream on the conversion of CO to $CO_2$ were examined. It was found that the CO gas could be removed almost 100% by using photocatalytic tubular reactor internally coated with Pt/$TiO_2$ photocatalyst under UV irradiation, when the linear velocity of gas stream was in the range of 0.01~0.25 m/s and CO concentration in the gas stream was ranged from 20 to 100 ppm and the relative humidity of the gas stream was in the range of 20~40%. The conversion of CO gas decreased gradually with increasing linear velocity of gas stream and CO concentration in the gas stream. The moisture in the gas stream could promote the removal of CO gas by means of the generation of OHradicals.